Abstract
The polarographic and voltammetric behaviour was studied for 4,4′-bis[(4-diethanolamino-6-(2,5-disulfophenylamino)-1,3,5-triazin-2-yl) amino]stilbene-2,2′-disulfonic acid, which is the basis of many commercial optical whitening agents. The optimum conditions were found for quantitation of this substance in tetraethylammonium bromide solutions in dimethylformamide containing 5% (v/v) water using TAST polarography, differential pulse polarography, linear sweep voltammetry at a hanging mercury drop electrode, and differential pulse voltammetry at a hanging mercury drop electrode over the concentration regions of 100-500, 10-500, 10-500, and 1-100 μmol 1-1, respectively. The practical applicability of the new analytical methods to the determination of the substance in technical products was verified.
| Original language | English |
|---|---|
| Pages (from-to) | 663-672 |
| Number of pages | 10 |
| Journal | Collection of Czechoslovak Chemical Communications |
| Volume | 61 |
| Issue number | 5 |
| DOIs | |
| Publication status | Published - 1 May 1996 |
| Externally published | Yes |
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Keywords
- 4,4′-Bis[(4-diethanolamino-6-(2,5-disulfophenylamino)-1,3,5-triazin-2-yl) amino]stilbene-2,2′-disulfonic acid
- Optical brightening agents
- Polarography
- Voltammetry
ASJC Scopus subject areas
- Chemistry(all)
Cite this
Polarographic and voltammetric determination of 4,4′-bis[(4-diethanolamino-6-(2,5-disulfophenylamino)-1,3,5-triazin-2-yl) amino]stilbene-2,2′-disulfonic acid. / Barek, Jiří; Hrnčíř, Roman; Moreira, Josino C.; Zima, Jiří.
In: Collection of Czechoslovak Chemical Communications, Vol. 61, No. 5, 01.05.1996, p. 663-672.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Polarographic and voltammetric determination of 4,4′-bis[(4-diethanolamino-6-(2,5-disulfophenylamino)-1,3,5-triazin-2-yl) amino]stilbene-2,2′-disulfonic acid
AU - Barek, Jiří
AU - Hrnčíř, Roman
AU - Moreira, Josino C.
AU - Zima, Jiří
PY - 1996/5/1
Y1 - 1996/5/1
N2 - The polarographic and voltammetric behaviour was studied for 4,4′-bis[(4-diethanolamino-6-(2,5-disulfophenylamino)-1,3,5-triazin-2-yl) amino]stilbene-2,2′-disulfonic acid, which is the basis of many commercial optical whitening agents. The optimum conditions were found for quantitation of this substance in tetraethylammonium bromide solutions in dimethylformamide containing 5% (v/v) water using TAST polarography, differential pulse polarography, linear sweep voltammetry at a hanging mercury drop electrode, and differential pulse voltammetry at a hanging mercury drop electrode over the concentration regions of 100-500, 10-500, 10-500, and 1-100 μmol 1-1, respectively. The practical applicability of the new analytical methods to the determination of the substance in technical products was verified.
AB - The polarographic and voltammetric behaviour was studied for 4,4′-bis[(4-diethanolamino-6-(2,5-disulfophenylamino)-1,3,5-triazin-2-yl) amino]stilbene-2,2′-disulfonic acid, which is the basis of many commercial optical whitening agents. The optimum conditions were found for quantitation of this substance in tetraethylammonium bromide solutions in dimethylformamide containing 5% (v/v) water using TAST polarography, differential pulse polarography, linear sweep voltammetry at a hanging mercury drop electrode, and differential pulse voltammetry at a hanging mercury drop electrode over the concentration regions of 100-500, 10-500, 10-500, and 1-100 μmol 1-1, respectively. The practical applicability of the new analytical methods to the determination of the substance in technical products was verified.
KW - 4,4′-Bis[(4-diethanolamino-6-(2,5-disulfophenylamino)-1,3,5-triazin-2-yl) amino]stilbene-2,2′-disulfonic acid
KW - Optical brightening agents
KW - Polarography
KW - Voltammetry
UR - http://www.scopus.com/inward/record.url?scp=0030548287&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0030548287&partnerID=8YFLogxK
U2 - 10.1135/cccc19960663
DO - 10.1135/cccc19960663
M3 - Article
VL - 61
SP - 663
EP - 672
JO - Collection of Czechoslovak Chemical Communications
JF - Collection of Czechoslovak Chemical Communications
SN - 0010-0765
IS - 5
ER -