Plasma chemical conversion of sulphur hexafluoride initiated by a pulsed electron beam

Abstract

This paper presents the results of the experimental investigation of plasma chemical conversion of sulphur hexafluoride initiated by a pulsed electron beam (TEA-500 pulsed electron accelerator) with the following characteristics: 400–450 keV electron energy, 60 ns pulse duration, up to 200 J pulse energy, and 5 cm beam diameter. Experiments were conducted on the effect of the pulsed electron beam on SF₆ and on mixtures of SF₆ with O₂, Ar, or N₂. For the mixture of SF₆ and oxygen, the results indicated chemical reactions involving the formation of a number of products of which one is sulphur, confirming the Wray – Fluorescence Analysis. The plasma chemical conversion of SF₆ initiated by the pulsed electron beam was not detected when SF₆ was mixed with Ar or N₂, suggesting a possible mechanism for the reaction of SF6 in the presence of O₂.

Original language	English
Pages (from-to)	273-276
Number of pages	4
Journal	Radiation Physics and Chemistry
Volume	130
DOIs	https://doi.org/10.1016/j.radphyschem.2016.08.018
Publication status	Published - 1 Jan 2017

Keywords

Plasma chemical conversion
Pulsed electron beam
SF, sulphur
UF

ASJC Scopus subject areas

Radiation

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10.1016/j.radphyschem.2016.08.018

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title = "Plasma chemical conversion of sulphur hexafluoride initiated by a pulsed electron beam",

abstract = "This paper presents the results of the experimental investigation of plasma chemical conversion of sulphur hexafluoride initiated by a pulsed electron beam (TEA-500 pulsed electron accelerator) with the following characteristics: 400–450 keV electron energy, 60 ns pulse duration, up to 200 J pulse energy, and 5 cm beam diameter. Experiments were conducted on the effect of the pulsed electron beam on SF6 and on mixtures of SF6 with O2, Ar, or N2. For the mixture of SF6 and oxygen, the results indicated chemical reactions involving the formation of a number of products of which one is sulphur, confirming the Wray – Fluorescence Analysis. The plasma chemical conversion of SF6 initiated by the pulsed electron beam was not detected when SF6 was mixed with Ar or N2, suggesting a possible mechanism for the reaction of SF6 in the presence of O2.",

keywords = "Plasma chemical conversion, Pulsed electron beam, SF, sulphur, UF",

author = "Galina Kholodnaya and Roman Sazonov and Denis Vladimirovich Ponomarev and Tatiana Guzeeva",

year = "2017",

month = jan,

day = "1",

doi = "10.1016/j.radphyschem.2016.08.018",

language = "English",

volume = "130",

pages = "273--276",

journal = "Radiation Physics and Chemistry",

issn = "0969-806X",

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T1 - Plasma chemical conversion of sulphur hexafluoride initiated by a pulsed electron beam

AU - Kholodnaya, Galina

AU - Sazonov, Roman

AU - Ponomarev, Denis Vladimirovich

AU - Guzeeva, Tatiana

PY - 2017/1/1

Y1 - 2017/1/1

N2 - This paper presents the results of the experimental investigation of plasma chemical conversion of sulphur hexafluoride initiated by a pulsed electron beam (TEA-500 pulsed electron accelerator) with the following characteristics: 400–450 keV electron energy, 60 ns pulse duration, up to 200 J pulse energy, and 5 cm beam diameter. Experiments were conducted on the effect of the pulsed electron beam on SF6 and on mixtures of SF6 with O2, Ar, or N2. For the mixture of SF6 and oxygen, the results indicated chemical reactions involving the formation of a number of products of which one is sulphur, confirming the Wray – Fluorescence Analysis. The plasma chemical conversion of SF6 initiated by the pulsed electron beam was not detected when SF6 was mixed with Ar or N2, suggesting a possible mechanism for the reaction of SF6 in the presence of O2.

AB - This paper presents the results of the experimental investigation of plasma chemical conversion of sulphur hexafluoride initiated by a pulsed electron beam (TEA-500 pulsed electron accelerator) with the following characteristics: 400–450 keV electron energy, 60 ns pulse duration, up to 200 J pulse energy, and 5 cm beam diameter. Experiments were conducted on the effect of the pulsed electron beam on SF6 and on mixtures of SF6 with O2, Ar, or N2. For the mixture of SF6 and oxygen, the results indicated chemical reactions involving the formation of a number of products of which one is sulphur, confirming the Wray – Fluorescence Analysis. The plasma chemical conversion of SF6 initiated by the pulsed electron beam was not detected when SF6 was mixed with Ar or N2, suggesting a possible mechanism for the reaction of SF6 in the presence of O2.

KW - Plasma chemical conversion

KW - Pulsed electron beam

KW - SF, sulphur

KW - UF

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