Abstract
Photonics of cyanine dyes of different ionicity in matrices of halogen-containing derivatives of PEPC polymers were studied. It was shown that in the presence of heavy atoms the intensity of both the fast and delayed fluorescence of the dyes is lower in comparison with the polymer matrix without atoms I or Br. The presence of heavy atoms in the structure of polymers leads to the appearance or enhancement of the phosphorescence of dyes due to an increase in the spin-orbit interaction in the dye molecule and an increase in the rate of singlet-triplet transitions in the presence of a polymer with a large number of heavy atoms.
| Original language | English |
|---|---|
| Title of host publication | Proceedings of the 2017 IEEE 7th International Conference on Nanomaterials |
| Subtitle of host publication | Applications and Properties, NAP 2017 |
| Publisher | Institute of Electrical and Electronics Engineers Inc. |
| ISBN (Electronic) | 9781538628102 |
| DOIs | |
| Publication status | Published - 12 Dec 2017 |
| Externally published | Yes |
| Event | 7th IEEE International Conference on Nanomaterials: Applications and Properties, NAP 2017 - Zatoka, Ukraine Duration: 10 Sep 2017 → 15 Sep 2017 |
Publication series
| Name | Proceedings of the 2017 IEEE 7th International Conference on Nanomaterials: Applications and Properties, NAP 2017 |
|---|---|
| Volume | 2017-January |
Conference
| Conference | 7th IEEE International Conference on Nanomaterials: Applications and Properties, NAP 2017 |
|---|---|
| Country | Ukraine |
| City | Zatoka |
| Period | 10.9.17 → 15.9.17 |
Fingerprint
Keywords
- Cyanine dyes
- PEPC
- Photonics
- Polymer films
- Spin-orbot interaction
ASJC Scopus subject areas
- Materials Science (miscellaneous)
- Mechanics of Materials
Cite this
Photonics of cyanine dyes of different ionicity in matrices of halogen-containing derivatives of PEPC. / Ibrayev, N. Kh; Seliverstova, E.; Afanasyev, D.; Nurmakhanova, A.; Davidenko, N. A.; Ishchenko, A. A.
Proceedings of the 2017 IEEE 7th International Conference on Nanomaterials: Applications and Properties, NAP 2017. Institute of Electrical and Electronics Engineers Inc., 2017. 8190246 (Proceedings of the 2017 IEEE 7th International Conference on Nanomaterials: Applications and Properties, NAP 2017; Vol. 2017-January).Research output: Chapter in Book/Report/Conference proceeding › Conference contribution
}
TY - GEN
T1 - Photonics of cyanine dyes of different ionicity in matrices of halogen-containing derivatives of PEPC
AU - Ibrayev, N. Kh
AU - Seliverstova, E.
AU - Afanasyev, D.
AU - Nurmakhanova, A.
AU - Davidenko, N. A.
AU - Ishchenko, A. A.
PY - 2017/12/12
Y1 - 2017/12/12
N2 - Photonics of cyanine dyes of different ionicity in matrices of halogen-containing derivatives of PEPC polymers were studied. It was shown that in the presence of heavy atoms the intensity of both the fast and delayed fluorescence of the dyes is lower in comparison with the polymer matrix without atoms I or Br. The presence of heavy atoms in the structure of polymers leads to the appearance or enhancement of the phosphorescence of dyes due to an increase in the spin-orbit interaction in the dye molecule and an increase in the rate of singlet-triplet transitions in the presence of a polymer with a large number of heavy atoms.
AB - Photonics of cyanine dyes of different ionicity in matrices of halogen-containing derivatives of PEPC polymers were studied. It was shown that in the presence of heavy atoms the intensity of both the fast and delayed fluorescence of the dyes is lower in comparison with the polymer matrix without atoms I or Br. The presence of heavy atoms in the structure of polymers leads to the appearance or enhancement of the phosphorescence of dyes due to an increase in the spin-orbit interaction in the dye molecule and an increase in the rate of singlet-triplet transitions in the presence of a polymer with a large number of heavy atoms.
KW - Cyanine dyes
KW - PEPC
KW - Photonics
KW - Polymer films
KW - Spin-orbot interaction
UR - http://www.scopus.com/inward/record.url?scp=85046273624&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85046273624&partnerID=8YFLogxK
U2 - 10.1109/NAP.2017.8190246
DO - 10.1109/NAP.2017.8190246
M3 - Conference contribution
AN - SCOPUS:85046273624
T3 - Proceedings of the 2017 IEEE 7th International Conference on Nanomaterials: Applications and Properties, NAP 2017
BT - Proceedings of the 2017 IEEE 7th International Conference on Nanomaterials
PB - Institute of Electrical and Electronics Engineers Inc.
ER -