Polybromide salts of tetraalkyl and N-heterocyclic cations: New entries into the structural library

Igor D. Gorokh, Sergey A. Adonin, Maxim N. Sokolov, Pavel A. Abramov, Ilya V. Korolkov, Evgeniy Yu Semitut, Vladimir P. Fedin

    Research output: Contribution to journalArticlepeer-review

    7 Citations (Scopus)

    Abstract

    Reactions between Br2 dissolved in HBr and salts of various organic cations resulted in formation of a series of polyhalide salts: (IsoquinolH)Br3 (1), (2-BrPyH)Br3 (2), (H2(4,4′-bipy))(Br3)2 (3), Bu4NBr3 (4), (Collidinium){(Br3)(Br2)} (5) and Et4N{(Br3)(Br2)2} (6). All compounds were characterized by X-ray diffractometry; the role of supramolecular Br⋯Br contacts is discussed.

    Original languageEnglish
    Pages (from-to)583-587
    Number of pages5
    JournalInorganica Chimica Acta
    Volume469
    DOIs
    Publication statusPublished - 1 Jan 2018

    Keywords

    • Polybromides
    • Polyhalides
    • Supramolecular contacts
    • X-ray diffractometry

    ASJC Scopus subject areas

    • Physical and Theoretical Chemistry
    • Inorganic Chemistry
    • Materials Chemistry

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