Abstract
The high-resolution absorption spectrum of the CHD3 molecule has been measured on a Fourier transform spectrometer in the region of the ν5 and ν3/ν6 bands and analyzed for the first time by taking into account a1 -a2 (K = 3) splittings of the ground vibrational state. The problem of ambiguity in determining the corresponding ∈̃ parameter of the ground vibrational state was solved on the basis of the analysis of the rotational structure of the ν5 band. Numerous a1-a2 splittings for the states with Kupper = 1, 2, 4, 5, 7 in the ν5 and ν6 bands are described.
| Original language | English |
|---|---|
| Pages (from-to) | 293-313 |
| Number of pages | 21 |
| Journal | Journal of Molecular Spectroscopy |
| Volume | 186 |
| Issue number | 2 |
| DOIs | |
| Publication status | Published - 1 Jan 1997 |
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ASJC Scopus subject areas
- Atomic and Molecular Physics, and Optics
- Spectroscopy
- Physical and Theoretical Chemistry
Cite this
Precise Study of the Lowest Vibration-Rotational Bands ν5 and ν3/ν6 of the CHD3 Molecule. / Ulenikov, O. N.; Onopenko, G. A.; Tyabaeva, N. E.; Alanko, S.; Koivusaari, M.; Anttila, R.
In: Journal of Molecular Spectroscopy, Vol. 186, No. 2, 01.01.1997, p. 293-313.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Precise Study of the Lowest Vibration-Rotational Bands ν5 and ν3/ν6 of the CHD3 Molecule
AU - Ulenikov, O. N.
AU - Onopenko, G. A.
AU - Tyabaeva, N. E.
AU - Alanko, S.
AU - Koivusaari, M.
AU - Anttila, R.
PY - 1997/1/1
Y1 - 1997/1/1
N2 - The high-resolution absorption spectrum of the CHD3 molecule has been measured on a Fourier transform spectrometer in the region of the ν5 and ν3/ν6 bands and analyzed for the first time by taking into account a1 -a2 (K = 3) splittings of the ground vibrational state. The problem of ambiguity in determining the corresponding ∈̃ parameter of the ground vibrational state was solved on the basis of the analysis of the rotational structure of the ν5 band. Numerous a1-a2 splittings for the states with Kupper = 1, 2, 4, 5, 7 in the ν5 and ν6 bands are described.
AB - The high-resolution absorption spectrum of the CHD3 molecule has been measured on a Fourier transform spectrometer in the region of the ν5 and ν3/ν6 bands and analyzed for the first time by taking into account a1 -a2 (K = 3) splittings of the ground vibrational state. The problem of ambiguity in determining the corresponding ∈̃ parameter of the ground vibrational state was solved on the basis of the analysis of the rotational structure of the ν5 band. Numerous a1-a2 splittings for the states with Kupper = 1, 2, 4, 5, 7 in the ν5 and ν6 bands are described.
UR - http://www.scopus.com/inward/record.url?scp=0342884265&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0342884265&partnerID=8YFLogxK
U2 - 10.1006/jmsp.1997.7431
DO - 10.1006/jmsp.1997.7431
M3 - Article
VL - 186
SP - 293
EP - 313
JO - Journal of Molecular Spectroscopy
JF - Journal of Molecular Spectroscopy
SN - 0022-2852
IS - 2
ER -