Preparation and structure of oligomeric iodosylbenzene sulfate (PhIO) 3·SO3: Stable and water-soluble analog of iodosylbenzene

Alexey Y. Koposov, Brian C. Netzel, Mekhman S. Yusubov, Victor N. Nemykin, Alexander Y. Nazarenko, Viktor Vladimirovich Zhdankin

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30 Citations (Scopus)

Abstract

New phenyliodine(III) sulfate (PhIO)3·SO3, which has a complex polymeric structure of the trimeric iodosylbenzene units linked by sulfate anions, can be conveniently prepared by treatment of (diacetoxy)iodobenzene with sodium bisulfate in the presence of water. This sulfate can find practical application as a readily available, stable, and water-soluble hypervalent iodine reagent with a reactivity pattern similar to that of iodosylbenzene.

Original languageEnglish
Pages (from-to)4475-4478
Number of pages4
JournalEuropean Journal of Organic Chemistry
Issue number27
DOIs
Publication statusPublished - 2007

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Keywords

  • Hypervalent compounds
  • Iodine
  • Iodosylbenzene
  • Oxidation
  • X-ray diffraction

ASJC Scopus subject areas

  • Organic Chemistry

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