Polarographic behaviour and determination of 1-(4′-bromophenyl)-3,3-dimethyltriazene

Ljubiša M. Ignjatović, Jiří Barek, Jiří Zima, Dragan A. Marković

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

A study was made of the polarographic behaviour of the genotoxic substance 1-(4′-bromopheyl)-3,3-dimethlytriazene and optimum conditions were found for its determination by tast polarography and differential-pulse polarography at a static mercury drop electrode in the concentration range 1 × 10-4-1 × 10-7 mol dm-3. The results indicate that the method can be used at pH between 4.5 and6.0 for the identification and determination of the investigated substance, which is protonated without decomposition in this pH range. It was established that for the reduction of the NN group four electrons are required and the resulting products are 4-bromoaniline and dimethylhydrazine.

Original languageEnglish
Pages (from-to)413-418
Number of pages6
JournalAnalytica Chimica Acta
Volume284
Issue number2
DOIs
Publication statusPublished - 30 Dec 1993
Externally publishedYes

Fingerprint

Polarography
Polarographic analysis
electrode
Dimethylhydrazines
decomposition
electron
Mercury
Electrodes
Electrons
Decomposition
1-(4-bromophenyl)-3,3-dimethyltriazene
method
mercury
product
4-bromoaniline

Keywords

  • Bromophenyldimethyltriazene
  • Polarography
  • Triazenes

ASJC Scopus subject areas

  • Analytical Chemistry
  • Environmental Chemistry
  • Biochemistry
  • Spectroscopy

Cite this

Polarographic behaviour and determination of 1-(4′-bromophenyl)-3,3-dimethyltriazene. / Ignjatović, Ljubiša M.; Barek, Jiří; Zima, Jiří; Marković, Dragan A.

In: Analytica Chimica Acta, Vol. 284, No. 2, 30.12.1993, p. 413-418.

Research output: Contribution to journalArticle

Ignjatović, Ljubiša M. ; Barek, Jiří ; Zima, Jiří ; Marković, Dragan A. / Polarographic behaviour and determination of 1-(4′-bromophenyl)-3,3-dimethyltriazene. In: Analytica Chimica Acta. 1993 ; Vol. 284, No. 2. pp. 413-418.
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