Relative Reactivity of Dicyclopentadiene and 2,3-Dicarbomethoxy-5-norbornene in Metathesis Copolymerization and the Properties of the Copolymer

A. A. Lyapkov, G. S. Bozhenkova, N. A. Smirnova, N. I. Prokudina, M. S. Yusubov, F. Verpoort

Research School of Chemistry & Applied Biomedical Sciences

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Abstract

Abstract: In this paper, Fourier transform infrared spectroscopy (FTIR) was applied to examine the metathesis copolymerization of dicyclopentadiene with a mixture of exo,exo- and endo,endo-2,3-dicarbomethoxy-5-norbornene using a Hoveyda-Grubbs II type catalyst. The obtained data allowed us to calculate the monomer reactivity ratios of dicyclopentadiene and the isomers of 2,3-dicarbomethoxy-5-norbornenes. The relative reactivity of dicyclopentadiene was around eight times lower than the reactivity of the isomer mixtures.

Original language	English
Pages (from-to)	49-57
Number of pages	9
Journal	Polymer Science - Series C
Volume	61
Issue number	1
DOIs	https://doi.org/10.1134/S1811238219010119
Publication status	Published - 1 Sep 2019

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ASJC Scopus subject areas

Chemistry(all)
Polymers and Plastics
Materials Chemistry

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Lyapkov, A. A., Bozhenkova, G. S., Smirnova, N. A., Prokudina, N. I., Yusubov, M. S., & Verpoort, F. (2019). Relative Reactivity of Dicyclopentadiene and 2,3-Dicarbomethoxy-5-norbornene in Metathesis Copolymerization and the Properties of the Copolymer. Polymer Science - Series C, 61(1), 49-57. https://doi.org/10.1134/S1811238219010119

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abstract = "Abstract: In this paper, Fourier transform infrared spectroscopy (FTIR) was applied to examine the metathesis copolymerization of dicyclopentadiene with a mixture of exo,exo- and endo,endo-2,3-dicarbomethoxy-5-norbornene using a Hoveyda-Grubbs II type catalyst. The obtained data allowed us to calculate the monomer reactivity ratios of dicyclopentadiene and the isomers of 2,3-dicarbomethoxy-5-norbornenes. The relative reactivity of dicyclopentadiene was around eight times lower than the reactivity of the isomer mixtures.",

author = "Lyapkov, {A. A.} and Bozhenkova, {G. S.} and Smirnova, {N. A.} and Prokudina, {N. I.} and Yusubov, {M. S.} and F. Verpoort",

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T1 - Relative Reactivity of Dicyclopentadiene and 2,3-Dicarbomethoxy-5-norbornene in Metathesis Copolymerization and the Properties of the Copolymer

AU - Lyapkov, A. A.

AU - Bozhenkova, G. S.

AU - Smirnova, N. A.

AU - Prokudina, N. I.

AU - Yusubov, M. S.

AU - Verpoort, F.

PY - 2019/9/1

Y1 - 2019/9/1

N2 - Abstract: In this paper, Fourier transform infrared spectroscopy (FTIR) was applied to examine the metathesis copolymerization of dicyclopentadiene with a mixture of exo,exo- and endo,endo-2,3-dicarbomethoxy-5-norbornene using a Hoveyda-Grubbs II type catalyst. The obtained data allowed us to calculate the monomer reactivity ratios of dicyclopentadiene and the isomers of 2,3-dicarbomethoxy-5-norbornenes. The relative reactivity of dicyclopentadiene was around eight times lower than the reactivity of the isomer mixtures.

AB - Abstract: In this paper, Fourier transform infrared spectroscopy (FTIR) was applied to examine the metathesis copolymerization of dicyclopentadiene with a mixture of exo,exo- and endo,endo-2,3-dicarbomethoxy-5-norbornene using a Hoveyda-Grubbs II type catalyst. The obtained data allowed us to calculate the monomer reactivity ratios of dicyclopentadiene and the isomers of 2,3-dicarbomethoxy-5-norbornenes. The relative reactivity of dicyclopentadiene was around eight times lower than the reactivity of the isomer mixtures.

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10.1134/S1811238219010119