Abstract
Lithium tert-butyltrialkylborates are capable of chemisorbing oxygen. The activation energy for thermal desorption of oxygen from [t-C4H9OB(OR)3]Li·nO2 at 298-548 K increases with decreasing degree of O2 sorption and with increasing length of the alkyl substituent; for complexes with R=n-C4H9, n-C7H15, and n-C10H21, the values increase from 48.90 to 70.92 kJ/mole.
Original language | English |
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Pages (from-to) | 209-211 |
Number of pages | 3 |
Journal | Bulletin of the Academy of Sciences of the USSR Division of Chemical Science |
Volume | 38 |
Issue number | 2 |
DOIs | |
Publication status | Published - Feb 1989 |
Externally published | Yes |
ASJC Scopus subject areas
- Chemistry(all)