Pd(NH3)4MoO4 as a precursor for Pd-Mo-containing catalysts: Thermal behavior, X-ray analysis of the thermolysis products and related catalytic studies

Alexander I. Gubanov, Eugeny Yu Filatov, Eugeny Yu Semitut, Anton I. Smolentsev, Pavel V. Snytnikov, Dmitry I. Potemkin, Sergey V. Korenev

Research output: Contribution to journal › Article

3 Citations (Scopus)

Abstract

Compound [Pd(NH₃)₄]MoO₄ (1) has been synthesized and characterized by IR spectroscopy, analytical data, powder and single-crystal X-ray crystallography. Thermal properties of 1 have been examined by thermogravimetry. Powder X-ray diffraction has been applied to investigate the nanosized products of thermal decomposition of the precursor in hydrogen (Pd-Mo) and helium (Pd-MoO₂) atmospheres. Pd-Mo catalysts supported with γ-Al₂O₃ have been tested in oxidation of CO and H₂ mixtures.

Original language	English
Pages (from-to)	100-104
Number of pages	5
Journal	Thermochimica Acta
Volume	566
DOIs	https://doi.org/10.1016/j.tca.2013.03.036
Publication status	Published - 2013
Externally published	Yes

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Keywords

Catalysis
Pd-Mo nanoalloy
Tetraamminepalladium(II) molybdate
Thermal behavior

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Condensed Matter Physics
Instrumentation

Cite this

Gubanov, A. I., Filatov, E. Y., Semitut, E. Y., Smolentsev, A. I., Snytnikov, P. V., Potemkin, D. I., & Korenev, S. V. (2013). Pd(NH3)4MoO4 as a precursor for Pd-Mo-containing catalysts: Thermal behavior, X-ray analysis of the thermolysis products and related catalytic studies. Thermochimica Acta, 566, 100-104. https://doi.org/10.1016/j.tca.2013.03.036

Pd(NH3)4MoO4 as a precursor for Pd-Mo-containing catalysts : Thermal behavior, X-ray analysis of the thermolysis products and related catalytic studies. / Gubanov, Alexander I.; Filatov, Eugeny Yu; Semitut, Eugeny Yu; Smolentsev, Anton I.; Snytnikov, Pavel V.; Potemkin, Dmitry I.; Korenev, Sergey V.

In: Thermochimica Acta, Vol. 566, 2013, p. 100-104.

Research output: Contribution to journal › Article

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title = "Pd(NH3)4MoO4 as a precursor for Pd-Mo-containing catalysts: Thermal behavior, X-ray analysis of the thermolysis products and related catalytic studies",

abstract = "Compound [Pd(NH3)4]MoO4 (1) has been synthesized and characterized by IR spectroscopy, analytical data, powder and single-crystal X-ray crystallography. Thermal properties of 1 have been examined by thermogravimetry. Powder X-ray diffraction has been applied to investigate the nanosized products of thermal decomposition of the precursor in hydrogen (Pd-Mo) and helium (Pd-MoO2) atmospheres. Pd-Mo catalysts supported with γ-Al2O3 have been tested in oxidation of CO and H2 mixtures.",

keywords = "Catalysis, Pd-Mo nanoalloy, Tetraamminepalladium(II) molybdate, Thermal behavior",

author = "Gubanov, {Alexander I.} and Filatov, {Eugeny Yu} and Semitut, {Eugeny Yu} and Smolentsev, {Anton I.} and Snytnikov, {Pavel V.} and Potemkin, {Dmitry I.} and Korenev, {Sergey V.}",

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T1 - Pd(NH3)4MoO4 as a precursor for Pd-Mo-containing catalysts

T2 - Thermal behavior, X-ray analysis of the thermolysis products and related catalytic studies

AU - Gubanov, Alexander I.

AU - Filatov, Eugeny Yu

AU - Semitut, Eugeny Yu

AU - Smolentsev, Anton I.

AU - Snytnikov, Pavel V.

AU - Potemkin, Dmitry I.

AU - Korenev, Sergey V.

PY - 2013

Y1 - 2013

N2 - Compound [Pd(NH3)4]MoO4 (1) has been synthesized and characterized by IR spectroscopy, analytical data, powder and single-crystal X-ray crystallography. Thermal properties of 1 have been examined by thermogravimetry. Powder X-ray diffraction has been applied to investigate the nanosized products of thermal decomposition of the precursor in hydrogen (Pd-Mo) and helium (Pd-MoO2) atmospheres. Pd-Mo catalysts supported with γ-Al2O3 have been tested in oxidation of CO and H2 mixtures.

AB - Compound [Pd(NH3)4]MoO4 (1) has been synthesized and characterized by IR spectroscopy, analytical data, powder and single-crystal X-ray crystallography. Thermal properties of 1 have been examined by thermogravimetry. Powder X-ray diffraction has been applied to investigate the nanosized products of thermal decomposition of the precursor in hydrogen (Pd-Mo) and helium (Pd-MoO2) atmospheres. Pd-Mo catalysts supported with γ-Al2O3 have been tested in oxidation of CO and H2 mixtures.

KW - Catalysis

KW - Pd-Mo nanoalloy

KW - Tetraamminepalladium(II) molybdate

KW - Thermal behavior

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Access to Document

10.1016/j.tca.2013.03.036