Polarographic behavior and determination of 1,1-dimethyl-3-phenyltriazene

Ljubiša M. Ignjatović, Jiří Barek, Jiří Zima, Dragan A. Marković

Research output: Contribution to journal › Article

Abstract

Polarographic behavior of the genotoxic substance 1,1-dimethyl-3- phenyltriazene was investigated and optimum conditions were found for its determination by sampled direct current polarography and differential pulse polarography at a static mercury drop electrode in the concentration range from 1 × 10^-4 to 1 × 10^-7 mol l^-1. It was established that for reduction of the triazene group four electrons are required resulting in the formation of amino and hydrazo compound. The resulting products were identified, and the reduction pathway was proposed.

Original language	English
Pages (from-to)	1229-1243
Number of pages	15
Journal	Collection of Czechoslovak Chemical Communications
Volume	72
Issue number	9
DOIs	https://doi.org/10.1135/cccc20071229
Publication status	Published - 1 Sep 2007
Externally published	Yes

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Keywords

Carcinogens
Electroreductions
Polarography
Reduction mechanism
Triazenes

ASJC Scopus subject areas

Chemistry(all)

Cite this

Ignjatović, L. M., Barek, J., Zima, J., & Marković, D. A. (2007). Polarographic behavior and determination of 1,1-dimethyl-3-phenyltriazene. Collection of Czechoslovak Chemical Communications, 72(9), 1229-1243. https://doi.org/10.1135/cccc20071229

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AU - Marković, Dragan A.

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AB - Polarographic behavior of the genotoxic substance 1,1-dimethyl-3- phenyltriazene was investigated and optimum conditions were found for its determination by sampled direct current polarography and differential pulse polarography at a static mercury drop electrode in the concentration range from 1 × 10-4 to 1 × 10-7 mol l-1. It was established that for reduction of the triazene group four electrons are required resulting in the formation of amino and hydrazo compound. The resulting products were identified, and the reduction pathway was proposed.

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KW - Triazenes

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Access to Document

10.1135/cccc20071229