Regioselective synthesis of 1,2,3-triazolyl derivatives of calix[4]arenes based on 1,3-dipolar cycloaddition

V. A. Burilov, N. A. Epifanova, E. V. Popova, S. F. Vasilevsky, S. E. Solovieva, I. S. Antipin, A. I. Konovalov

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Regioselective synthesis of 1,2,3-triazolyl derivatives of calix[4]arenes based on the 1,3-dipolar cycloaddition of substituted benzyl azides to tetra(propargyloxy)calix[4]arenes in the presence of copper iodide was carried out. The presence of the p-methoxybenzyl substituent in the triazole ring leads to a dramatic (more than tenfold) increase in the fluorescence of the corresponding macrocycle in a region of 290-310 nm.

Original languageEnglish
Pages (from-to)767-772
Number of pages6
JournalRussian Chemical Bulletin
Volume62
Issue number3
DOIs
Publication statusPublished - 1 Mar 2013
Externally publishedYes

Fingerprint

Triazoles
Azides
Cycloaddition
Iodides
Copper
Fluorescence
Derivatives

Keywords

  • 1,2,3-triazoles
  • 1,3-dipolar cycloaddition
  • benzyl azides
  • calix[4]arenes
  • fluorescence

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Burilov, V. A., Epifanova, N. A., Popova, E. V., Vasilevsky, S. F., Solovieva, S. E., Antipin, I. S., & Konovalov, A. I. (2013). Regioselective synthesis of 1,2,3-triazolyl derivatives of calix[4]arenes based on 1,3-dipolar cycloaddition. Russian Chemical Bulletin, 62(3), 767-772. https://doi.org/10.1007/s11172-013-0104-3

Regioselective synthesis of 1,2,3-triazolyl derivatives of calix[4]arenes based on 1,3-dipolar cycloaddition. / Burilov, V. A.; Epifanova, N. A.; Popova, E. V.; Vasilevsky, S. F.; Solovieva, S. E.; Antipin, I. S.; Konovalov, A. I.

In: Russian Chemical Bulletin, Vol. 62, No. 3, 01.03.2013, p. 767-772.

Research output: Contribution to journalArticle

Burilov, V. A. ; Epifanova, N. A. ; Popova, E. V. ; Vasilevsky, S. F. ; Solovieva, S. E. ; Antipin, I. S. ; Konovalov, A. I. / Regioselective synthesis of 1,2,3-triazolyl derivatives of calix[4]arenes based on 1,3-dipolar cycloaddition. In: Russian Chemical Bulletin. 2013 ; Vol. 62, No. 3. pp. 767-772.
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