Rhodium(II)-catalyzed asymmetric sulfur(VI) reduction of diazo sulfonylamidines

Abstract

Diazo sulfonylamidines readily undergo enantioselective oxygen transfer from sulfur to carbon atom in the presence of chiral rhodium(II) carboxylates resulting in chiral sulfinylamidines. This unusual asymmetric atom transfer "reduction" occurs rapidly under mild conditions, and sulfinylamidines are obtained in excellent yield.

Original language	English
Pages (from-to)	2477-2480
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	134
Issue number	5
DOIs	https://doi.org/10.1021/ja210180q
Publication status	Published - 8 Feb 2012
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)
Catalysis
Biochemistry
Colloid and Surface Chemistry

Access to Document

10.1021/ja210180q

Fingerprint Dive into the research topics of 'Rhodium(II)-catalyzed asymmetric sulfur(VI) reduction of diazo sulfonylamidines'. Together they form a unique fingerprint.

Cite this

@article{577b289f5d944f9e9c383813cabde1c7,

title = "Rhodium(II)-catalyzed asymmetric sulfur(VI) reduction of diazo sulfonylamidines",

abstract = "Diazo sulfonylamidines readily undergo enantioselective oxygen transfer from sulfur to carbon atom in the presence of chiral rhodium(II) carboxylates resulting in chiral sulfinylamidines. This unusual asymmetric atom transfer {"}reduction{"} occurs rapidly under mild conditions, and sulfinylamidines are obtained in excellent yield.",

author = "Nicklas Selander and Fokin, {Valery V.}",

year = "2012",

month = feb,

day = "8",

doi = "10.1021/ja210180q",

language = "English",

volume = "134",

pages = "2477--2480",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "5",

}

TY - JOUR

T1 - Rhodium(II)-catalyzed asymmetric sulfur(VI) reduction of diazo sulfonylamidines

AU - Selander, Nicklas

AU - Fokin, Valery V.

PY - 2012/2/8

Y1 - 2012/2/8

N2 - Diazo sulfonylamidines readily undergo enantioselective oxygen transfer from sulfur to carbon atom in the presence of chiral rhodium(II) carboxylates resulting in chiral sulfinylamidines. This unusual asymmetric atom transfer "reduction" occurs rapidly under mild conditions, and sulfinylamidines are obtained in excellent yield.

AB - Diazo sulfonylamidines readily undergo enantioselective oxygen transfer from sulfur to carbon atom in the presence of chiral rhodium(II) carboxylates resulting in chiral sulfinylamidines. This unusual asymmetric atom transfer "reduction" occurs rapidly under mild conditions, and sulfinylamidines are obtained in excellent yield.

UR - http://www.scopus.com/inward/record.url?scp=84856727975&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84856727975&partnerID=8YFLogxK

U2 - 10.1021/ja210180q

DO - 10.1021/ja210180q

M3 - Article

C2 - 22233190

AN - SCOPUS:84856727975

VL - 134

SP - 2477

EP - 2480

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

IS - 5

ER -