Abstract
Abstract: In this paper, Fourier transform infrared spectroscopy (FTIR) was applied to examine the metathesis copolymerization of dicyclopentadiene with a mixture of exo,exo- and endo,endo-2,3-dicarbomethoxy-5-norbornene using a Hoveyda-Grubbs II type catalyst. The obtained data allowed us to calculate the monomer reactivity ratios of dicyclopentadiene and the isomers of 2,3-dicarbomethoxy-5-norbornenes. The relative reactivity of dicyclopentadiene was around eight times lower than the reactivity of the isomer mixtures.
| Original language | English |
|---|---|
| Pages (from-to) | 49-57 |
| Number of pages | 9 |
| Journal | Polymer Science - Series C |
| Volume | 61 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - 1 Sep 2019 |
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ASJC Scopus subject areas
- Chemistry(all)
- Polymers and Plastics
- Materials Chemistry
Cite this
Relative Reactivity of Dicyclopentadiene and 2,3-Dicarbomethoxy-5-norbornene in Metathesis Copolymerization and the Properties of the Copolymer. / Lyapkov, A. A.; Bozhenkova, G. S.; Smirnova, N. A.; Prokudina, N. I.; Yusubov, M. S.; Verpoort, F.
In: Polymer Science - Series C, Vol. 61, No. 1, 01.09.2019, p. 49-57.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Relative Reactivity of Dicyclopentadiene and 2,3-Dicarbomethoxy-5-norbornene in Metathesis Copolymerization and the Properties of the Copolymer
AU - Lyapkov, A. A.
AU - Bozhenkova, G. S.
AU - Smirnova, N. A.
AU - Prokudina, N. I.
AU - Yusubov, M. S.
AU - Verpoort, F.
PY - 2019/9/1
Y1 - 2019/9/1
N2 - Abstract: In this paper, Fourier transform infrared spectroscopy (FTIR) was applied to examine the metathesis copolymerization of dicyclopentadiene with a mixture of exo,exo- and endo,endo-2,3-dicarbomethoxy-5-norbornene using a Hoveyda-Grubbs II type catalyst. The obtained data allowed us to calculate the monomer reactivity ratios of dicyclopentadiene and the isomers of 2,3-dicarbomethoxy-5-norbornenes. The relative reactivity of dicyclopentadiene was around eight times lower than the reactivity of the isomer mixtures.
AB - Abstract: In this paper, Fourier transform infrared spectroscopy (FTIR) was applied to examine the metathesis copolymerization of dicyclopentadiene with a mixture of exo,exo- and endo,endo-2,3-dicarbomethoxy-5-norbornene using a Hoveyda-Grubbs II type catalyst. The obtained data allowed us to calculate the monomer reactivity ratios of dicyclopentadiene and the isomers of 2,3-dicarbomethoxy-5-norbornenes. The relative reactivity of dicyclopentadiene was around eight times lower than the reactivity of the isomer mixtures.
UR - http://www.scopus.com/inward/record.url?scp=85074290093&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85074290093&partnerID=8YFLogxK
U2 - 10.1134/S1811238219010119
DO - 10.1134/S1811238219010119
M3 - Article
AN - SCOPUS:85074290093
VL - 61
SP - 49
EP - 57
JO - Polymer Science - Series C
JF - Polymer Science - Series C
SN - 1811-2382
IS - 1
ER -