Preparation of High-Purity Iron by Means of Ammonium Chloride Complexes

A. N. D’yachenko, R. I. Kraidenko, A. A. Smorokov

Research output: Contribution to journalArticle

Abstract

A method for the preparation of high-purity iron via the chlorination of a mixture containing iron(III) oxide by ammonium chloride with the subsequent decomposition of the intermediate product to iron(III) chloride, its sublimation, and further reduction in a hydrogen flow was proposed. The reaction between ammonium chloride and iron(III) oxide and the thermal decomposition of the ammonium chloride complex were thermogravimetrically studied. The conditions and energetic characteristics of these reactions were determined. The method was tested on iron-containing raw materials. The impurities in the end product of reduction by hydrogen were 0.25%.

Original languageEnglish
Pages (from-to)736-741
Number of pages6
JournalRussian Journal of Inorganic Chemistry
Volume63
Issue number6
DOIs
Publication statusPublished - 1 Jun 2018

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Ammonium Chloride
ammonium chlorides
purity
Iron
Iron oxides
iron
preparation
Hydrogen
Chlorination
Sublimation
Chlorides
Raw materials
Pyrolysis
chlorination
oxides
Impurities
Decomposition
hydrogen
products
sublimation

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

Preparation of High-Purity Iron by Means of Ammonium Chloride Complexes. / D’yachenko, A. N.; Kraidenko, R. I.; Smorokov, A. A.

In: Russian Journal of Inorganic Chemistry, Vol. 63, No. 6, 01.06.2018, p. 736-741.

Research output: Contribution to journalArticle

D’yachenko, A. N. ; Kraidenko, R. I. ; Smorokov, A. A. / Preparation of High-Purity Iron by Means of Ammonium Chloride Complexes. In: Russian Journal of Inorganic Chemistry. 2018 ; Vol. 63, No. 6. pp. 736-741.
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