Abstract
(Equation Presented) Polytriazolylamines were synthesized by the copper(I)-catalyzed ligation of azides and alkynes. The C3-symmetric derivative, TBTA, was shown to be a powerful stabilizing ligand for copper(I), protecting it from oxidation and disproportionation, while enhancing its catalytic activity.
| Original language | English |
|---|---|
| Pages (from-to) | 2853-2855 |
| Number of pages | 3 |
| Journal | Organic Letters |
| Volume | 6 |
| Issue number | 17 |
| DOIs | |
| Publication status | Published - 19 Aug 2004 |
| Externally published | Yes |
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ASJC Scopus subject areas
- Molecular Medicine
Cite this
Polytriazoles as copper(I)-stabilizing ligands in catalysis. / Chan, Timothy R.; Hilgraf, Robert; Sharpless, K. Barry; Fokin, Valery V.
In: Organic Letters, Vol. 6, No. 17, 19.08.2004, p. 2853-2855.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Polytriazoles as copper(I)-stabilizing ligands in catalysis
AU - Chan, Timothy R.
AU - Hilgraf, Robert
AU - Sharpless, K. Barry
AU - Fokin, Valery V.
PY - 2004/8/19
Y1 - 2004/8/19
N2 - (Equation Presented) Polytriazolylamines were synthesized by the copper(I)-catalyzed ligation of azides and alkynes. The C3-symmetric derivative, TBTA, was shown to be a powerful stabilizing ligand for copper(I), protecting it from oxidation and disproportionation, while enhancing its catalytic activity.
AB - (Equation Presented) Polytriazolylamines were synthesized by the copper(I)-catalyzed ligation of azides and alkynes. The C3-symmetric derivative, TBTA, was shown to be a powerful stabilizing ligand for copper(I), protecting it from oxidation and disproportionation, while enhancing its catalytic activity.
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UR - http://www.scopus.com/inward/citedby.url?scp=4444324951&partnerID=8YFLogxK
U2 - 10.1021/ol0493094
DO - 10.1021/ol0493094
M3 - Article
VL - 6
SP - 2853
EP - 2855
JO - Organic Letters
JF - Organic Letters
SN - 1523-7060
IS - 17
ER -