Rhodium-catalyzed enantioselective cyclopropanation of olefins with N-sulfonyl 1,2,3-triazoles

Stepan Chuprakov, Sen Wai Kwok, Li Zhang, Lukas Lercher, Valery V. Fokin

Research output: Contribution to journal › Article › peer-review

Abstract

(Figure Presented) N-Sulfonyl 1,2,3-triazoles readily form rhodium(II) azavinyl carbenes, which react with olefins to produce cyclopropanes with excellent diastereo- and enantioselectivity and in high yield.

Original language	English
Pages (from-to)	18034-18035
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	131
Issue number	50
DOIs	https://doi.org/10.1021/ja908075u
Publication status	Published - 23 Dec 2009
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)
Catalysis
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja908075u

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title = "Rhodium-catalyzed enantioselective cyclopropanation of olefins with N-sulfonyl 1,2,3-triazoles",

abstract = "(Figure Presented) N-Sulfonyl 1,2,3-triazoles readily form rhodium(II) azavinyl carbenes, which react with olefins to produce cyclopropanes with excellent diastereo- and enantioselectivity and in high yield.",

author = "Stepan Chuprakov and Kwok, {Sen Wai} and Li Zhang and Lukas Lercher and Fokin, {Valery V.}",

year = "2009",

month = dec,

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language = "English",

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journal = "Journal of the American Chemical Society",

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T1 - Rhodium-catalyzed enantioselective cyclopropanation of olefins with N-sulfonyl 1,2,3-triazoles

AU - Chuprakov, Stepan

AU - Kwok, Sen Wai

AU - Zhang, Li

AU - Lercher, Lukas

AU - Fokin, Valery V.

PY - 2009/12/23

Y1 - 2009/12/23

N2 - (Figure Presented) N-Sulfonyl 1,2,3-triazoles readily form rhodium(II) azavinyl carbenes, which react with olefins to produce cyclopropanes with excellent diastereo- and enantioselectivity and in high yield.

AB - (Figure Presented) N-Sulfonyl 1,2,3-triazoles readily form rhodium(II) azavinyl carbenes, which react with olefins to produce cyclopropanes with excellent diastereo- and enantioselectivity and in high yield.

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