Properties of lithium tetraalkylborate complexes in adsorption and desorption of oxygen

Z. T. Dmitrieva, I. G. Ryzhikova, V. I. Erofeev

Research output: Contribution to journal › Article

Abstract

Lithium tert-butyltrialkylborates are capable of chemisorbing oxygen. The activation energy for thermal desorption of oxygen from [t-C₄H₉OB(OR)₃]Li·nO₂ at 298-548 K increases with decreasing degree of O₂ sorption and with increasing length of the alkyl substituent; for complexes with R=n-C₄H₉, n-C₇H₁₅, and n-C₁₀H₂₁, the values increase from 48.90 to 70.92 kJ/mole.

Original language	English
Pages (from-to)	209-211
Number of pages	3
Journal	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume	38
Issue number	2
DOIs	https://doi.org/10.1007/BF00953597
Publication status	Published - Feb 1989
Externally published	Yes

Fingerprint

Lithium

Desorption

Oxygen

Adsorption

Thermal desorption

Sorption

Activation energy

ASJC Scopus subject areas

Chemistry(all)

Cite this

Dmitrieva, Z. T., Ryzhikova, I. G., & Erofeev, V. I. (1989). Properties of lithium tetraalkylborate complexes in adsorption and desorption of oxygen. Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, 38(2), 209-211. https://doi.org/10.1007/BF00953597

Properties of lithium tetraalkylborate complexes in adsorption and desorption of oxygen. / Dmitrieva, Z. T.; Ryzhikova, I. G.; Erofeev, V. I.

In: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, Vol. 38, No. 2, 02.1989, p. 209-211.

Research output: Contribution to journal › Article

Dmitrieva, ZT, Ryzhikova, IG & Erofeev, VI 1989, 'Properties of lithium tetraalkylborate complexes in adsorption and desorption of oxygen', Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, vol. 38, no. 2, pp. 209-211. https://doi.org/10.1007/BF00953597

Dmitrieva ZT, Ryzhikova IG, Erofeev VI. Properties of lithium tetraalkylborate complexes in adsorption and desorption of oxygen. Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 1989 Feb;38(2):209-211. https://doi.org/10.1007/BF00953597

Dmitrieva, Z. T. ; Ryzhikova, I. G. ; Erofeev, V. I. / Properties of lithium tetraalkylborate complexes in adsorption and desorption of oxygen. In: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 1989 ; Vol. 38, No. 2. pp. 209-211.

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abstract = "Lithium tert-butyltrialkylborates are capable of chemisorbing oxygen. The activation energy for thermal desorption of oxygen from [t-C4H9OB(OR)3]Li·nO2 at 298-548 K increases with decreasing degree of O2 sorption and with increasing length of the alkyl substituent; for complexes with R=n-C4H9, n-C7H15, and n-C10H21, the values increase from 48.90 to 70.92 kJ/mole.",

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AB - Lithium tert-butyltrialkylborates are capable of chemisorbing oxygen. The activation energy for thermal desorption of oxygen from [t-C4H9OB(OR)3]Li·nO2 at 298-548 K increases with decreasing degree of O2 sorption and with increasing length of the alkyl substituent; for complexes with R=n-C4H9, n-C7H15, and n-C10H21, the values increase from 48.90 to 70.92 kJ/mole.

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Access to Document

10.1007/BF00953597