Relative Reactivity of Dicyclopentadiene and 2,3-Dicarbomethoxy-5-norbornene in Metathesis Copolymerization and the Properties of the Copolymer

Abstract

Abstract: In this paper, Fourier transform infrared spectroscopy (FTIR) was applied to examine the metathesis copolymerization of dicyclopentadiene with a mixture of exo,exo- and endo,endo-2,3-dicarbomethoxy-5-norbornene using a Hoveyda-Grubbs II type catalyst. The obtained data allowed us to calculate the monomer reactivity ratios of dicyclopentadiene and the isomers of 2,3-dicarbomethoxy-5-norbornenes. The relative reactivity of dicyclopentadiene was around eight times lower than the reactivity of the isomer mixtures.

Original language	English
Pages (from-to)	49-57
Number of pages	9
Journal	Polymer Science - Series C
Volume	61
Issue number	1
DOIs	https://doi.org/10.1134/S1811238219010119
Publication status	Published - 1 Sep 2019

ASJC Scopus subject areas

Chemistry(all)
Polymers and Plastics
Materials Chemistry

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10.1134/S1811238219010119

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Relative Reactivity of Dicyclopentadiene and 2,3-Dicarbomethoxy-5-norbornene in Metathesis Copolymerization and the Properties of the Copolymer. / Lyapkov, A. A.; Bozhenkova, G. S.; Smirnova, N. A.; Prokudina, N. I.; Yusubov, M. S.; Verpoort, F.

In: Polymer Science - Series C, Vol. 61, No. 1, 01.09.2019, p. 49-57.

Research output: Contribution to journal › Article › peer-review

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title = "Relative Reactivity of Dicyclopentadiene and 2,3-Dicarbomethoxy-5-norbornene in Metathesis Copolymerization and the Properties of the Copolymer",

abstract = "Abstract: In this paper, Fourier transform infrared spectroscopy (FTIR) was applied to examine the metathesis copolymerization of dicyclopentadiene with a mixture of exo,exo- and endo,endo-2,3-dicarbomethoxy-5-norbornene using a Hoveyda-Grubbs II type catalyst. The obtained data allowed us to calculate the monomer reactivity ratios of dicyclopentadiene and the isomers of 2,3-dicarbomethoxy-5-norbornenes. The relative reactivity of dicyclopentadiene was around eight times lower than the reactivity of the isomer mixtures.",

author = "Lyapkov, {A. A.} and Bozhenkova, {G. S.} and Smirnova, {N. A.} and Prokudina, {N. I.} and Yusubov, {M. S.} and F. Verpoort",

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T1 - Relative Reactivity of Dicyclopentadiene and 2,3-Dicarbomethoxy-5-norbornene in Metathesis Copolymerization and the Properties of the Copolymer

AU - Lyapkov, A. A.

AU - Bozhenkova, G. S.

AU - Smirnova, N. A.

AU - Prokudina, N. I.

AU - Yusubov, M. S.

AU - Verpoort, F.

PY - 2019/9/1

Y1 - 2019/9/1

N2 - Abstract: In this paper, Fourier transform infrared spectroscopy (FTIR) was applied to examine the metathesis copolymerization of dicyclopentadiene with a mixture of exo,exo- and endo,endo-2,3-dicarbomethoxy-5-norbornene using a Hoveyda-Grubbs II type catalyst. The obtained data allowed us to calculate the monomer reactivity ratios of dicyclopentadiene and the isomers of 2,3-dicarbomethoxy-5-norbornenes. The relative reactivity of dicyclopentadiene was around eight times lower than the reactivity of the isomer mixtures.

AB - Abstract: In this paper, Fourier transform infrared spectroscopy (FTIR) was applied to examine the metathesis copolymerization of dicyclopentadiene with a mixture of exo,exo- and endo,endo-2,3-dicarbomethoxy-5-norbornene using a Hoveyda-Grubbs II type catalyst. The obtained data allowed us to calculate the monomer reactivity ratios of dicyclopentadiene and the isomers of 2,3-dicarbomethoxy-5-norbornenes. The relative reactivity of dicyclopentadiene was around eight times lower than the reactivity of the isomer mixtures.

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