Plasma chemical conversion of sulphur hexafluoride initiated by a pulsed electron beam

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

This paper presents the results of the experimental investigation of plasma chemical conversion of sulphur hexafluoride initiated by a pulsed electron beam (TEA-500 pulsed electron accelerator) with the following characteristics: 400–450 keV electron energy, 60 ns pulse duration, up to 200 J pulse energy, and 5 cm beam diameter. Experiments were conducted on the effect of the pulsed electron beam on SF6 and on mixtures of SF6 with O2, Ar, or N2. For the mixture of SF6 and oxygen, the results indicated chemical reactions involving the formation of a number of products of which one is sulphur, confirming the Wray – Fluorescence Analysis. The plasma chemical conversion of SF6 initiated by the pulsed electron beam was not detected when SF6 was mixed with Ar or N2, suggesting a possible mechanism for the reaction of SF6 in the presence of O2.

Original languageEnglish
Pages (from-to)273-276
Number of pages4
JournalRadiation Physics and Chemistry
Volume130
DOIs
Publication statusPublished - 1 Jan 2017

Fingerprint

sulfur hexafluoride
electron beams
electron accelerators
chemical reactions
pulse duration
sulfur
electron energy
fluorescence
oxygen
products
pulses
energy

Keywords

  • Plasma chemical conversion
  • Pulsed electron beam
  • SF, sulphur
  • UF

ASJC Scopus subject areas

  • Radiation

Cite this

@article{1da9f3b29cfb41aca6fe424eb8a3de3d,
title = "Plasma chemical conversion of sulphur hexafluoride initiated by a pulsed electron beam",
abstract = "This paper presents the results of the experimental investigation of plasma chemical conversion of sulphur hexafluoride initiated by a pulsed electron beam (TEA-500 pulsed electron accelerator) with the following characteristics: 400–450 keV electron energy, 60 ns pulse duration, up to 200 J pulse energy, and 5 cm beam diameter. Experiments were conducted on the effect of the pulsed electron beam on SF6 and on mixtures of SF6 with O2, Ar, or N2. For the mixture of SF6 and oxygen, the results indicated chemical reactions involving the formation of a number of products of which one is sulphur, confirming the Wray – Fluorescence Analysis. The plasma chemical conversion of SF6 initiated by the pulsed electron beam was not detected when SF6 was mixed with Ar or N2, suggesting a possible mechanism for the reaction of SF6 in the presence of O2.",
keywords = "Plasma chemical conversion, Pulsed electron beam, SF, sulphur, UF",
author = "Galina Kholodnaya and Roman Sazonov and Denis Vladimirovich Ponomarev and Tatiana Guzeeva",
year = "2017",
month = "1",
day = "1",
doi = "10.1016/j.radphyschem.2016.08.018",
language = "English",
volume = "130",
pages = "273--276",
journal = "Radiation Physics and Chemistry",
issn = "0969-806X",
publisher = "Elsevier Limited",

}

TY - JOUR

T1 - Plasma chemical conversion of sulphur hexafluoride initiated by a pulsed electron beam

AU - Kholodnaya, Galina

AU - Sazonov, Roman

AU - Ponomarev, Denis Vladimirovich

AU - Guzeeva, Tatiana

PY - 2017/1/1

Y1 - 2017/1/1

N2 - This paper presents the results of the experimental investigation of plasma chemical conversion of sulphur hexafluoride initiated by a pulsed electron beam (TEA-500 pulsed electron accelerator) with the following characteristics: 400–450 keV electron energy, 60 ns pulse duration, up to 200 J pulse energy, and 5 cm beam diameter. Experiments were conducted on the effect of the pulsed electron beam on SF6 and on mixtures of SF6 with O2, Ar, or N2. For the mixture of SF6 and oxygen, the results indicated chemical reactions involving the formation of a number of products of which one is sulphur, confirming the Wray – Fluorescence Analysis. The plasma chemical conversion of SF6 initiated by the pulsed electron beam was not detected when SF6 was mixed with Ar or N2, suggesting a possible mechanism for the reaction of SF6 in the presence of O2.

AB - This paper presents the results of the experimental investigation of plasma chemical conversion of sulphur hexafluoride initiated by a pulsed electron beam (TEA-500 pulsed electron accelerator) with the following characteristics: 400–450 keV electron energy, 60 ns pulse duration, up to 200 J pulse energy, and 5 cm beam diameter. Experiments were conducted on the effect of the pulsed electron beam on SF6 and on mixtures of SF6 with O2, Ar, or N2. For the mixture of SF6 and oxygen, the results indicated chemical reactions involving the formation of a number of products of which one is sulphur, confirming the Wray – Fluorescence Analysis. The plasma chemical conversion of SF6 initiated by the pulsed electron beam was not detected when SF6 was mixed with Ar or N2, suggesting a possible mechanism for the reaction of SF6 in the presence of O2.

KW - Plasma chemical conversion

KW - Pulsed electron beam

KW - SF, sulphur

KW - UF

UR - http://www.scopus.com/inward/record.url?scp=84987994738&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84987994738&partnerID=8YFLogxK

U2 - 10.1016/j.radphyschem.2016.08.018

DO - 10.1016/j.radphyschem.2016.08.018

M3 - Article

VL - 130

SP - 273

EP - 276

JO - Radiation Physics and Chemistry

JF - Radiation Physics and Chemistry

SN - 0969-806X

ER -