Preparation and structure of oligomeric iodosylbenzene sulfate (PhIO) 3·SO3

Stable and water-soluble analog of iodosylbenzene

Alexey Y. Koposov, Brian C. Netzel, Mekhman S. Yusubov, Victor N. Nemykin, Alexander Y. Nazarenko, Viktor Vladimirovich Zhdankin

Research output: Contribution to journalArticle

30 Citations (Scopus)

Abstract

New phenyliodine(III) sulfate (PhIO)3·SO3, which has a complex polymeric structure of the trimeric iodosylbenzene units linked by sulfate anions, can be conveniently prepared by treatment of (diacetoxy)iodobenzene with sodium bisulfate in the presence of water. This sulfate can find practical application as a readily available, stable, and water-soluble hypervalent iodine reagent with a reactivity pattern similar to that of iodosylbenzene.

Original languageEnglish
Pages (from-to)4475-4478
Number of pages4
JournalEuropean Journal of Organic Chemistry
Issue number27
DOIs
Publication statusPublished - 2007

Fingerprint

Sulfates
sulfates
analogs
preparation
Water
water
Iodine
iodine
Anions
reagents
reactivity
sodium
anions
iodosobenzene
sodium sulfate
iodobenzene

Keywords

  • Hypervalent compounds
  • Iodine
  • Iodosylbenzene
  • Oxidation
  • X-ray diffraction

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Preparation and structure of oligomeric iodosylbenzene sulfate (PhIO) 3·SO3 : Stable and water-soluble analog of iodosylbenzene. / Koposov, Alexey Y.; Netzel, Brian C.; Yusubov, Mekhman S.; Nemykin, Victor N.; Nazarenko, Alexander Y.; Zhdankin, Viktor Vladimirovich.

In: European Journal of Organic Chemistry, No. 27, 2007, p. 4475-4478.

Research output: Contribution to journalArticle

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AU - Zhdankin, Viktor Vladimirovich

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