Properties of lithium tetraalkylborate complexes in adsorption and desorption of oxygen

Z. T. Dmitrieva, I. G. Ryzhikova, V. I. Erofeev

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Abstract

Lithium tert-butyltrialkylborates are capable of chemisorbing oxygen. The activation energy for thermal desorption of oxygen from [t-C4H9OB(OR)3]Li·nO2 at 298-548 K increases with decreasing degree of O2 sorption and with increasing length of the alkyl substituent; for complexes with R=n-C4H9, n-C7H15, and n-C10H21, the values increase from 48.90 to 70.92 kJ/mole.

Original languageEnglish
Pages (from-to)209-211
Number of pages3
JournalBulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume38
Issue number2
DOIs
Publication statusPublished - Feb 1989
Externally publishedYes

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ASJC Scopus subject areas

  • Chemistry(all)

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