Rhodium(II)-catalyzed asymmetric sulfur(VI) reduction of diazo sulfonylamidines

Abstract

Diazo sulfonylamidines readily undergo enantioselective oxygen transfer from sulfur to carbon atom in the presence of chiral rhodium(II) carboxylates resulting in chiral sulfinylamidines. This unusual asymmetric atom transfer "reduction" occurs rapidly under mild conditions, and sulfinylamidines are obtained in excellent yield.

Original language	English
Pages (from-to)	2477-2480
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	134
Issue number	5
DOIs	https://doi.org/10.1021/ja210180q
Publication status	Published - 8 Feb 2012
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)
Catalysis
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja210180q

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title = "Rhodium(II)-catalyzed asymmetric sulfur(VI) reduction of diazo sulfonylamidines",

abstract = "Diazo sulfonylamidines readily undergo enantioselective oxygen transfer from sulfur to carbon atom in the presence of chiral rhodium(II) carboxylates resulting in chiral sulfinylamidines. This unusual asymmetric atom transfer {"}reduction{"} occurs rapidly under mild conditions, and sulfinylamidines are obtained in excellent yield.",

author = "Nicklas Selander and Fokin, {Valery V.}",

year = "2012",

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AU - Fokin, Valery V.

PY - 2012/2/8

Y1 - 2012/2/8

N2 - Diazo sulfonylamidines readily undergo enantioselective oxygen transfer from sulfur to carbon atom in the presence of chiral rhodium(II) carboxylates resulting in chiral sulfinylamidines. This unusual asymmetric atom transfer "reduction" occurs rapidly under mild conditions, and sulfinylamidines are obtained in excellent yield.

AB - Diazo sulfonylamidines readily undergo enantioselective oxygen transfer from sulfur to carbon atom in the presence of chiral rhodium(II) carboxylates resulting in chiral sulfinylamidines. This unusual asymmetric atom transfer "reduction" occurs rapidly under mild conditions, and sulfinylamidines are obtained in excellent yield.

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Rhodium(II)-catalyzed asymmetric sulfur(VI) reduction of diazo sulfonylamidines

Abstract

ASJC Scopus subject areas

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