Abstract
Composite metal–carbon materials are created on the basis of different kinds of carbon (multiwall carbon nanotubes, carbon black, Sibunit carbon–carbon material) and metals (Ag, Ni, Co), and their physicochemical and catalytic properties are investigated. It is shown that interaction between metals and carbon carriers proceeds not only with the functional groups on the surfaces of the carriers, but also through a system of–C–C–conjugated bonds. Silver deposited on the surface of a carbon carrier has a crystalline structure (dcr = 10–15 nm), while nickel has an amorphous lamellar structure. Based on quantum-chemical calculations using the density functional theory, it is shown that cumene oxidation occurs via a homogeneous–heterogeneous mechanism.
| Original language | English |
|---|---|
| Pages (from-to) | 1197-1203 |
| Number of pages | 7 |
| Journal | Russian Journal of Physical Chemistry A |
| Volume | 91 |
| Issue number | 7 |
| DOIs | |
| Publication status | Published - 1 Jul 2017 |
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Keywords
- carbon black
- carbon nanotubes
- catalytic activity
- composite materials
- Sibunit
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
Cite this
Physicochemical properties and catalytic activity of metal–carbon carrier composite materials. / Kobotaeva, N. S.; Skorokhodova, T. S.; Razd’yakonova, G. I.; Poleshchuk, O. Kh.
In: Russian Journal of Physical Chemistry A, Vol. 91, No. 7, 01.07.2017, p. 1197-1203.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Physicochemical properties and catalytic activity of metal–carbon carrier composite materials
AU - Kobotaeva, N. S.
AU - Skorokhodova, T. S.
AU - Razd’yakonova, G. I.
AU - Poleshchuk, O. Kh
PY - 2017/7/1
Y1 - 2017/7/1
N2 - Composite metal–carbon materials are created on the basis of different kinds of carbon (multiwall carbon nanotubes, carbon black, Sibunit carbon–carbon material) and metals (Ag, Ni, Co), and their physicochemical and catalytic properties are investigated. It is shown that interaction between metals and carbon carriers proceeds not only with the functional groups on the surfaces of the carriers, but also through a system of–C–C–conjugated bonds. Silver deposited on the surface of a carbon carrier has a crystalline structure (dcr = 10–15 nm), while nickel has an amorphous lamellar structure. Based on quantum-chemical calculations using the density functional theory, it is shown that cumene oxidation occurs via a homogeneous–heterogeneous mechanism.
AB - Composite metal–carbon materials are created on the basis of different kinds of carbon (multiwall carbon nanotubes, carbon black, Sibunit carbon–carbon material) and metals (Ag, Ni, Co), and their physicochemical and catalytic properties are investigated. It is shown that interaction between metals and carbon carriers proceeds not only with the functional groups on the surfaces of the carriers, but also through a system of–C–C–conjugated bonds. Silver deposited on the surface of a carbon carrier has a crystalline structure (dcr = 10–15 nm), while nickel has an amorphous lamellar structure. Based on quantum-chemical calculations using the density functional theory, it is shown that cumene oxidation occurs via a homogeneous–heterogeneous mechanism.
KW - carbon black
KW - carbon nanotubes
KW - catalytic activity
KW - composite materials
KW - Sibunit
UR - http://www.scopus.com/inward/record.url?scp=85020819201&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85020819201&partnerID=8YFLogxK
U2 - 10.1134/S0036024417070172
DO - 10.1134/S0036024417070172
M3 - Article
VL - 91
SP - 1197
EP - 1203
JO - Russian Journal of Physical Chemistry A
JF - Russian Journal of Physical Chemistry A
SN - 0036-0244
IS - 7
ER -