Pd(NH3)4MoO4 as a precursor for Pd-Mo-containing catalysts: Thermal behavior, X-ray analysis of the thermolysis products and related catalytic studies

Abstract

Compound [Pd(NH₃)₄]MoO₄ (1) has been synthesized and characterized by IR spectroscopy, analytical data, powder and single-crystal X-ray crystallography. Thermal properties of 1 have been examined by thermogravimetry. Powder X-ray diffraction has been applied to investigate the nanosized products of thermal decomposition of the precursor in hydrogen (Pd-Mo) and helium (Pd-MoO₂) atmospheres. Pd-Mo catalysts supported with γ-Al₂O₃ have been tested in oxidation of CO and H₂ mixtures.

Original language	English
Pages (from-to)	100-104
Number of pages	5
Journal	Thermochimica Acta
Volume	566
DOIs	https://doi.org/10.1016/j.tca.2013.03.036
Publication status	Published - 2013
Externally published	Yes

Keywords

Catalysis
Pd-Mo nanoalloy
Tetraamminepalladium(II) molybdate
Thermal behavior

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Condensed Matter Physics
Instrumentation

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10.1016/j.tca.2013.03.036

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Pd(NH3)4MoO4 as a precursor for Pd-Mo-containing catalysts : Thermal behavior, X-ray analysis of the thermolysis products and related catalytic studies. / Gubanov, Alexander I.; Filatov, Eugeny Yu; Semitut, Eugeny Yu; Smolentsev, Anton I.; Snytnikov, Pavel V.; Potemkin, Dmitry I.; Korenev, Sergey V.

In: Thermochimica Acta, Vol. 566, 2013, p. 100-104.

Research output: Contribution to journal › Article › peer-review

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title = "Pd(NH3)4MoO4 as a precursor for Pd-Mo-containing catalysts: Thermal behavior, X-ray analysis of the thermolysis products and related catalytic studies",

abstract = "Compound [Pd(NH3)4]MoO4 (1) has been synthesized and characterized by IR spectroscopy, analytical data, powder and single-crystal X-ray crystallography. Thermal properties of 1 have been examined by thermogravimetry. Powder X-ray diffraction has been applied to investigate the nanosized products of thermal decomposition of the precursor in hydrogen (Pd-Mo) and helium (Pd-MoO2) atmospheres. Pd-Mo catalysts supported with γ-Al2O3 have been tested in oxidation of CO and H2 mixtures.",

keywords = "Catalysis, Pd-Mo nanoalloy, Tetraamminepalladium(II) molybdate, Thermal behavior",

author = "Gubanov, {Alexander I.} and Filatov, {Eugeny Yu} and Semitut, {Eugeny Yu} and Smolentsev, {Anton I.} and Snytnikov, {Pavel V.} and Potemkin, {Dmitry I.} and Korenev, {Sergey V.}",

year = "2013",

doi = "10.1016/j.tca.2013.03.036",

language = "English",

volume = "566",

pages = "100--104",

journal = "Thermochimica Acta",

issn = "0040-6031",

publisher = "Elsevier",

}

TY - JOUR

T1 - Pd(NH3)4MoO4 as a precursor for Pd-Mo-containing catalysts

T2 - Thermal behavior, X-ray analysis of the thermolysis products and related catalytic studies

AU - Gubanov, Alexander I.

AU - Filatov, Eugeny Yu

AU - Semitut, Eugeny Yu

AU - Smolentsev, Anton I.

AU - Snytnikov, Pavel V.

AU - Potemkin, Dmitry I.

AU - Korenev, Sergey V.

PY - 2013

Y1 - 2013

N2 - Compound [Pd(NH3)4]MoO4 (1) has been synthesized and characterized by IR spectroscopy, analytical data, powder and single-crystal X-ray crystallography. Thermal properties of 1 have been examined by thermogravimetry. Powder X-ray diffraction has been applied to investigate the nanosized products of thermal decomposition of the precursor in hydrogen (Pd-Mo) and helium (Pd-MoO2) atmospheres. Pd-Mo catalysts supported with γ-Al2O3 have been tested in oxidation of CO and H2 mixtures.

AB - Compound [Pd(NH3)4]MoO4 (1) has been synthesized and characterized by IR spectroscopy, analytical data, powder and single-crystal X-ray crystallography. Thermal properties of 1 have been examined by thermogravimetry. Powder X-ray diffraction has been applied to investigate the nanosized products of thermal decomposition of the precursor in hydrogen (Pd-Mo) and helium (Pd-MoO2) atmospheres. Pd-Mo catalysts supported with γ-Al2O3 have been tested in oxidation of CO and H2 mixtures.

KW - Catalysis

KW - Pd-Mo nanoalloy

KW - Tetraamminepalladium(II) molybdate

KW - Thermal behavior

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