Abstract
Polarographic behavior of the genotoxic substance 1,1-dimethyl-3- phenyltriazene was investigated and optimum conditions were found for its determination by sampled direct current polarography and differential pulse polarography at a static mercury drop electrode in the concentration range from 1 × 10-4 to 1 × 10-7 mol l-1. It was established that for reduction of the triazene group four electrons are required resulting in the formation of amino and hydrazo compound. The resulting products were identified, and the reduction pathway was proposed.
| Original language | English |
|---|---|
| Pages (from-to) | 1229-1243 |
| Number of pages | 15 |
| Journal | Collection of Czechoslovak Chemical Communications |
| Volume | 72 |
| Issue number | 9 |
| DOIs | |
| Publication status | Published - 1 Sep 2007 |
| Externally published | Yes |
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Keywords
- Carcinogens
- Electroreductions
- Polarography
- Reduction mechanism
- Triazenes
ASJC Scopus subject areas
- Chemistry(all)
Cite this
Polarographic behavior and determination of 1,1-dimethyl-3-phenyltriazene. / Ignjatović, Ljubiša M.; Barek, Jiří; Zima, Jiří; Marković, Dragan A.
In: Collection of Czechoslovak Chemical Communications, Vol. 72, No. 9, 01.09.2007, p. 1229-1243.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Polarographic behavior and determination of 1,1-dimethyl-3-phenyltriazene
AU - Ignjatović, Ljubiša M.
AU - Barek, Jiří
AU - Zima, Jiří
AU - Marković, Dragan A.
PY - 2007/9/1
Y1 - 2007/9/1
N2 - Polarographic behavior of the genotoxic substance 1,1-dimethyl-3- phenyltriazene was investigated and optimum conditions were found for its determination by sampled direct current polarography and differential pulse polarography at a static mercury drop electrode in the concentration range from 1 × 10-4 to 1 × 10-7 mol l-1. It was established that for reduction of the triazene group four electrons are required resulting in the formation of amino and hydrazo compound. The resulting products were identified, and the reduction pathway was proposed.
AB - Polarographic behavior of the genotoxic substance 1,1-dimethyl-3- phenyltriazene was investigated and optimum conditions were found for its determination by sampled direct current polarography and differential pulse polarography at a static mercury drop electrode in the concentration range from 1 × 10-4 to 1 × 10-7 mol l-1. It was established that for reduction of the triazene group four electrons are required resulting in the formation of amino and hydrazo compound. The resulting products were identified, and the reduction pathway was proposed.
KW - Carcinogens
KW - Electroreductions
KW - Polarography
KW - Reduction mechanism
KW - Triazenes
UR - http://www.scopus.com/inward/record.url?scp=36849024303&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=36849024303&partnerID=8YFLogxK
U2 - 10.1135/cccc20071229
DO - 10.1135/cccc20071229
M3 - Article
AN - SCOPUS:36849024303
VL - 72
SP - 1229
EP - 1243
JO - Collection of Czechoslovak Chemical Communications
JF - Collection of Czechoslovak Chemical Communications
SN - 0010-0765
IS - 9
ER -