Plasma dynamic synthesis of iron oxides in a discharge plasma jet with possibility to control final phase composition

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Abstract

Magnetite Fe3O4 and epsilon iron oxide -Fe2O3, having excellent frequency characteristics and high electrical resistivity, are considered as the most promising phases among all iron oxides for high-frequency equipment in order to increase the working frequency of the data transmission. Despite the large number of existing methods for synthesizing these materials, many of them do not provide both of these phases. In opposite to these methods, the plasma dynamic synthesis can provide the synthesis of necessary phases in a one-step process. The process is implemented in an electrodischarge iron-containing plasma jet, which interacts with gaseous precursor (oxygen). The use of plasma jet allows obtaining nanoscale powdered products. This work shows the results of the experiment series, where the influence of initial energy parameters on the final phase composition was studied. It is found that the plasma dynamic synthesis allows obtaining both magnetite Fe3O4 and epsilon phase -Fe2O3 during one short-term process (less than 1 ms). It is also established that the final phase composition strongly depends on the initial parameters of the system. The increased energy parameters lead to the formation of the product with predominant content of epsilon phase, while lower parameters allow synthesizing magnetite phase. Thus, by changing energy parameters, it is possible to control the final composition in the considered system.

Original languageEnglish
Article number012116
JournalJournal of Physics: Conference Series
Volume830
Issue number1
DOIs
Publication statusPublished - 4 May 2017
Event5th International Congress on Energy Fluxes and Radiation Effects 2016, EFRE 2016 - Tomsk, Russian Federation
Duration: 2 Oct 20167 Oct 2016

ASJC Scopus subject areas

  • Physics and Astronomy(all)

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