Abstract
The known methods of the detoxication of the high toxic and poisonous compounds such as thermal, catalytic oxidation, plasmochemical destruction, have a number of large technological lacks, consisting in necessity, of creating bulky installations, difficulty in operating, presence of the secondary polluting substances etc. By analysing the available ways of the degradation we have chosen the wet oxidation in a liquid phase under low temperatures and atmospheric pressure, thus the oxidizer is electrogenerated. We offered as such medium the water solutions sulfuric acid (with concentration 40-96%). It was found that conducting the current (with density to 1 A/cm2) in such solutions the degradation and the oxidizing destruction of metalorganic pesticides. The process passes as a result of electrochemical formation of the intermediate, thermodynamically unstable, the connections with the high oxidizing potential. The formally kinetic research of process is carried out, the influence of such factors, as temperature, density of a current, the composition of a solvent is revealed. The depth of the pesticides oxidizing destruction is easily adjusted. The stability of a number of constructional materials is also investigated under conditions of the realization of the pesticides oxidizing destruction process. The standard treating by the calcium hydroxide is used for the detoxication of the process final products. It is possible to carry out the process both in homogeneous system and in the presence suspended phase.
| Original language | English |
|---|---|
| Title of host publication | 8th Korea-Russia International Symposium on Science and Technology - Proceedings |
| Subtitle of host publication | KORUS 2004 |
| Pages | 94-96 |
| Number of pages | 3 |
| Publication status | Published - 1 Dec 2004 |
| Event | 8th Korea-Russia International Symposium on Science and Technology, KORUS 2004 - Tomsk, Russian Federation Duration: 26 Jun 2004 → 3 Jul 2004 |
Publication series
| Name | 8th Korea-Russia International Symposium on Science and Technology - Proceedings: KORUS 2004 |
|---|---|
| Volume | 2 |
Conference
| Conference | 8th Korea-Russia International Symposium on Science and Technology, KORUS 2004 |
|---|---|
| Country | Russian Federation |
| City | Tomsk |
| Period | 26.6.04 → 3.7.04 |
Fingerprint
Keywords
- And oxidation in a liquid phase
- Metalorganic compound
- Pesticides
ASJC Scopus subject areas
- Engineering(all)
Cite this
Process oxidaction the metallorganic pesticides in the sulfuric acid medium. / Volgina, T. N.; Katukhin, V. E.
8th Korea-Russia International Symposium on Science and Technology - Proceedings: KORUS 2004. 2004. p. 94-96 (8th Korea-Russia International Symposium on Science and Technology - Proceedings: KORUS 2004; Vol. 2).Research output: Chapter in Book/Report/Conference proceeding › Conference contribution
}
TY - GEN
T1 - Process oxidaction the metallorganic pesticides in the sulfuric acid medium
AU - Volgina, T. N.
AU - Katukhin, V. E.
PY - 2004/12/1
Y1 - 2004/12/1
N2 - The known methods of the detoxication of the high toxic and poisonous compounds such as thermal, catalytic oxidation, plasmochemical destruction, have a number of large technological lacks, consisting in necessity, of creating bulky installations, difficulty in operating, presence of the secondary polluting substances etc. By analysing the available ways of the degradation we have chosen the wet oxidation in a liquid phase under low temperatures and atmospheric pressure, thus the oxidizer is electrogenerated. We offered as such medium the water solutions sulfuric acid (with concentration 40-96%). It was found that conducting the current (with density to 1 A/cm2) in such solutions the degradation and the oxidizing destruction of metalorganic pesticides. The process passes as a result of electrochemical formation of the intermediate, thermodynamically unstable, the connections with the high oxidizing potential. The formally kinetic research of process is carried out, the influence of such factors, as temperature, density of a current, the composition of a solvent is revealed. The depth of the pesticides oxidizing destruction is easily adjusted. The stability of a number of constructional materials is also investigated under conditions of the realization of the pesticides oxidizing destruction process. The standard treating by the calcium hydroxide is used for the detoxication of the process final products. It is possible to carry out the process both in homogeneous system and in the presence suspended phase.
AB - The known methods of the detoxication of the high toxic and poisonous compounds such as thermal, catalytic oxidation, plasmochemical destruction, have a number of large technological lacks, consisting in necessity, of creating bulky installations, difficulty in operating, presence of the secondary polluting substances etc. By analysing the available ways of the degradation we have chosen the wet oxidation in a liquid phase under low temperatures and atmospheric pressure, thus the oxidizer is electrogenerated. We offered as such medium the water solutions sulfuric acid (with concentration 40-96%). It was found that conducting the current (with density to 1 A/cm2) in such solutions the degradation and the oxidizing destruction of metalorganic pesticides. The process passes as a result of electrochemical formation of the intermediate, thermodynamically unstable, the connections with the high oxidizing potential. The formally kinetic research of process is carried out, the influence of such factors, as temperature, density of a current, the composition of a solvent is revealed. The depth of the pesticides oxidizing destruction is easily adjusted. The stability of a number of constructional materials is also investigated under conditions of the realization of the pesticides oxidizing destruction process. The standard treating by the calcium hydroxide is used for the detoxication of the process final products. It is possible to carry out the process both in homogeneous system and in the presence suspended phase.
KW - And oxidation in a liquid phase
KW - Metalorganic compound
KW - Pesticides
UR - http://www.scopus.com/inward/record.url?scp=29144509957&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=29144509957&partnerID=8YFLogxK
M3 - Conference contribution
AN - SCOPUS:29144509957
SN - 0780383834
SN - 9780780383838
T3 - 8th Korea-Russia International Symposium on Science and Technology - Proceedings: KORUS 2004
SP - 94
EP - 96
BT - 8th Korea-Russia International Symposium on Science and Technology - Proceedings
ER -