Preparation, structure, and versatile reactivity of pseudocyclic benziodoxole triflate, new hypervalent iodine reagent

Akira Yoshimura, Khiem C. Nguyen, Scott C. Klasen, Akio Saito, Victor N. Nemykin, Viktor V. Zhdankin

Research output: Contribution to journal › Article › peer-review

Abstract

A new pseudocyclic triflate derivative of benziodoxole (IBA-OTf) was prepared and characterized by X-ray analysis. This highly electrophilic reagent readily reacts with various organic substrates to give the corresponding products in good yields. Furthermore, IBA-OTf can be used as a catalyst with m-chloroperoxybenzoic acid as the terminal oxidant. This journal is

Original language	English
Pages (from-to)	7835-7838
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	37
DOIs	https://doi.org/10.1039/c5cc02009c
Publication status	Published - 7 May 2015
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "A new pseudocyclic triflate derivative of benziodoxole (IBA-OTf) was prepared and characterized by X-ray analysis. This highly electrophilic reagent readily reacts with various organic substrates to give the corresponding products in good yields. Furthermore, IBA-OTf can be used as a catalyst with m-chloroperoxybenzoic acid as the terminal oxidant. This journal is",

author = "Akira Yoshimura and Nguyen, {Khiem C.} and Klasen, {Scott C.} and Akio Saito and Nemykin, {Victor N.} and Zhdankin, {Viktor V.}",

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language = "English",

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AU - Yoshimura, Akira

AU - Nguyen, Khiem C.

AU - Klasen, Scott C.

AU - Saito, Akio

AU - Nemykin, Victor N.

AU - Zhdankin, Viktor V.

PY - 2015/5/7

Y1 - 2015/5/7

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AB - A new pseudocyclic triflate derivative of benziodoxole (IBA-OTf) was prepared and characterized by X-ray analysis. This highly electrophilic reagent readily reacts with various organic substrates to give the corresponding products in good yields. Furthermore, IBA-OTf can be used as a catalyst with m-chloroperoxybenzoic acid as the terminal oxidant. This journal is

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Preparation, structure, and versatile reactivity of pseudocyclic benziodoxole triflate, new hypervalent iodine reagent

Abstract

ASJC Scopus subject areas

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