Pd(NH3)4MoO4 as a precursor for Pd-Mo-containing catalysts: Thermal behavior, X-ray analysis of the thermolysis products and related catalytic studies

Alexander I. Gubanov, Eugeny Yu Filatov, Eugeny Yu Semitut, Anton I. Smolentsev, Pavel V. Snytnikov, Dmitry I. Potemkin, Sergey V. Korenev

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Compound [Pd(NH3)4]MoO4 (1) has been synthesized and characterized by IR spectroscopy, analytical data, powder and single-crystal X-ray crystallography. Thermal properties of 1 have been examined by thermogravimetry. Powder X-ray diffraction has been applied to investigate the nanosized products of thermal decomposition of the precursor in hydrogen (Pd-Mo) and helium (Pd-MoO2) atmospheres. Pd-Mo catalysts supported with γ-Al2O3 have been tested in oxidation of CO and H2 mixtures.

Original languageEnglish
Pages (from-to)100-104
Number of pages5
JournalThermochimica Acta
Volume566
DOIs
Publication statusPublished - 2013
Externally publishedYes

Fingerprint

Helium
Thermolysis
X ray crystallography
X ray analysis
Carbon Monoxide
Catalyst supports
Powders
X ray powder diffraction
Thermogravimetric analysis
Hydrogen
Infrared spectroscopy
Pyrolysis
Thermodynamic properties
Single crystals
catalysts
Oxidation
Catalysts
products
thermogravimetry
crystallography

Keywords

  • Catalysis
  • Pd-Mo nanoalloy
  • Tetraamminepalladium(II) molybdate
  • Thermal behavior

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Condensed Matter Physics
  • Instrumentation

Cite this

Gubanov, A. I., Filatov, E. Y., Semitut, E. Y., Smolentsev, A. I., Snytnikov, P. V., Potemkin, D. I., & Korenev, S. V. (2013). Pd(NH3)4MoO4 as a precursor for Pd-Mo-containing catalysts: Thermal behavior, X-ray analysis of the thermolysis products and related catalytic studies. Thermochimica Acta, 566, 100-104. https://doi.org/10.1016/j.tca.2013.03.036

Pd(NH3)4MoO4 as a precursor for Pd-Mo-containing catalysts : Thermal behavior, X-ray analysis of the thermolysis products and related catalytic studies. / Gubanov, Alexander I.; Filatov, Eugeny Yu; Semitut, Eugeny Yu; Smolentsev, Anton I.; Snytnikov, Pavel V.; Potemkin, Dmitry I.; Korenev, Sergey V.

In: Thermochimica Acta, Vol. 566, 2013, p. 100-104.

Research output: Contribution to journalArticle

Gubanov, Alexander I. ; Filatov, Eugeny Yu ; Semitut, Eugeny Yu ; Smolentsev, Anton I. ; Snytnikov, Pavel V. ; Potemkin, Dmitry I. ; Korenev, Sergey V. / Pd(NH3)4MoO4 as a precursor for Pd-Mo-containing catalysts : Thermal behavior, X-ray analysis of the thermolysis products and related catalytic studies. In: Thermochimica Acta. 2013 ; Vol. 566. pp. 100-104.
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AU - Smolentsev, Anton I.

AU - Snytnikov, Pavel V.

AU - Potemkin, Dmitry I.

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