TY - JOUR
T1 - Precise Study of the Lowest Vibration-Rotational Bands ν5 and ν3/ν6 of the CHD3 Molecule
AU - Ulenikov, O. N.
AU - Onopenko, G. A.
AU - Tyabaeva, N. E.
AU - Alanko, S.
AU - Koivusaari, M.
AU - Anttila, R.
PY - 1997/1/1
Y1 - 1997/1/1
N2 - The high-resolution absorption spectrum of the CHD3 molecule has been measured on a Fourier transform spectrometer in the region of the ν5 and ν3/ν6 bands and analyzed for the first time by taking into account a1 -a2 (K = 3) splittings of the ground vibrational state. The problem of ambiguity in determining the corresponding ∈̃ parameter of the ground vibrational state was solved on the basis of the analysis of the rotational structure of the ν5 band. Numerous a1-a2 splittings for the states with Kupper = 1, 2, 4, 5, 7 in the ν5 and ν6 bands are described.
AB - The high-resolution absorption spectrum of the CHD3 molecule has been measured on a Fourier transform spectrometer in the region of the ν5 and ν3/ν6 bands and analyzed for the first time by taking into account a1 -a2 (K = 3) splittings of the ground vibrational state. The problem of ambiguity in determining the corresponding ∈̃ parameter of the ground vibrational state was solved on the basis of the analysis of the rotational structure of the ν5 band. Numerous a1-a2 splittings for the states with Kupper = 1, 2, 4, 5, 7 in the ν5 and ν6 bands are described.
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U2 - 10.1006/jmsp.1997.7431
DO - 10.1006/jmsp.1997.7431
M3 - Article
AN - SCOPUS:0342884265
VL - 186
SP - 293
EP - 313
JO - Journal of Molecular Spectroscopy
JF - Journal of Molecular Spectroscopy
SN - 0022-2852
IS - 2
ER -