Polarographic and voltammetric determination of selected nitrated polycyclic aromatic hydrocarbons

Jiří Barek, Martin Pumera, Alexandr Muck, Milena Kadeřábková, Jiří Zima

Research output: Contribution to journalArticle

33 Citations (Scopus)

Abstract

The use of differential pulse polarography, differential pulse voltammetry and adsorptive stripping voltammetry for the determination of trace amounts of selected nitrated polycyclic aromatic hydrocarbons (1-nitropyrene, 9-nitroanthracene, 2-nitrofluorene and 2,7-dinitrofluorene were chosen as model substances) were studied. The influence of pH and the composition of the base electrolyte on the polarographic and voltammetric behaviour of these substances was investigated and the optimum conditions for their determination in the concentration range of 1x10-4-1x10-9moll-1 were found. Practical applicability of these methods was demonstrated on the determination of trace amounts of selected chemical carcinogens in river water and on monitoring the chemical destruction of the test substances. Copyright (C) 1999 Elsevier Science B.V.

Original languageEnglish
Pages (from-to)141-146
Number of pages6
JournalAnalytica Chimica Acta
Volume393
Issue number1-3
DOIs
Publication statusPublished - 30 Jun 1999
Externally publishedYes

Fingerprint

1-nitropyrene
Polarography
Polycyclic Aromatic Hydrocarbons
Base Composition
Voltammetry
Rivers
Carcinogens
Electrolytes
PAH
Polarographic analysis
Water
carcinogen
electrolyte
river water
Monitoring
monitoring
Chemical analysis
2,7-dinitrofluorene
9-nitroanthracene
2-nitrofluorene

Keywords

  • Adsorptive stripping voltammetry
  • Differential pulse polarography
  • Differential pulse voltammetry
  • Nitrated polycyclic aromatic hydrocarbons

ASJC Scopus subject areas

  • Analytical Chemistry
  • Biochemistry
  • Environmental Chemistry
  • Spectroscopy

Cite this

Polarographic and voltammetric determination of selected nitrated polycyclic aromatic hydrocarbons. / Barek, Jiří; Pumera, Martin; Muck, Alexandr; Kadeřábková, Milena; Zima, Jiří.

In: Analytica Chimica Acta, Vol. 393, No. 1-3, 30.06.1999, p. 141-146.

Research output: Contribution to journalArticle

Barek, Jiří ; Pumera, Martin ; Muck, Alexandr ; Kadeřábková, Milena ; Zima, Jiří. / Polarographic and voltammetric determination of selected nitrated polycyclic aromatic hydrocarbons. In: Analytica Chimica Acta. 1999 ; Vol. 393, No. 1-3. pp. 141-146.
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