Preparation and X-ray structures of 3-[bis(trifluoroacetoxy)iodo]benzoic acid and 3-[hydroxy(tosyloxy)iodo]benzoic acid

New recyclable hypervalent iodine reagents

Mekhman S. Yusubov, Tatyana V. Funk, Ki Whan Chi, Eun Hye Cha, Hwa Kim Ghyung, Andreas Kirschning, Viktor Vladimirovich Zhdankin

Research output: Contribution to journalArticle

37 Citations (Scopus)

Abstract

(Chemical Equation Presented) Preparation, structural characterization, and reactivity of 3-[bis(trifluoroacetoxy)iodo]benzoic acid and 3-[hydroxy-(tosyloxy)iodo]benzoic acid, new recyclable iodine(III) reagents derived from 3-iodosylbenzoic acid, are described. The reduced form of these reagents, 3-iodobenzoic acid, can be easily recovered from the reaction mixtures using ion-exchange resin or basic aqueous workup followed by acidification with HCl.

Original languageEnglish
Pages (from-to)295-297
Number of pages3
JournalJournal of Organic Chemistry
Volume73
Issue number1
DOIs
Publication statusPublished - 4 Jan 2008

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Iodine
Ion Exchange Resins
X rays
Acidification
Acids
3-(bis(trifluoroacetoxy)iodo)benzoic acid
3-(hydroxy(tosyloxy)iodo)benzoic acid
3-iodobenzoic acid

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Preparation and X-ray structures of 3-[bis(trifluoroacetoxy)iodo]benzoic acid and 3-[hydroxy(tosyloxy)iodo]benzoic acid : New recyclable hypervalent iodine reagents. / Yusubov, Mekhman S.; Funk, Tatyana V.; Chi, Ki Whan; Cha, Eun Hye; Ghyung, Hwa Kim; Kirschning, Andreas; Zhdankin, Viktor Vladimirovich.

In: Journal of Organic Chemistry, Vol. 73, No. 1, 04.01.2008, p. 295-297.

Research output: Contribution to journalArticle

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