Role of spin states of polymethine dyes in the generation of electron-hole pairs

N. Kh Ibrayev, D. A. Afanasyev, A. A. Ishchenko, N. A. Davidenko

Research output: Contribution to journalArticle

Abstract

The spectral and luminescent properties of film composites based on photoconductive poly-N-epoxypropylcarbazole (PEPC) and electrically neutral polyvinylbutyral (PVB) with admixtures of polymethine dyes with various ionicities are studied. The external magnetic field effect on the spectral and luminescent properties of film composites based on PEPC with cationic polymethine and merocyanine dyes is studied. The magnetic field effect in the photogeneration of electron-hole pairs is explained by the participation of the singlet-triplet intersystem crossing of excited dye molecules.

Original languageEnglish
Pages (from-to)171-177
Number of pages7
JournalMolecular Crystals and Liquid Crystals
Volume589
Issue number1
DOIs
Publication statusPublished - 22 Jan 2014
Externally publishedYes

Keywords

  • electron-hole pair
  • Polymethine dye
  • triplet

ASJC Scopus subject areas

  • Chemistry(all)
  • Condensed Matter Physics
  • Materials Science(all)

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