Radiation-induced processes and defects in alkali and alkaline-earth borate crystals

Igor N. Ogorodnikov, Victor Yu Yakovlev, Lyudmila I. Isaenko

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

The paper presents the results of a study of the radiation-induced processes and defects in nonlinear optical crystals Li2B 4O7 (LTB), LiB3O5 (LBO), CsLiB 6O10, KB5O8·4H2O, β-BaB2O4. It was revealed that a pulsed electron beam irradiation at 290 K forms the radiation-induced pairs of the 'vacancy - interstitial atom' defects in the cation sublattice of these crystals. This gives rise to a creation of metastable electronic (interstitial atom) and hole (small-radius polaron near the cation vacancy) centers in high concentrations. Optical hole-transitions from the local level of the trapped hole centers to the valence band states are responsible for the transient optical absorptions (TOA) of borates in the visible and UV spectral ranges. A sublattice of the weakly bound mobile lithium cations in LTB and LBO favors a spatial separation of the radiation-induced pair defects 'hole polaron near Li-vacancy - mobile interstitial Li0 atom'. Their decay rated by the electron-hole nonradiative tunnel recombination determines a peculiar feature of the TOA decay kinetics in LTB and LBO.

Original languageEnglish
Pages (from-to)659-662
Number of pages4
JournalRadiation Measurements
Volume38
Issue number4-6
DOIs
Publication statusPublished - Aug 2004

Fingerprint

borates
Vacancies
alkalies
Positive ions
Earth (planet)
Radiation
Atoms
Light absorption
Defects
Crystals
defects
radiation
interstitials
crystals
cations
sublattices
Valence bands
optical absorption
Electron beams
Tunnels

Keywords

  • β-BaBO (BBO)
  • CsLiBO (CLBO)
  • KBO ·4HO (KB5)
  • LiBO (LTB)
  • LiBO (LBO)
  • Radiation defects

ASJC Scopus subject areas

  • Radiation

Cite this

Radiation-induced processes and defects in alkali and alkaline-earth borate crystals. / Ogorodnikov, Igor N.; Yakovlev, Victor Yu; Isaenko, Lyudmila I.

In: Radiation Measurements, Vol. 38, No. 4-6, 08.2004, p. 659-662.

Research output: Contribution to journalArticle

Ogorodnikov, Igor N. ; Yakovlev, Victor Yu ; Isaenko, Lyudmila I. / Radiation-induced processes and defects in alkali and alkaline-earth borate crystals. In: Radiation Measurements. 2004 ; Vol. 38, No. 4-6. pp. 659-662.
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