Abstract
(Figure Presented) N-Sulfonyl 1,2,3-triazoles readily form rhodium(II) azavinyl carbenes, which react with olefins to produce cyclopropanes with excellent diastereo- and enantioselectivity and in high yield.
| Original language | English |
|---|---|
| Pages (from-to) | 18034-18035 |
| Number of pages | 2 |
| Journal | Journal of the American Chemical Society |
| Volume | 131 |
| Issue number | 50 |
| DOIs | |
| Publication status | Published - 23 Dec 2009 |
| Externally published | Yes |
ASJC Scopus subject areas
- Chemistry(all)
- Catalysis
- Biochemistry
- Colloid and Surface Chemistry
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Cite this
Chuprakov, S., Kwok, S. W., Zhang, L., Lercher, L., & Fokin, V. V. (2009). Rhodium-catalyzed enantioselective cyclopropanation of olefins with N-sulfonyl 1,2,3-triazoles. Journal of the American Chemical Society, 131(50), 18034-18035. https://doi.org/10.1021/ja908075u