Preparation and structure of oligomeric iodosylbenzene sulfate (PhIO) ₃·SO₃: Stable and water-soluble analog of iodosylbenzene

Alexey Y. Koposov, Brian C. Netzel, Mekhman S. Yusubov, Victor N. Nemykin, Alexander Y. Nazarenko, Viktor Vladimirovich Zhdankin

Research School of Chemistry & Applied Biomedical Sciences

Research output: Contribution to journal › Article

30 Citations (Scopus)

Abstract

New phenyliodine(III) sulfate (PhIO)₃·SO₃, which has a complex polymeric structure of the trimeric iodosylbenzene units linked by sulfate anions, can be conveniently prepared by treatment of (diacetoxy)iodobenzene with sodium bisulfate in the presence of water. This sulfate can find practical application as a readily available, stable, and water-soluble hypervalent iodine reagent with a reactivity pattern similar to that of iodosylbenzene.

Original language	English
Pages (from-to)	4475-4478
Number of pages	4
Journal	European Journal of Organic Chemistry
Issue number	27
DOIs	https://doi.org/10.1002/ejoc.200700625
Publication status	Published - 2007

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Keywords

Hypervalent compounds
Iodine
Iodosylbenzene
Oxidation
X-ray diffraction

ASJC Scopus subject areas

Organic Chemistry

Cite this

Koposov, A. Y., Netzel, B. C., Yusubov, M. S., Nemykin, V. N., Nazarenko, A. Y., & Zhdankin, V. V. (2007). Preparation and structure of oligomeric iodosylbenzene sulfate (PhIO) ₃·SO₃: Stable and water-soluble analog of iodosylbenzene. European Journal of Organic Chemistry, (27), 4475-4478. https://doi.org/10.1002/ejoc.200700625

Preparation and structure of oligomeric iodosylbenzene sulfate (PhIO) ₃·SO₃ : Stable and water-soluble analog of iodosylbenzene. / Koposov, Alexey Y.; Netzel, Brian C.; Yusubov, Mekhman S.; Nemykin, Victor N.; Nazarenko, Alexander Y.; Zhdankin, Viktor Vladimirovich.

In: European Journal of Organic Chemistry, No. 27, 2007, p. 4475-4478.

Research output: Contribution to journal › Article

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AU - Nazarenko, Alexander Y.

AU - Zhdankin, Viktor Vladimirovich

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KW - Iodosylbenzene

KW - Oxidation

KW - X-ray diffraction

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Access to Document

10.1002/ejoc.200700625