Abstract
(Figure Presented) N-Sulfonyl 1,2,3-triazoles readily form rhodium(II) azavinyl carbenes, which react with olefins to produce cyclopropanes with excellent diastereo- and enantioselectivity and in high yield.
| Original language | English |
|---|---|
| Pages (from-to) | 18034-18035 |
| Number of pages | 2 |
| Journal | Journal of the American Chemical Society |
| Volume | 131 |
| Issue number | 50 |
| DOIs | |
| Publication status | Published - 23 Dec 2009 |
| Externally published | Yes |
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ASJC Scopus subject areas
- Chemistry(all)
- Catalysis
- Biochemistry
- Colloid and Surface Chemistry
Cite this
Rhodium-catalyzed enantioselective cyclopropanation of olefins with N-sulfonyl 1,2,3-triazoles. / Chuprakov, Stepan; Kwok, Sen Wai; Zhang, Li; Lercher, Lukas; Fokin, Valery V.
In: Journal of the American Chemical Society, Vol. 131, No. 50, 23.12.2009, p. 18034-18035.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Rhodium-catalyzed enantioselective cyclopropanation of olefins with N-sulfonyl 1,2,3-triazoles
AU - Chuprakov, Stepan
AU - Kwok, Sen Wai
AU - Zhang, Li
AU - Lercher, Lukas
AU - Fokin, Valery V.
PY - 2009/12/23
Y1 - 2009/12/23
N2 - (Figure Presented) N-Sulfonyl 1,2,3-triazoles readily form rhodium(II) azavinyl carbenes, which react with olefins to produce cyclopropanes with excellent diastereo- and enantioselectivity and in high yield.
AB - (Figure Presented) N-Sulfonyl 1,2,3-triazoles readily form rhodium(II) azavinyl carbenes, which react with olefins to produce cyclopropanes with excellent diastereo- and enantioselectivity and in high yield.
UR - http://www.scopus.com/inward/record.url?scp=72449165436&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=72449165436&partnerID=8YFLogxK
U2 - 10.1021/ja908075u
DO - 10.1021/ja908075u
M3 - Article
VL - 131
SP - 18034
EP - 18035
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 50
ER -