Rhodium-catalyzed enantioselective cyclopropanation of olefins with N-sulfonyl 1,2,3-triazoles

Stepan Chuprakov, Sen Wai Kwok, Li Zhang, Lukas Lercher, Valery V. Fokin

Research output: Contribution to journalArticle

197 Citations (Scopus)

Abstract

(Figure Presented) N-Sulfonyl 1,2,3-triazoles readily form rhodium(II) azavinyl carbenes, which react with olefins to produce cyclopropanes with excellent diastereo- and enantioselectivity and in high yield.

Original languageEnglish
Pages (from-to)18034-18035
Number of pages2
JournalJournal of the American Chemical Society
Volume131
Issue number50
DOIs
Publication statusPublished - 23 Dec 2009
Externally publishedYes

Fingerprint

Cyclopropanes
Rhodium
Triazoles
Enantioselectivity
Alkenes
Olefins
carbene

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Rhodium-catalyzed enantioselective cyclopropanation of olefins with N-sulfonyl 1,2,3-triazoles. / Chuprakov, Stepan; Kwok, Sen Wai; Zhang, Li; Lercher, Lukas; Fokin, Valery V.

In: Journal of the American Chemical Society, Vol. 131, No. 50, 23.12.2009, p. 18034-18035.

Research output: Contribution to journalArticle

Chuprakov, Stepan ; Kwok, Sen Wai ; Zhang, Li ; Lercher, Lukas ; Fokin, Valery V. / Rhodium-catalyzed enantioselective cyclopropanation of olefins with N-sulfonyl 1,2,3-triazoles. In: Journal of the American Chemical Society. 2009 ; Vol. 131, No. 50. pp. 18034-18035.
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