Polybromide salts of tetraalkyl and N-heterocyclic cations: New entries into the structural library

Igor D. Gorokh, Sergey A. Adonin, Maxim N. Sokolov, Pavel A. Abramov, Ilya V. Korolkov, Evgeniy Yu Semitut, Vladimir P. Fedin

    Research output: Contribution to journalArticle

    6 Citations (Scopus)

    Abstract

    Reactions between Br2 dissolved in HBr and salts of various organic cations resulted in formation of a series of polyhalide salts: (IsoquinolH)Br3 (1), (2-BrPyH)Br3 (2), (H2(4,4′-bipy))(Br3)2 (3), Bu4NBr3 (4), (Collidinium){(Br3)(Br2)} (5) and Et4N{(Br3)(Br2)2} (6). All compounds were characterized by X-ray diffractometry; the role of supramolecular Br⋯Br contacts is discussed.

    Original languageEnglish
    Pages (from-to)583-587
    Number of pages5
    JournalInorganica Chimica Acta
    Volume469
    DOIs
    Publication statusPublished - 1 Jan 2018

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    Cations
    Salts
    Positive ions
    salts
    cations
    X ray diffraction analysis
    x rays

    Keywords

    • Polybromides
    • Polyhalides
    • Supramolecular contacts
    • X-ray diffractometry

    ASJC Scopus subject areas

    • Physical and Theoretical Chemistry
    • Inorganic Chemistry
    • Materials Chemistry

    Cite this

    Gorokh, I. D., Adonin, S. A., Sokolov, M. N., Abramov, P. A., Korolkov, I. V., Semitut, E. Y., & Fedin, V. P. (2018). Polybromide salts of tetraalkyl and N-heterocyclic cations: New entries into the structural library. Inorganica Chimica Acta, 469, 583-587. https://doi.org/10.1016/j.ica.2017.10.008

    Polybromide salts of tetraalkyl and N-heterocyclic cations : New entries into the structural library. / Gorokh, Igor D.; Adonin, Sergey A.; Sokolov, Maxim N.; Abramov, Pavel A.; Korolkov, Ilya V.; Semitut, Evgeniy Yu; Fedin, Vladimir P.

    In: Inorganica Chimica Acta, Vol. 469, 01.01.2018, p. 583-587.

    Research output: Contribution to journalArticle

    Gorokh, ID, Adonin, SA, Sokolov, MN, Abramov, PA, Korolkov, IV, Semitut, EY & Fedin, VP 2018, 'Polybromide salts of tetraalkyl and N-heterocyclic cations: New entries into the structural library', Inorganica Chimica Acta, vol. 469, pp. 583-587. https://doi.org/10.1016/j.ica.2017.10.008
    Gorokh, Igor D. ; Adonin, Sergey A. ; Sokolov, Maxim N. ; Abramov, Pavel A. ; Korolkov, Ilya V. ; Semitut, Evgeniy Yu ; Fedin, Vladimir P. / Polybromide salts of tetraalkyl and N-heterocyclic cations : New entries into the structural library. In: Inorganica Chimica Acta. 2018 ; Vol. 469. pp. 583-587.
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    abstract = "Reactions between Br2 dissolved in HBr and salts of various organic cations resulted in formation of a series of polyhalide salts: (IsoquinolH)Br3 (1), (2-BrPyH)Br3 (2), (H2(4,4′-bipy))(Br3)2 (3), Bu4NBr3 (4), (Collidinium){(Br3)(Br2)} (5) and Et4N{(Br3)(Br2)2} (6). All compounds were characterized by X-ray diffractometry; the role of supramolecular Br⋯Br contacts is discussed.",
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    AU - Gorokh, Igor D.

    AU - Adonin, Sergey A.

    AU - Sokolov, Maxim N.

    AU - Abramov, Pavel A.

    AU - Korolkov, Ilya V.

    AU - Semitut, Evgeniy Yu

    AU - Fedin, Vladimir P.

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    AB - Reactions between Br2 dissolved in HBr and salts of various organic cations resulted in formation of a series of polyhalide salts: (IsoquinolH)Br3 (1), (2-BrPyH)Br3 (2), (H2(4,4′-bipy))(Br3)2 (3), Bu4NBr3 (4), (Collidinium){(Br3)(Br2)} (5) and Et4N{(Br3)(Br2)2} (6). All compounds were characterized by X-ray diffractometry; the role of supramolecular Br⋯Br contacts is discussed.

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    KW - Supramolecular contacts

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