Abstract
Graphical abstract Highlights Nucleophilic addition of amino alcohols to CF3CO-acetylenes gave enaminoketones. Diastereoselectivity is determined nature of amino alcohol. New type of fragmentation is observed to form amides and acetophenones. Possible reaction mechanism was proposed.
| Original language | English |
|---|---|
| Pages (from-to) | 61-67 |
| Number of pages | 7 |
| Journal | Journal of Fluorine Chemistry |
| Volume | 190 |
| DOIs | |
| Publication status | Published - 1 Oct 2016 |
| Externally published | Yes |
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ASJC Scopus subject areas
- Biochemistry
- Environmental Chemistry
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
Cite this
Reaction of trifluoroacetyl acetylenes with β-amino alcohols. Synthesis of enaminoketones and unusual fragmentation. / Davydova, Maria P.; Vasilevsky, Sergey F.; Nenajdenko, Valentine G.
In: Journal of Fluorine Chemistry, Vol. 190, 01.10.2016, p. 61-67.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Reaction of trifluoroacetyl acetylenes with β-amino alcohols. Synthesis of enaminoketones and unusual fragmentation
AU - Davydova, Maria P.
AU - Vasilevsky, Sergey F.
AU - Nenajdenko, Valentine G.
PY - 2016/10/1
Y1 - 2016/10/1
N2 - Graphical abstract Highlights Nucleophilic addition of amino alcohols to CF3CO-acetylenes gave enaminoketones. Diastereoselectivity is determined nature of amino alcohol. New type of fragmentation is observed to form amides and acetophenones. Possible reaction mechanism was proposed.
AB - Graphical abstract Highlights Nucleophilic addition of amino alcohols to CF3CO-acetylenes gave enaminoketones. Diastereoselectivity is determined nature of amino alcohol. New type of fragmentation is observed to form amides and acetophenones. Possible reaction mechanism was proposed.
UR - http://www.scopus.com/inward/record.url?scp=84986879581&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84986879581&partnerID=8YFLogxK
U2 - 10.1016/j.jfluchem.2016.08.008
DO - 10.1016/j.jfluchem.2016.08.008
M3 - Article
AN - SCOPUS:84986879581
VL - 190
SP - 61
EP - 67
JO - Journal of Fluorine Chemistry
JF - Journal of Fluorine Chemistry
SN - 0022-1139
ER -