Photochemical reaction of the heterometallic complex (μ-H)Os₃{μ-O₂CC₅H₄Mn(CO)₃}(CO)₁₀ with triphenylphosphine

V. A. Maksakov, I. V. Slovokhotova, S. P. Babailov

Research output: Contribution to journal › Article

Abstract

Photolysis of the heterometallic complex (μ-H)Os₃{μ-O₂CC₅H₄Mn(CO)₃}(CO)₁₀ together with PPh₃ results in replacement of the CO groups by PPh₃ both at the Mn atom and in the Os₃ metallocycle to afford the complexes (μ-H)Os₃{μ-O₂CC₅H₄Mn(CO)₂PPh₃}(CO)₁₀, (μ-H)Os₃{μ-O₂CC₅H₄Mn(CO)₃}(CO)₉PPh₃, and (μ-H)Os₃{μ-O₂CC₅H₄Mn(CO)₂PPh₃)(CO)₉PPh₃ (two isomers). The reaction is also accompanied by the partial removal of the Mn(CO)₃ group followed by the protonation of the cyclopentadienyl group and formation of triosmium clusters (μ-H)Os₃(μ-O₂CC₅H₄R}(CO)_{1 0} (R = H, Et).

Original language	English
Pages (from-to)	747-752
Number of pages	6
Journal	Russian Chemical Bulletin
Volume	49
Issue number	4
DOIs	https://doi.org/10.1007/BF02495496
Publication status	Published - Apr 2000

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Photochemical reactions

Carbon Monoxide

triphenylphosphine

Protonation

Photolysis

Isomers

Atoms

Keywords

Heterometallic OsMn complexes
Photochemical reaction
Replacement of CO ligands by PPh

ASJC Scopus subject areas

Chemistry(all)

Cite this

Maksakov, V. A., Slovokhotova, I. V., & Babailov, S. P. (2000). Photochemical reaction of the heterometallic complex (μ-H)Os₃{μ-O₂CC₅H₄Mn(CO)₃}(CO)₁₀ with triphenylphosphine. Russian Chemical Bulletin, 49(4), 747-752. https://doi.org/10.1007/BF02495496

Photochemical reaction of the heterometallic complex (μ-H)Os₃{μ-O₂CC₅H₄Mn(CO)₃}(CO)₁₀ with triphenylphosphine. / Maksakov, V. A.; Slovokhotova, I. V.; Babailov, S. P.

In: Russian Chemical Bulletin, Vol. 49, No. 4, 04.2000, p. 747-752.

Research output: Contribution to journal › Article

Maksakov, VA, Slovokhotova, IV & Babailov, SP 2000, 'Photochemical reaction of the heterometallic complex (μ-H)Os₃{μ-O₂CC₅H₄Mn(CO)₃}(CO)₁₀ with triphenylphosphine', Russian Chemical Bulletin, vol. 49, no. 4, pp. 747-752. https://doi.org/10.1007/BF02495496

Maksakov VA, Slovokhotova IV, Babailov SP. Photochemical reaction of the heterometallic complex (μ-H)Os₃{μ-O₂CC₅H₄Mn(CO)₃}(CO)₁₀ with triphenylphosphine. Russian Chemical Bulletin. 2000 Apr;49(4):747-752. https://doi.org/10.1007/BF02495496

Maksakov, V. A. ; Slovokhotova, I. V. ; Babailov, S. P. / Photochemical reaction of the heterometallic complex (μ-H)Os₃{μ-O₂CC₅H₄Mn(CO)₃}(CO)₁₀ with triphenylphosphine. In: Russian Chemical Bulletin. 2000 ; Vol. 49, No. 4. pp. 747-752.

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title = "Photochemical reaction of the heterometallic complex (μ-H)Os3{μ-O2CC5H4Mn(CO)3 }(CO)10 with triphenylphosphine",

abstract = "Photolysis of the heterometallic complex (μ-H)Os3{μ-O2CC5H4Mn(CO)3 }(CO)10 together with PPh3 results in replacement of the CO groups by PPh3 both at the Mn atom and in the Os3 metallocycle to afford the complexes (μ-H)Os3{μ-O2CC5H4Mn(CO)2 PPh3}(CO)10, (μ-H)Os3{μ-O2CC5H4Mn(CO)3 }(CO)9PPh3, and (μ-H)Os3{μ-O2CC5H4Mn(CO)2 PPh3)(CO)9PPh3 (two isomers). The reaction is also accompanied by the partial removal of the Mn(CO)3 group followed by the protonation of the cyclopentadienyl group and formation of triosmium clusters (μ-H)Os3(μ-O2CC5H4R}(CO)1 0 (R = H, Et).",

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AU - Maksakov, V. A.

AU - Slovokhotova, I. V.

AU - Babailov, S. P.

PY - 2000/4

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N2 - Photolysis of the heterometallic complex (μ-H)Os3{μ-O2CC5H4Mn(CO)3 }(CO)10 together with PPh3 results in replacement of the CO groups by PPh3 both at the Mn atom and in the Os3 metallocycle to afford the complexes (μ-H)Os3{μ-O2CC5H4Mn(CO)2 PPh3}(CO)10, (μ-H)Os3{μ-O2CC5H4Mn(CO)3 }(CO)9PPh3, and (μ-H)Os3{μ-O2CC5H4Mn(CO)2 PPh3)(CO)9PPh3 (two isomers). The reaction is also accompanied by the partial removal of the Mn(CO)3 group followed by the protonation of the cyclopentadienyl group and formation of triosmium clusters (μ-H)Os3(μ-O2CC5H4R}(CO)1 0 (R = H, Et).

AB - Photolysis of the heterometallic complex (μ-H)Os3{μ-O2CC5H4Mn(CO)3 }(CO)10 together with PPh3 results in replacement of the CO groups by PPh3 both at the Mn atom and in the Os3 metallocycle to afford the complexes (μ-H)Os3{μ-O2CC5H4Mn(CO)2 PPh3}(CO)10, (μ-H)Os3{μ-O2CC5H4Mn(CO)3 }(CO)9PPh3, and (μ-H)Os3{μ-O2CC5H4Mn(CO)2 PPh3)(CO)9PPh3 (two isomers). The reaction is also accompanied by the partial removal of the Mn(CO)3 group followed by the protonation of the cyclopentadienyl group and formation of triosmium clusters (μ-H)Os3(μ-O2CC5H4R}(CO)1 0 (R = H, Et).

KW - Heterometallic OsMn complexes

KW - Photochemical reaction

KW - Replacement of CO ligands by PPh

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10.1007/BF02495496