Polarographic behavior and determination of 1,1-dimethyl-3-phenyltriazene

Abstract

Polarographic behavior of the genotoxic substance 1,1-dimethyl-3- phenyltriazene was investigated and optimum conditions were found for its determination by sampled direct current polarography and differential pulse polarography at a static mercury drop electrode in the concentration range from 1 × 10^-4 to 1 × 10^-7 mol l^-1. It was established that for reduction of the triazene group four electrons are required resulting in the formation of amino and hydrazo compound. The resulting products were identified, and the reduction pathway was proposed.

Original language	English
Pages (from-to)	1229-1243
Number of pages	15
Journal	Collection of Czechoslovak Chemical Communications
Volume	72
Issue number	9
DOIs	https://doi.org/10.1135/cccc20071229
Publication status	Published - 1 Sep 2007
Externally published	Yes

Keywords

Carcinogens
Electroreductions
Polarography
Reduction mechanism
Triazenes

ASJC Scopus subject areas

Chemistry(all)

Access to Document

10.1135/cccc20071229

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@article{0d86036cc7974fbeb28febbd4135f9dc,

title = "Polarographic behavior and determination of 1,1-dimethyl-3-phenyltriazene",

abstract = "Polarographic behavior of the genotoxic substance 1,1-dimethyl-3- phenyltriazene was investigated and optimum conditions were found for its determination by sampled direct current polarography and differential pulse polarography at a static mercury drop electrode in the concentration range from 1 × 10-4 to 1 × 10-7 mol l-1. It was established that for reduction of the triazene group four electrons are required resulting in the formation of amino and hydrazo compound. The resulting products were identified, and the reduction pathway was proposed.",

keywords = "Carcinogens, Electroreductions, Polarography, Reduction mechanism, Triazenes",

author = "Ignjatovi{\'c}, {Ljubi{\v s}a M.} and Ji{\v r}{\'i} Barek and Ji{\v r}{\'i} Zima and Markovi{\'c}, {Dragan A.}",

year = "2007",

month = sep,

day = "1",

doi = "10.1135/cccc20071229",

language = "English",

volume = "72",

pages = "1229--1243",

journal = "Collection of Czechoslovak Chemical Communications",

issn = "0010-0765",

publisher = "Czech Academy of Sciences",

number = "9",

}

TY - JOUR

T1 - Polarographic behavior and determination of 1,1-dimethyl-3-phenyltriazene

AU - Ignjatović, Ljubiša M.

AU - Barek, Jiří

AU - Zima, Jiří

AU - Marković, Dragan A.

PY - 2007/9/1

Y1 - 2007/9/1

N2 - Polarographic behavior of the genotoxic substance 1,1-dimethyl-3- phenyltriazene was investigated and optimum conditions were found for its determination by sampled direct current polarography and differential pulse polarography at a static mercury drop electrode in the concentration range from 1 × 10-4 to 1 × 10-7 mol l-1. It was established that for reduction of the triazene group four electrons are required resulting in the formation of amino and hydrazo compound. The resulting products were identified, and the reduction pathway was proposed.

AB - Polarographic behavior of the genotoxic substance 1,1-dimethyl-3- phenyltriazene was investigated and optimum conditions were found for its determination by sampled direct current polarography and differential pulse polarography at a static mercury drop electrode in the concentration range from 1 × 10-4 to 1 × 10-7 mol l-1. It was established that for reduction of the triazene group four electrons are required resulting in the formation of amino and hydrazo compound. The resulting products were identified, and the reduction pathway was proposed.

KW - Carcinogens

KW - Electroreductions

KW - Polarography

KW - Reduction mechanism

KW - Triazenes

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U2 - 10.1135/cccc20071229

DO - 10.1135/cccc20071229

M3 - Article

AN - SCOPUS:36849024303

VL - 72

SP - 1229

EP - 1243

JO - Collection of Czechoslovak Chemical Communications

JF - Collection of Czechoslovak Chemical Communications

SN - 0010-0765

IS - 9

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