Preparation and reactivity of polystyrene-supported iodosylbenzene

Convenient recyclable oxidizing reagent and catalyst

Jiang Min Chen, Xiao Mei Zeng, Kyle Middleton, Mekhman S. Yusubov, Viktor Vladimirovich Zhdankin

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

A facile preparation of novel polystyrene-supported iodosylbenzene (PS-ISB, loading of IO up to 1.50 mmol/g) from iodopolystyrene is described. This resin has been successfully used for efficient oxidation of a diverse collection of alcohols to aldehydes and ketones in the presence of BF3OEt 2. PS-ISB can also be employed as efficient co-catalyst in combination with RuCl3 in the catalytic oxidation of alcohols and aromatic hydrocarbons, respectively, to corresponding carboxylic acids and ketones using Oxone as the stoichiometric oxidant.

Original languageEnglish
Pages (from-to)1613-1617
Number of pages5
JournalSynlett
Issue number11
DOIs
Publication statusPublished - 2011

Fingerprint

Polystyrenes
Ketones
Alcohols
Aromatic Hydrocarbons
Catalysts
Catalytic oxidation
Carboxylic Acids
Oxidants
Aldehydes
Resins
Oxidation
iodosobenzene
potassium peroxymonosulfuric acid

Keywords

  • iodine
  • iodosylbenzene
  • oxidation
  • polymers
  • recyclable reagent

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Preparation and reactivity of polystyrene-supported iodosylbenzene : Convenient recyclable oxidizing reagent and catalyst. / Chen, Jiang Min; Zeng, Xiao Mei; Middleton, Kyle; Yusubov, Mekhman S.; Zhdankin, Viktor Vladimirovich.

In: Synlett, No. 11, 2011, p. 1613-1617.

Research output: Contribution to journalArticle

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