Abstract
New phenyliodine(III) sulfate (PhIO)3·SO3, which has a complex polymeric structure of the trimeric iodosylbenzene units linked by sulfate anions, can be conveniently prepared by treatment of (diacetoxy)iodobenzene with sodium bisulfate in the presence of water. This sulfate can find practical application as a readily available, stable, and water-soluble hypervalent iodine reagent with a reactivity pattern similar to that of iodosylbenzene.
| Original language | English |
|---|---|
| Pages (from-to) | 4475-4478 |
| Number of pages | 4 |
| Journal | European Journal of Organic Chemistry |
| Issue number | 27 |
| DOIs | |
| Publication status | Published - 2007 |
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Keywords
- Hypervalent compounds
- Iodine
- Iodosylbenzene
- Oxidation
- X-ray diffraction
ASJC Scopus subject areas
- Organic Chemistry
Cite this
Preparation and structure of oligomeric iodosylbenzene sulfate (PhIO) 3·SO3 : Stable and water-soluble analog of iodosylbenzene. / Koposov, Alexey Y.; Netzel, Brian C.; Yusubov, Mekhman S.; Nemykin, Victor N.; Nazarenko, Alexander Y.; Zhdankin, Viktor Vladimirovich.
In: European Journal of Organic Chemistry, No. 27, 2007, p. 4475-4478.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Preparation and structure of oligomeric iodosylbenzene sulfate (PhIO) 3·SO3
T2 - Stable and water-soluble analog of iodosylbenzene
AU - Koposov, Alexey Y.
AU - Netzel, Brian C.
AU - Yusubov, Mekhman S.
AU - Nemykin, Victor N.
AU - Nazarenko, Alexander Y.
AU - Zhdankin, Viktor Vladimirovich
PY - 2007
Y1 - 2007
N2 - New phenyliodine(III) sulfate (PhIO)3·SO3, which has a complex polymeric structure of the trimeric iodosylbenzene units linked by sulfate anions, can be conveniently prepared by treatment of (diacetoxy)iodobenzene with sodium bisulfate in the presence of water. This sulfate can find practical application as a readily available, stable, and water-soluble hypervalent iodine reagent with a reactivity pattern similar to that of iodosylbenzene.
AB - New phenyliodine(III) sulfate (PhIO)3·SO3, which has a complex polymeric structure of the trimeric iodosylbenzene units linked by sulfate anions, can be conveniently prepared by treatment of (diacetoxy)iodobenzene with sodium bisulfate in the presence of water. This sulfate can find practical application as a readily available, stable, and water-soluble hypervalent iodine reagent with a reactivity pattern similar to that of iodosylbenzene.
KW - Hypervalent compounds
KW - Iodine
KW - Iodosylbenzene
KW - Oxidation
KW - X-ray diffraction
UR - http://www.scopus.com/inward/record.url?scp=34748852665&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=34748852665&partnerID=8YFLogxK
U2 - 10.1002/ejoc.200700625
DO - 10.1002/ejoc.200700625
M3 - Article
SP - 4475
EP - 4478
JO - Annalen der Pharmacie
JF - Annalen der Pharmacie
SN - 0075-4617
IS - 27
ER -