Abstract
(Chemical Equation Presented) Preparation, structural characterization, and reactivity of 3-[bis(trifluoroacetoxy)iodo]benzoic acid and 3-[hydroxy-(tosyloxy)iodo]benzoic acid, new recyclable iodine(III) reagents derived from 3-iodosylbenzoic acid, are described. The reduced form of these reagents, 3-iodobenzoic acid, can be easily recovered from the reaction mixtures using ion-exchange resin or basic aqueous workup followed by acidification with HCl.
| Original language | English |
|---|---|
| Pages (from-to) | 295-297 |
| Number of pages | 3 |
| Journal | Journal of Organic Chemistry |
| Volume | 73 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - 4 Jan 2008 |
ASJC Scopus subject areas
- Organic Chemistry
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Cite this
Yusubov, M. S., Funk, T. V., Chi, K. W., Cha, E. H., Ghyung, H. K., Kirschning, A., & Zhdankin, V. V. (2008). Preparation and X-ray structures of 3-[bis(trifluoroacetoxy)iodo]benzoic acid and 3-[hydroxy(tosyloxy)iodo]benzoic acid: New recyclable hypervalent iodine reagents. Journal of Organic Chemistry, 73(1), 295-297. https://doi.org/10.1021/jo702112s