Preparation of enantiopure sultams by intramolecular Diels-Alder reaction of 1,3-cyclohexadiene-containing vinylsulfonamides

Victor O. Rogachev, Peter Metz

    Research output: Chapter in Book/Report/Conference proceedingConference contribution

    Abstract

    Enantiomerically pure δ-sultams have been prepared by intramolecular [4+2] cycloaddition of N-1-phenylethyl substituted vinylsulfonamides with purely thermal activation and under high pressure. An optimized procedure for reductive debenzylation of the resultant δ-sultams is also reported.

    Original languageEnglish
    Title of host publication8th Korea-Russia International Symposium on Science and Technology - Proceedings: KORUS 2004
    Pages76-79
    Number of pages4
    Volume2
    Publication statusPublished - 2004
    Event8th Korea-Russia International Symposium on Science and Technology, KORUS 2004 - Tomsk, Russian Federation
    Duration: 26 Jun 20043 Jul 2004

    Other

    Other8th Korea-Russia International Symposium on Science and Technology, KORUS 2004
    CountryRussian Federation
    CityTomsk
    Period26.6.043.7.04

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    Keywords

    • Debenzylation
    • Diels-Alder reactions
    • Pressure
    • Reactions under
    • Sultams

    ASJC Scopus subject areas

    • Engineering(all)

    Cite this

    Rogachev, V. O., & Metz, P. (2004). Preparation of enantiopure sultams by intramolecular Diels-Alder reaction of 1,3-cyclohexadiene-containing vinylsulfonamides. In 8th Korea-Russia International Symposium on Science and Technology - Proceedings: KORUS 2004 (Vol. 2, pp. 76-79)