Rhodium-catalyzed enantioselective cyclopropanation of olefins with N-sulfonyl 1,2,3-triazoles

Stepan Chuprakov, Sen Wai Kwok, Li Zhang, Lukas Lercher, Valery V. Fokin

Research output: Contribution to journal › Article

Abstract

(Figure Presented) N-Sulfonyl 1,2,3-triazoles readily form rhodium(II) azavinyl carbenes, which react with olefins to produce cyclopropanes with excellent diastereo- and enantioselectivity and in high yield.

Original language	English
Pages (from-to)	18034-18035
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	131
Issue number	50
DOIs	https://doi.org/10.1021/ja908075u
Publication status	Published - 23 Dec 2009
Externally published	Yes

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ASJC Scopus subject areas

Chemistry(all)
Catalysis
Biochemistry
Colloid and Surface Chemistry

Cite this

Chuprakov, S., Kwok, S. W., Zhang, L., Lercher, L., & Fokin, V. V. (2009). Rhodium-catalyzed enantioselective cyclopropanation of olefins with N-sulfonyl 1,2,3-triazoles. Journal of the American Chemical Society, 131(50), 18034-18035. https://doi.org/10.1021/ja908075u

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abstract = "(Figure Presented) N-Sulfonyl 1,2,3-triazoles readily form rhodium(II) azavinyl carbenes, which react with olefins to produce cyclopropanes with excellent diastereo- and enantioselectivity and in high yield.",

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AU - Lercher, Lukas

AU - Fokin, Valery V.

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N2 - (Figure Presented) N-Sulfonyl 1,2,3-triazoles readily form rhodium(II) azavinyl carbenes, which react with olefins to produce cyclopropanes with excellent diastereo- and enantioselectivity and in high yield.

AB - (Figure Presented) N-Sulfonyl 1,2,3-triazoles readily form rhodium(II) azavinyl carbenes, which react with olefins to produce cyclopropanes with excellent diastereo- and enantioselectivity and in high yield.

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Access to Document

10.1021/ja908075u