Abstract
Various 1-arylbenziodoxolones can be conveniently prepared from 2-iodobenzoic acid and arenes by a one-pot procedure using Oxone (2KHSO 5·KHSO4·K2SO4) as an inexpensive and environmentally safe oxidant. This procedure is also applicable for the synthesis of the 7-methylbenziodoxolone ring system using 2-iodo-3-methylbenzoic acid as starting compound. Structures of four 1-arylbenziodoxolone derivatives were established by single-crystal X-ray diffraction analysis. An enhanced reactivity of 1-aryl-7-methylbenziodoxolones toward nucleophiles compared to unsubstituted 1-arylbenziodoxolones has been found.
| Original language | English |
|---|---|
| Pages (from-to) | 3767-3773 |
| Number of pages | 7 |
| Journal | Journal of Organic Chemistry |
| Volume | 78 |
| Issue number | 8 |
| DOIs | |
| Publication status | Published - 19 Apr 2013 |
ASJC Scopus subject areas
- Organic Chemistry
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Cite this
Yusubov, M. S., Yusubova, R. Y., Nemykin, V. N., & Zhdankin, V. V. (2013). Preparation and X-ray structural study of 1-arylbenziodoxolones. Journal of Organic Chemistry, 78(8), 3767-3773. https://doi.org/10.1021/jo400212u