Rational Design of Holey 2D Nonlayered Transition Metal Carbide/Nitride Heterostructure Nanosheets for Highly Efficient Water Oxidation

Zongkui Kou, Tingting Wang, Qilin Gu, Mo Xiong, Lirong Zheng, Xin Li, Zhenghui Pan, Hao Chen, Francis Verpoort, Anthony K. Cheetham, Shichun Mu, John Wang

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

Due to integrated advantages in electrochemical functionalities for energy conversion, 2D nonlayered heterostructure nanosheets offer new and fascinating opportunities for electrocatalysis but their fabrication is challenging when compared with the widely studied 2D layered heterostructure. Herein, a bottom-up approach is established for facile synthesis of holey 2D transition metal carbide/nitride heterostructure nanosheets (h-TMCN) with regulated hole sizes by controlled thermal annealing of the Mo/Zn bimetallic imidazolate frameworks (Mo/Zn BIFs). Ex situ phase and structural identifications disclose that the Mo/Zn BIFs precursor experiences interconnected three steps of transformation to produce h-TMCN. Especially, the slow successive solid-state diffusion of nitrogen and carbon into immediate noncrystalline molybdenum oxides allows the intergrowth of Mo 2 C and Mo 2 N into the 2D nonlayered heterostructure. X-ray fine structure analysis coupled with high resolution X-ray photoelectron spectroscopy demonstrate that Mo 2 C and Mo 2 N in the microdomains can chemically bond with each other, producing the abundant active N–Mo–C interfaces toward water splitting. Consequently, h-TMCN affords low overpotentials, high turnover frequencies, rapid charge transfer, and superior long-term stability toward electrocatalytic water oxidation. The present work demonstrates the feasibility of developing a broad range of 2D nonlayered heterostructures for high efficiency chemical energy conversion.

Original languageEnglish
Article number1803768
JournalAdvanced Energy Materials
DOIs
Publication statusPublished - 1 Jan 2019

Fingerprint

Nanosheets
Nitrides
Transition metals
Carbides
Heterojunctions
Oxidation
Water
Energy conversion
Molybdenum oxide
Electrocatalysis
Charge transfer
Nitrogen
Carbon
X ray photoelectron spectroscopy
Annealing
Fabrication
X rays

Keywords

  • 2D nonlayered structure
  • carbide
  • heterostructure
  • nitride
  • water splitting

ASJC Scopus subject areas

  • Renewable Energy, Sustainability and the Environment
  • Materials Science(all)

Cite this

Rational Design of Holey 2D Nonlayered Transition Metal Carbide/Nitride Heterostructure Nanosheets for Highly Efficient Water Oxidation. / Kou, Zongkui; Wang, Tingting; Gu, Qilin; Xiong, Mo; Zheng, Lirong; Li, Xin; Pan, Zhenghui; Chen, Hao; Verpoort, Francis; Cheetham, Anthony K.; Mu, Shichun; Wang, John.

In: Advanced Energy Materials, 01.01.2019.

Research output: Contribution to journalArticle

Kou, Zongkui ; Wang, Tingting ; Gu, Qilin ; Xiong, Mo ; Zheng, Lirong ; Li, Xin ; Pan, Zhenghui ; Chen, Hao ; Verpoort, Francis ; Cheetham, Anthony K. ; Mu, Shichun ; Wang, John. / Rational Design of Holey 2D Nonlayered Transition Metal Carbide/Nitride Heterostructure Nanosheets for Highly Efficient Water Oxidation. In: Advanced Energy Materials. 2019.
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