Rotation-vibration spectra of deuterated water vapor in the 9160-9390-cm-1 region

A. D. Bykov, V. P. Lopasov, Yu S. Makushkin, L. N. Sinitsa, O. N. Ulenikov, V. E. Zuev

Research output: Contribution to journalArticle

40 Citations (Scopus)

Abstract

The absorption spectrum of mixtures of H2O, HDO and D2O has been recorded in the region 9161.5 to 9392.5 cm-1 with an absorption sensitivity of 10-7 cm-1 and a line-center determination accuracy of 0.08 cm-1. An attempt to identify the absorption bands of the spectrum obtained experimentally was undertaken. The justification for attributing the observed lines to the HDO bands (3ν1 + ν2), (ν1 + 2ν2 + ν3) and D2O bands (ν2 + 3ν3), (ν1 + ν2 + 2ν3) is given. In this study the bands centers have been found and the molecular rotational and centrifugal constants have been determined as well.

Original languageEnglish
Pages (from-to)1-27
Number of pages27
JournalJournal of Molecular Spectroscopy
Volume94
Issue number1
DOIs
Publication statusPublished - 1982
Externally publishedYes

Fingerprint

Steam
water vapor
Absorption spectra
vibration
absorption spectra
sensitivity

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Spectroscopy
  • Atomic and Molecular Physics, and Optics

Cite this

Rotation-vibration spectra of deuterated water vapor in the 9160-9390-cm-1 region. / Bykov, A. D.; Lopasov, V. P.; Makushkin, Yu S.; Sinitsa, L. N.; Ulenikov, O. N.; Zuev, V. E.

In: Journal of Molecular Spectroscopy, Vol. 94, No. 1, 1982, p. 1-27.

Research output: Contribution to journalArticle

Bykov, A. D. ; Lopasov, V. P. ; Makushkin, Yu S. ; Sinitsa, L. N. ; Ulenikov, O. N. ; Zuev, V. E. / Rotation-vibration spectra of deuterated water vapor in the 9160-9390-cm-1 region. In: Journal of Molecular Spectroscopy. 1982 ; Vol. 94, No. 1. pp. 1-27.
@article{479c4c58e44c4fc0bf2f86b1c29feb72,
title = "Rotation-vibration spectra of deuterated water vapor in the 9160-9390-cm-1 region",
abstract = "The absorption spectrum of mixtures of H2O, HDO and D2O has been recorded in the region 9161.5 to 9392.5 cm-1 with an absorption sensitivity of 10-7 cm-1 and a line-center determination accuracy of 0.08 cm-1. An attempt to identify the absorption bands of the spectrum obtained experimentally was undertaken. The justification for attributing the observed lines to the HDO bands (3ν1 + ν2), (ν1 + 2ν2 + ν3) and D2O bands (ν2 + 3ν3), (ν1 + ν2 + 2ν3) is given. In this study the bands centers have been found and the molecular rotational and centrifugal constants have been determined as well.",
author = "Bykov, {A. D.} and Lopasov, {V. P.} and Makushkin, {Yu S.} and Sinitsa, {L. N.} and Ulenikov, {O. N.} and Zuev, {V. E.}",
year = "1982",
doi = "10.1016/0022-2852(82)90290-9",
language = "English",
volume = "94",
pages = "1--27",
journal = "Journal of Molecular Spectroscopy",
issn = "0022-2852",
publisher = "Academic Press Inc.",
number = "1",

}

TY - JOUR

T1 - Rotation-vibration spectra of deuterated water vapor in the 9160-9390-cm-1 region

AU - Bykov, A. D.

AU - Lopasov, V. P.

AU - Makushkin, Yu S.

AU - Sinitsa, L. N.

AU - Ulenikov, O. N.

AU - Zuev, V. E.

PY - 1982

Y1 - 1982

N2 - The absorption spectrum of mixtures of H2O, HDO and D2O has been recorded in the region 9161.5 to 9392.5 cm-1 with an absorption sensitivity of 10-7 cm-1 and a line-center determination accuracy of 0.08 cm-1. An attempt to identify the absorption bands of the spectrum obtained experimentally was undertaken. The justification for attributing the observed lines to the HDO bands (3ν1 + ν2), (ν1 + 2ν2 + ν3) and D2O bands (ν2 + 3ν3), (ν1 + ν2 + 2ν3) is given. In this study the bands centers have been found and the molecular rotational and centrifugal constants have been determined as well.

AB - The absorption spectrum of mixtures of H2O, HDO and D2O has been recorded in the region 9161.5 to 9392.5 cm-1 with an absorption sensitivity of 10-7 cm-1 and a line-center determination accuracy of 0.08 cm-1. An attempt to identify the absorption bands of the spectrum obtained experimentally was undertaken. The justification for attributing the observed lines to the HDO bands (3ν1 + ν2), (ν1 + 2ν2 + ν3) and D2O bands (ν2 + 3ν3), (ν1 + ν2 + 2ν3) is given. In this study the bands centers have been found and the molecular rotational and centrifugal constants have been determined as well.

UR - http://www.scopus.com/inward/record.url?scp=0002384975&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0002384975&partnerID=8YFLogxK

U2 - 10.1016/0022-2852(82)90290-9

DO - 10.1016/0022-2852(82)90290-9

M3 - Article

VL - 94

SP - 1

EP - 27

JO - Journal of Molecular Spectroscopy

JF - Journal of Molecular Spectroscopy

SN - 0022-2852

IS - 1

ER -