Rotation-vibration spectra of deuterated water vapor in the 9160-9390-cm^-1 region

A. D. Bykov, V. P. Lopasov, Yu S. Makushkin, L. N. Sinitsa, O. N. Ulenikov, V. E. Zuev

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Abstract

The absorption spectrum of mixtures of H₂O, HDO and D₂O has been recorded in the region 9161.5 to 9392.5 cm^-1 with an absorption sensitivity of 10^-7 cm^-1 and a line-center determination accuracy of 0.08 cm^-1. An attempt to identify the absorption bands of the spectrum obtained experimentally was undertaken. The justification for attributing the observed lines to the HDO bands (3ν₁ + ν₂), (ν₁ + 2ν₂ + ν₃) and D₂O bands (ν₂ + 3ν₃), (ν₁ + ν₂ + 2ν₃) is given. In this study the bands centers have been found and the molecular rotational and centrifugal constants have been determined as well.

Original language	English
Pages (from-to)	1-27
Number of pages	27
Journal	Journal of Molecular Spectroscopy
Volume	94
Issue number	1
DOIs	https://doi.org/10.1016/0022-2852(82)90290-9
Publication status	Published - 1982
Externally published	Yes

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ASJC Scopus subject areas

Physical and Theoretical Chemistry
Spectroscopy
Atomic and Molecular Physics, and Optics

Cite this

Bykov, A. D., Lopasov, V. P., Makushkin, Y. S., Sinitsa, L. N., Ulenikov, O. N., & Zuev, V. E. (1982). Rotation-vibration spectra of deuterated water vapor in the 9160-9390-cm^-1 region. Journal of Molecular Spectroscopy, 94(1), 1-27. https://doi.org/10.1016/0022-2852(82)90290-9

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title = "Rotation-vibration spectra of deuterated water vapor in the 9160-9390-cm-1 region",

abstract = "The absorption spectrum of mixtures of H2O, HDO and D2O has been recorded in the region 9161.5 to 9392.5 cm-1 with an absorption sensitivity of 10-7 cm-1 and a line-center determination accuracy of 0.08 cm-1. An attempt to identify the absorption bands of the spectrum obtained experimentally was undertaken. The justification for attributing the observed lines to the HDO bands (3ν1 + ν2), (ν1 + 2ν2 + ν3) and D2O bands (ν2 + 3ν3), (ν1 + ν2 + 2ν3) is given. In this study the bands centers have been found and the molecular rotational and centrifugal constants have been determined as well.",

author = "Bykov, {A. D.} and Lopasov, {V. P.} and Makushkin, {Yu S.} and Sinitsa, {L. N.} and Ulenikov, {O. N.} and Zuev, {V. E.}",

year = "1982",

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T1 - Rotation-vibration spectra of deuterated water vapor in the 9160-9390-cm-1 region

AU - Bykov, A. D.

AU - Lopasov, V. P.

AU - Makushkin, Yu S.

AU - Sinitsa, L. N.

AU - Ulenikov, O. N.

AU - Zuev, V. E.

PY - 1982

Y1 - 1982

N2 - The absorption spectrum of mixtures of H2O, HDO and D2O has been recorded in the region 9161.5 to 9392.5 cm-1 with an absorption sensitivity of 10-7 cm-1 and a line-center determination accuracy of 0.08 cm-1. An attempt to identify the absorption bands of the spectrum obtained experimentally was undertaken. The justification for attributing the observed lines to the HDO bands (3ν1 + ν2), (ν1 + 2ν2 + ν3) and D2O bands (ν2 + 3ν3), (ν1 + ν2 + 2ν3) is given. In this study the bands centers have been found and the molecular rotational and centrifugal constants have been determined as well.

AB - The absorption spectrum of mixtures of H2O, HDO and D2O has been recorded in the region 9161.5 to 9392.5 cm-1 with an absorption sensitivity of 10-7 cm-1 and a line-center determination accuracy of 0.08 cm-1. An attempt to identify the absorption bands of the spectrum obtained experimentally was undertaken. The justification for attributing the observed lines to the HDO bands (3ν1 + ν2), (ν1 + 2ν2 + ν3) and D2O bands (ν2 + 3ν3), (ν1 + ν2 + 2ν3) is given. In this study the bands centers have been found and the molecular rotational and centrifugal constants have been determined as well.

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10.1016/0022-2852(82)90290-9