Polyhedral Anions BnHn 2- (n = 6, 10, 12) in Lead Complexes

A. M. Orlova, L. V. Goeva, V. L. Lagun, K. A. Solntsev, N. T. Kuznetsov

Research output: Contribution to journalArticlepeer-review

3 Citations (Scopus)

Abstract

Reaction of lead nitrates with bipyridylamine (py2NH) in the presence of a series of closo-hydioborate anions B12H12 2+, B10H10 2+, and B6H6 2+ is considered. The compounds Pb(py2NH)2B12H12, Pb(py2N)(OH)B10H10, and [Pb(OH)]2B6H6 are synthesized. The IR spectra of the complexes are studied. It is shown that the formation of the inner coordination sphere of lead is influenced by the composition of the outersphere closo-hydroborate anion.

Original languageEnglish
Pages (from-to)377-380
Number of pages4
JournalRussian Journal of Inorganic Chemistry
Volume41
Issue number3
Publication statusPublished - 1996
Externally publishedYes

ASJC Scopus subject areas

  • Materials Science (miscellaneous)
  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

Fingerprint Dive into the research topics of 'Polyhedral Anions B<sub>n</sub>H<sub>n</sub> <sup>2-</sup> (n = 6, 10, 12) in Lead Complexes'. Together they form a unique fingerprint.

Cite this