Polybromide salts of tetraalkyl and N-heterocyclic cations

New entries into the structural library

Igor D. Gorokh, Sergey A. Adonin, Maxim N. Sokolov, Pavel A. Abramov, Ilya V. Korolkov, Evgeniy Yu Semitut, Vladimir P. Fedin

    Research output: Contribution to journalArticle

    5 Citations (Scopus)

    Abstract

    Reactions between Br2 dissolved in HBr and salts of various organic cations resulted in formation of a series of polyhalide salts: (IsoquinolH)Br3 (1), (2-BrPyH)Br3 (2), (H2(4,4′-bipy))(Br3)2 (3), Bu4NBr3 (4), (Collidinium){(Br3)(Br2)} (5) and Et4N{(Br3)(Br2)2} (6). All compounds were characterized by X-ray diffractometry; the role of supramolecular Br⋯Br contacts is discussed.

    Original languageEnglish
    Pages (from-to)583-587
    Number of pages5
    JournalInorganica Chimica Acta
    Volume469
    DOIs
    Publication statusPublished - 1 Jan 2018

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    Cations
    Salts
    Positive ions
    salts
    cations
    X ray diffraction analysis
    x rays

    Keywords

    • Polybromides
    • Polyhalides
    • Supramolecular contacts
    • X-ray diffractometry

    ASJC Scopus subject areas

    • Physical and Theoretical Chemistry
    • Inorganic Chemistry
    • Materials Chemistry

    Cite this

    Gorokh, I. D., Adonin, S. A., Sokolov, M. N., Abramov, P. A., Korolkov, I. V., Semitut, E. Y., & Fedin, V. P. (2018). Polybromide salts of tetraalkyl and N-heterocyclic cations: New entries into the structural library. Inorganica Chimica Acta, 469, 583-587. https://doi.org/10.1016/j.ica.2017.10.008

    Polybromide salts of tetraalkyl and N-heterocyclic cations : New entries into the structural library. / Gorokh, Igor D.; Adonin, Sergey A.; Sokolov, Maxim N.; Abramov, Pavel A.; Korolkov, Ilya V.; Semitut, Evgeniy Yu; Fedin, Vladimir P.

    In: Inorganica Chimica Acta, Vol. 469, 01.01.2018, p. 583-587.

    Research output: Contribution to journalArticle

    Gorokh, ID, Adonin, SA, Sokolov, MN, Abramov, PA, Korolkov, IV, Semitut, EY & Fedin, VP 2018, 'Polybromide salts of tetraalkyl and N-heterocyclic cations: New entries into the structural library', Inorganica Chimica Acta, vol. 469, pp. 583-587. https://doi.org/10.1016/j.ica.2017.10.008
    Gorokh, Igor D. ; Adonin, Sergey A. ; Sokolov, Maxim N. ; Abramov, Pavel A. ; Korolkov, Ilya V. ; Semitut, Evgeniy Yu ; Fedin, Vladimir P. / Polybromide salts of tetraalkyl and N-heterocyclic cations : New entries into the structural library. In: Inorganica Chimica Acta. 2018 ; Vol. 469. pp. 583-587.
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    abstract = "Reactions between Br2 dissolved in HBr and salts of various organic cations resulted in formation of a series of polyhalide salts: (IsoquinolH)Br3 (1), (2-BrPyH)Br3 (2), (H2(4,4′-bipy))(Br3)2 (3), Bu4NBr3 (4), (Collidinium){(Br3)(Br2)} (5) and Et4N{(Br3)(Br2)2} (6). All compounds were characterized by X-ray diffractometry; the role of supramolecular Br⋯Br contacts is discussed.",
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    AU - Gorokh, Igor D.

    AU - Adonin, Sergey A.

    AU - Sokolov, Maxim N.

    AU - Abramov, Pavel A.

    AU - Korolkov, Ilya V.

    AU - Semitut, Evgeniy Yu

    AU - Fedin, Vladimir P.

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    AB - Reactions between Br2 dissolved in HBr and salts of various organic cations resulted in formation of a series of polyhalide salts: (IsoquinolH)Br3 (1), (2-BrPyH)Br3 (2), (H2(4,4′-bipy))(Br3)2 (3), Bu4NBr3 (4), (Collidinium){(Br3)(Br2)} (5) and Et4N{(Br3)(Br2)2} (6). All compounds were characterized by X-ray diffractometry; the role of supramolecular Br⋯Br contacts is discussed.

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    KW - Supramolecular contacts

    KW - X-ray diffractometry

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