Preparation, structure, and versatile reactivity of pseudocyclic benziodoxole triflate, new hypervalent iodine reagent

Akira Yoshimura, Khiem C. Nguyen, Scott C. Klasen, Akio Saito, Victor N. Nemykin, Viktor V. Zhdankin

Research output: Contribution to journalArticle

33 Citations (Scopus)

Abstract

A new pseudocyclic triflate derivative of benziodoxole (IBA-OTf) was prepared and characterized by X-ray analysis. This highly electrophilic reagent readily reacts with various organic substrates to give the corresponding products in good yields. Furthermore, IBA-OTf can be used as a catalyst with m-chloroperoxybenzoic acid as the terminal oxidant. This journal is

Original languageEnglish
Pages (from-to)7835-7838
Number of pages4
JournalChemical Communications
Volume51
Issue number37
DOIs
Publication statusPublished - 7 May 2015
Externally publishedYes

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X ray analysis
Iodine
Oxidants
Derivatives
Catalysts
Acids
Substrates
2-iodoxybenzoic acid

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

Preparation, structure, and versatile reactivity of pseudocyclic benziodoxole triflate, new hypervalent iodine reagent. / Yoshimura, Akira; Nguyen, Khiem C.; Klasen, Scott C.; Saito, Akio; Nemykin, Victor N.; Zhdankin, Viktor V.

In: Chemical Communications, Vol. 51, No. 37, 07.05.2015, p. 7835-7838.

Research output: Contribution to journalArticle

Yoshimura, Akira ; Nguyen, Khiem C. ; Klasen, Scott C. ; Saito, Akio ; Nemykin, Victor N. ; Zhdankin, Viktor V. / Preparation, structure, and versatile reactivity of pseudocyclic benziodoxole triflate, new hypervalent iodine reagent. In: Chemical Communications. 2015 ; Vol. 51, No. 37. pp. 7835-7838.
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