Preparation, structure, and versatile reactivity of pseudocyclic benziodoxole triflate, new hypervalent iodine reagent

Akira Yoshimura, Khiem C. Nguyen, Scott C. Klasen, Akio Saito, Victor N. Nemykin, Viktor V. Zhdankin

Research output: Contribution to journal › Article

Abstract

A new pseudocyclic triflate derivative of benziodoxole (IBA-OTf) was prepared and characterized by X-ray analysis. This highly electrophilic reagent readily reacts with various organic substrates to give the corresponding products in good yields. Furthermore, IBA-OTf can be used as a catalyst with m-chloroperoxybenzoic acid as the terminal oxidant. This journal is

Original language	English
Pages (from-to)	7835-7838
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	37
DOIs	https://doi.org/10.1039/c5cc02009c
Publication status	Published - 7 May 2015
Externally published	Yes

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ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Cite this

Yoshimura, A., Nguyen, K. C., Klasen, S. C., Saito, A., Nemykin, V. N., & Zhdankin, V. V. (2015). Preparation, structure, and versatile reactivity of pseudocyclic benziodoxole triflate, new hypervalent iodine reagent. Chemical Communications, 51(37), 7835-7838. https://doi.org/10.1039/c5cc02009c

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Access to Document

10.1039/c5cc02009c