Abstract
Compound [Pd(NH3)4]MoO4 (1) has been synthesized and characterized by IR spectroscopy, analytical data, powder and single-crystal X-ray crystallography. Thermal properties of 1 have been examined by thermogravimetry. Powder X-ray diffraction has been applied to investigate the nanosized products of thermal decomposition of the precursor in hydrogen (Pd-Mo) and helium (Pd-MoO2) atmospheres. Pd-Mo catalysts supported with γ-Al2O3 have been tested in oxidation of CO and H2 mixtures.
| Original language | English |
|---|---|
| Pages (from-to) | 100-104 |
| Number of pages | 5 |
| Journal | Thermochimica Acta |
| Volume | 566 |
| DOIs | |
| Publication status | Published - 2013 |
| Externally published | Yes |
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Keywords
- Catalysis
- Pd-Mo nanoalloy
- Tetraamminepalladium(II) molybdate
- Thermal behavior
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Condensed Matter Physics
- Instrumentation
Cite this
Pd(NH3)4MoO4 as a precursor for Pd-Mo-containing catalysts : Thermal behavior, X-ray analysis of the thermolysis products and related catalytic studies. / Gubanov, Alexander I.; Filatov, Eugeny Yu; Semitut, Eugeny Yu; Smolentsev, Anton I.; Snytnikov, Pavel V.; Potemkin, Dmitry I.; Korenev, Sergey V.
In: Thermochimica Acta, Vol. 566, 2013, p. 100-104.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Pd(NH3)4MoO4 as a precursor for Pd-Mo-containing catalysts
T2 - Thermal behavior, X-ray analysis of the thermolysis products and related catalytic studies
AU - Gubanov, Alexander I.
AU - Filatov, Eugeny Yu
AU - Semitut, Eugeny Yu
AU - Smolentsev, Anton I.
AU - Snytnikov, Pavel V.
AU - Potemkin, Dmitry I.
AU - Korenev, Sergey V.
PY - 2013
Y1 - 2013
N2 - Compound [Pd(NH3)4]MoO4 (1) has been synthesized and characterized by IR spectroscopy, analytical data, powder and single-crystal X-ray crystallography. Thermal properties of 1 have been examined by thermogravimetry. Powder X-ray diffraction has been applied to investigate the nanosized products of thermal decomposition of the precursor in hydrogen (Pd-Mo) and helium (Pd-MoO2) atmospheres. Pd-Mo catalysts supported with γ-Al2O3 have been tested in oxidation of CO and H2 mixtures.
AB - Compound [Pd(NH3)4]MoO4 (1) has been synthesized and characterized by IR spectroscopy, analytical data, powder and single-crystal X-ray crystallography. Thermal properties of 1 have been examined by thermogravimetry. Powder X-ray diffraction has been applied to investigate the nanosized products of thermal decomposition of the precursor in hydrogen (Pd-Mo) and helium (Pd-MoO2) atmospheres. Pd-Mo catalysts supported with γ-Al2O3 have been tested in oxidation of CO and H2 mixtures.
KW - Catalysis
KW - Pd-Mo nanoalloy
KW - Tetraamminepalladium(II) molybdate
KW - Thermal behavior
UR - http://www.scopus.com/inward/record.url?scp=84884522376&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84884522376&partnerID=8YFLogxK
U2 - 10.1016/j.tca.2013.03.036
DO - 10.1016/j.tca.2013.03.036
M3 - Article
AN - SCOPUS:84884522376
VL - 566
SP - 100
EP - 104
JO - Thermochimica Acta
JF - Thermochimica Acta
SN - 0040-6031
ER -