Relative Reactivity of Dicyclopentadiene and 2,3-Dicarbomethoxy-5-norbornene in Metathesis Copolymerization and the Properties of the Copolymer

A. A. Lyapkov, G. S. Bozhenkova, N. A. Smirnova, N. I. Prokudina, M. S. Yusubov, F. Verpoort

Research output: Contribution to journalArticle

Abstract

Abstract: In this paper, Fourier transform infrared spectroscopy (FTIR) was applied to examine the metathesis copolymerization of dicyclopentadiene with a mixture of exo,exo- and endo,endo-2,3-dicarbomethoxy-5-norbornene using a Hoveyda-Grubbs II type catalyst. The obtained data allowed us to calculate the monomer reactivity ratios of dicyclopentadiene and the isomers of 2,3-dicarbomethoxy-5-norbornenes. The relative reactivity of dicyclopentadiene was around eight times lower than the reactivity of the isomer mixtures.

Original languageEnglish
Pages (from-to)49-57
Number of pages9
JournalPolymer Science - Series C
Volume61
Issue number1
DOIs
Publication statusPublished - 1 Sep 2019

Fingerprint

dicyclopentadiene
Isomers
Copolymerization
Copolymers
Fourier transform infrared spectroscopy
Monomers
Catalysts
2-norbornene

ASJC Scopus subject areas

  • Chemistry(all)
  • Polymers and Plastics
  • Materials Chemistry

Cite this

Relative Reactivity of Dicyclopentadiene and 2,3-Dicarbomethoxy-5-norbornene in Metathesis Copolymerization and the Properties of the Copolymer. / Lyapkov, A. A.; Bozhenkova, G. S.; Smirnova, N. A.; Prokudina, N. I.; Yusubov, M. S.; Verpoort, F.

In: Polymer Science - Series C, Vol. 61, No. 1, 01.09.2019, p. 49-57.

Research output: Contribution to journalArticle

@article{78d52c3daac344d483065f225c44d294,
title = "Relative Reactivity of Dicyclopentadiene and 2,3-Dicarbomethoxy-5-norbornene in Metathesis Copolymerization and the Properties of the Copolymer",
abstract = "Abstract: In this paper, Fourier transform infrared spectroscopy (FTIR) was applied to examine the metathesis copolymerization of dicyclopentadiene with a mixture of exo,exo- and endo,endo-2,3-dicarbomethoxy-5-norbornene using a Hoveyda-Grubbs II type catalyst. The obtained data allowed us to calculate the monomer reactivity ratios of dicyclopentadiene and the isomers of 2,3-dicarbomethoxy-5-norbornenes. The relative reactivity of dicyclopentadiene was around eight times lower than the reactivity of the isomer mixtures.",
author = "Lyapkov, {A. A.} and Bozhenkova, {G. S.} and Smirnova, {N. A.} and Prokudina, {N. I.} and Yusubov, {M. S.} and F. Verpoort",
year = "2019",
month = "9",
day = "1",
doi = "10.1134/S1811238219010119",
language = "English",
volume = "61",
pages = "49--57",
journal = "Polymer Science - Series C",
issn = "1811-2382",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "1",

}

TY - JOUR

T1 - Relative Reactivity of Dicyclopentadiene and 2,3-Dicarbomethoxy-5-norbornene in Metathesis Copolymerization and the Properties of the Copolymer

AU - Lyapkov, A. A.

AU - Bozhenkova, G. S.

AU - Smirnova, N. A.

AU - Prokudina, N. I.

AU - Yusubov, M. S.

AU - Verpoort, F.

PY - 2019/9/1

Y1 - 2019/9/1

N2 - Abstract: In this paper, Fourier transform infrared spectroscopy (FTIR) was applied to examine the metathesis copolymerization of dicyclopentadiene with a mixture of exo,exo- and endo,endo-2,3-dicarbomethoxy-5-norbornene using a Hoveyda-Grubbs II type catalyst. The obtained data allowed us to calculate the monomer reactivity ratios of dicyclopentadiene and the isomers of 2,3-dicarbomethoxy-5-norbornenes. The relative reactivity of dicyclopentadiene was around eight times lower than the reactivity of the isomer mixtures.

AB - Abstract: In this paper, Fourier transform infrared spectroscopy (FTIR) was applied to examine the metathesis copolymerization of dicyclopentadiene with a mixture of exo,exo- and endo,endo-2,3-dicarbomethoxy-5-norbornene using a Hoveyda-Grubbs II type catalyst. The obtained data allowed us to calculate the monomer reactivity ratios of dicyclopentadiene and the isomers of 2,3-dicarbomethoxy-5-norbornenes. The relative reactivity of dicyclopentadiene was around eight times lower than the reactivity of the isomer mixtures.

UR - http://www.scopus.com/inward/record.url?scp=85074290093&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85074290093&partnerID=8YFLogxK

U2 - 10.1134/S1811238219010119

DO - 10.1134/S1811238219010119

M3 - Article

AN - SCOPUS:85074290093

VL - 61

SP - 49

EP - 57

JO - Polymer Science - Series C

JF - Polymer Science - Series C

SN - 1811-2382

IS - 1

ER -