Rhodium(II)-catalyzed asymmetric sulfur(VI) reduction of diazo sulfonylamidines

Nicklas Selander, Valery V. Fokin

Research output: Contribution to journalArticle

54 Citations (Scopus)

Abstract

Diazo sulfonylamidines readily undergo enantioselective oxygen transfer from sulfur to carbon atom in the presence of chiral rhodium(II) carboxylates resulting in chiral sulfinylamidines. This unusual asymmetric atom transfer "reduction" occurs rapidly under mild conditions, and sulfinylamidines are obtained in excellent yield.

Original languageEnglish
Pages (from-to)2477-2480
Number of pages4
JournalJournal of the American Chemical Society
Volume134
Issue number5
DOIs
Publication statusPublished - 8 Feb 2012
Externally publishedYes

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Rhodium
Sulfur
Carbon
Oxygen
Atoms

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Rhodium(II)-catalyzed asymmetric sulfur(VI) reduction of diazo sulfonylamidines. / Selander, Nicklas; Fokin, Valery V.

In: Journal of the American Chemical Society, Vol. 134, No. 5, 08.02.2012, p. 2477-2480.

Research output: Contribution to journalArticle

Selander, Nicklas ; Fokin, Valery V. / Rhodium(II)-catalyzed asymmetric sulfur(VI) reduction of diazo sulfonylamidines. In: Journal of the American Chemical Society. 2012 ; Vol. 134, No. 5. pp. 2477-2480.
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