Abstract
The absorption spectrum of mixtures of H2O, HDO and D2O has been recorded in the region 9161.5 to 9392.5 cm-1 with an absorption sensitivity of 10-7 cm-1 and a line-center determination accuracy of 0.08 cm-1. An attempt to identify the absorption bands of the spectrum obtained experimentally was undertaken. The justification for attributing the observed lines to the HDO bands (3ν1 + ν2), (ν1 + 2ν2 + ν3) and D2O bands (ν2 + 3ν3), (ν1 + ν2 + 2ν3) is given. In this study the bands centers have been found and the molecular rotational and centrifugal constants have been determined as well.
| Original language | English |
|---|---|
| Pages (from-to) | 1-27 |
| Number of pages | 27 |
| Journal | Journal of Molecular Spectroscopy |
| Volume | 94 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - 1982 |
| Externally published | Yes |
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ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Spectroscopy
- Atomic and Molecular Physics, and Optics
Cite this
Rotation-vibration spectra of deuterated water vapor in the 9160-9390-cm-1 region. / Bykov, A. D.; Lopasov, V. P.; Makushkin, Yu S.; Sinitsa, L. N.; Ulenikov, O. N.; Zuev, V. E.
In: Journal of Molecular Spectroscopy, Vol. 94, No. 1, 1982, p. 1-27.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Rotation-vibration spectra of deuterated water vapor in the 9160-9390-cm-1 region
AU - Bykov, A. D.
AU - Lopasov, V. P.
AU - Makushkin, Yu S.
AU - Sinitsa, L. N.
AU - Ulenikov, O. N.
AU - Zuev, V. E.
PY - 1982
Y1 - 1982
N2 - The absorption spectrum of mixtures of H2O, HDO and D2O has been recorded in the region 9161.5 to 9392.5 cm-1 with an absorption sensitivity of 10-7 cm-1 and a line-center determination accuracy of 0.08 cm-1. An attempt to identify the absorption bands of the spectrum obtained experimentally was undertaken. The justification for attributing the observed lines to the HDO bands (3ν1 + ν2), (ν1 + 2ν2 + ν3) and D2O bands (ν2 + 3ν3), (ν1 + ν2 + 2ν3) is given. In this study the bands centers have been found and the molecular rotational and centrifugal constants have been determined as well.
AB - The absorption spectrum of mixtures of H2O, HDO and D2O has been recorded in the region 9161.5 to 9392.5 cm-1 with an absorption sensitivity of 10-7 cm-1 and a line-center determination accuracy of 0.08 cm-1. An attempt to identify the absorption bands of the spectrum obtained experimentally was undertaken. The justification for attributing the observed lines to the HDO bands (3ν1 + ν2), (ν1 + 2ν2 + ν3) and D2O bands (ν2 + 3ν3), (ν1 + ν2 + 2ν3) is given. In this study the bands centers have been found and the molecular rotational and centrifugal constants have been determined as well.
UR - http://www.scopus.com/inward/record.url?scp=0002384975&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0002384975&partnerID=8YFLogxK
U2 - 10.1016/0022-2852(82)90290-9
DO - 10.1016/0022-2852(82)90290-9
M3 - Article
VL - 94
SP - 1
EP - 27
JO - Journal of Molecular Spectroscopy
JF - Journal of Molecular Spectroscopy
SN - 0022-2852
IS - 1
ER -