RbBrF₄ Revisited

Sergei I. Ivlev, Antti J. Karttunen, Roman Ostvald, Florian Kraus

Division for Nuclear-Fuel Cycle

Research output: Contribution to journal › Article

Abstract

Rubidium tetrafluoridobromate(III) was synthesized and structurally characterized. The compound is isotypic to sodium and potassium tetrafluoridobromate(III), and crystallizes in the tetragonal space group I4/mcm (tI24, KBrF₄ structure type) with a = 6.3718(2), c = 11.4934(3) Å, V = 466.63(2) Å³, Z = 4, at T = 293 K. Additionally we investigated the compound by means of IR and Raman spectroscopy as well as theoretical studies. The data obtained by quantum chemical calculations confirm the crystal structure, and also the atomic distances and angles with an average deviation of 2.2 to 2.7 %.

Original language	English
Pages (from-to)	2593-2598
Number of pages	6
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	641
Issue number	15
DOIs	https://doi.org/10.1002/zaac.201500647
Publication status	Published - 1 Dec 2015

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Rubidium

Raman spectroscopy

Infrared spectroscopy

Potassium

Crystal structure

Sodium

Keywords

Crystal structure
Density functional calculations
Powder X-ray diffraction
Rubidium
Tetrafluoridobromate

ASJC Scopus subject areas

Inorganic Chemistry

Cite this

Ivlev, S. I., Karttunen, A. J., Ostvald, R., & Kraus, F. (2015). RbBrF₄ Revisited. Zeitschrift fur Anorganische und Allgemeine Chemie, 641(15), 2593-2598. https://doi.org/10.1002/zaac.201500647

RbBrF₄ Revisited. / Ivlev, Sergei I.; Karttunen, Antti J.; Ostvald, Roman; Kraus, Florian.

In: Zeitschrift fur Anorganische und Allgemeine Chemie, Vol. 641, No. 15, 01.12.2015, p. 2593-2598.

Research output: Contribution to journal › Article

Ivlev, SI, Karttunen, AJ, Ostvald, R & Kraus, F 2015, 'RbBrF₄ Revisited', Zeitschrift fur Anorganische und Allgemeine Chemie, vol. 641, no. 15, pp. 2593-2598. https://doi.org/10.1002/zaac.201500647

Ivlev SI, Karttunen AJ, Ostvald R, Kraus F. RbBrF₄ Revisited. Zeitschrift fur Anorganische und Allgemeine Chemie. 2015 Dec 1;641(15):2593-2598. https://doi.org/10.1002/zaac.201500647

Ivlev, Sergei I. ; Karttunen, Antti J. ; Ostvald, Roman ; Kraus, Florian. / RbBrF₄ Revisited. In: Zeitschrift fur Anorganische und Allgemeine Chemie. 2015 ; Vol. 641, No. 15. pp. 2593-2598.

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Access to Document

10.1002/zaac.201500647