Pd(NH3)4MoO4 as a precursor for Pd-Mo-containing catalysts

Thermal behavior, X-ray analysis of the thermolysis products and related catalytic studies

Alexander I. Gubanov, Eugeny Yu Filatov, Eugeny Yu Semitut, Anton I. Smolentsev, Pavel V. Snytnikov, Dmitry I. Potemkin, Sergey V. Korenev

Research output: Contribution to journal › Article

3 Citations (Scopus)

Abstract

Compound [Pd(NH3)4]MoO4 (1) has been synthesized and characterized by IR spectroscopy, analytical data, powder and single-crystal X-ray crystallography. Thermal properties of 1 have been examined by thermogravimetry. Powder X-ray diffraction has been applied to investigate the nanosized products of thermal decomposition of the precursor in hydrogen (Pd-Mo) and helium (Pd-MoO2) atmospheres. Pd-Mo catalysts supported with γ-Al2O3 have been tested in oxidation of CO and H2 mixtures.

Original languageEnglish
Pages (from-to)100-104
Number of pages5
JournalThermochimica Acta
Volume566
DOIs
Publication statusPublished - 2013
Externally publishedYes

Fingerprint

Helium
Thermolysis
X ray crystallography
X ray analysis
Carbon Monoxide
Catalyst supports
Powders
X ray powder diffraction
Thermogravimetric analysis
Hydrogen
Infrared spectroscopy
Pyrolysis
Thermodynamic properties
Single crystals
catalysts
Oxidation
Catalysts
products
thermogravimetry
crystallography

Keywords

  • Catalysis
  • Pd-Mo nanoalloy
  • Tetraamminepalladium(II) molybdate
  • Thermal behavior

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Condensed Matter Physics
  • Instrumentation

Cite this

Gubanov, A. I., Filatov, E. Y., Semitut, E. Y., Smolentsev, A. I., Snytnikov, P. V., Potemkin, D. I., & Korenev, S. V. (2013). Pd(NH3)4MoO4 as a precursor for Pd-Mo-containing catalysts: Thermal behavior, X-ray analysis of the thermolysis products and related catalytic studies. Thermochimica Acta, 566, 100-104. https://doi.org/10.1016/j.tca.2013.03.036

Pd(NH3)4MoO4 as a precursor for Pd-Mo-containing catalysts : Thermal behavior, X-ray analysis of the thermolysis products and related catalytic studies. / Gubanov, Alexander I.; Filatov, Eugeny Yu; Semitut, Eugeny Yu; Smolentsev, Anton I.; Snytnikov, Pavel V.; Potemkin, Dmitry I.; Korenev, Sergey V.

In: Thermochimica Acta, Vol. 566, 2013, p. 100-104.

Research output: Contribution to journal › Article

Gubanov, AI, Filatov, EY, Semitut, EY, Smolentsev, AI, Snytnikov, PV, Potemkin, DI & Korenev, SV 2013, 'Pd(NH3)4MoO4 as a precursor for Pd-Mo-containing catalysts: Thermal behavior, X-ray analysis of the thermolysis products and related catalytic studies', Thermochimica Acta, vol. 566, pp. 100-104. https://doi.org/10.1016/j.tca.2013.03.036
Gubanov AI, Filatov EY, Semitut EY, Smolentsev AI, Snytnikov PV, Potemkin DI et al. Pd(NH3)4MoO4 as a precursor for Pd-Mo-containing catalysts: Thermal behavior, X-ray analysis of the thermolysis products and related catalytic studies. Thermochimica Acta. 2013;566:100-104. https://doi.org/10.1016/j.tca.2013.03.036
Gubanov, Alexander I. ; Filatov, Eugeny Yu ; Semitut, Eugeny Yu ; Smolentsev, Anton I. ; Snytnikov, Pavel V. ; Potemkin, Dmitry I. ; Korenev, Sergey V. / Pd(NH3)4MoO4 as a precursor for Pd-Mo-containing catalysts : Thermal behavior, X-ray analysis of the thermolysis products and related catalytic studies. In: Thermochimica Acta. 2013 ; Vol. 566. pp. 100-104.
@article{3eac37e385c64dfdb32a4dbf5584298d,
title = "Pd(NH3)4MoO4 as a precursor for Pd-Mo-containing catalysts: Thermal behavior, X-ray analysis of the thermolysis products and related catalytic studies",
abstract = "Compound [Pd(NH3)4]MoO4 (1) has been synthesized and characterized by IR spectroscopy, analytical data, powder and single-crystal X-ray crystallography. Thermal properties of 1 have been examined by thermogravimetry. Powder X-ray diffraction has been applied to investigate the nanosized products of thermal decomposition of the precursor in hydrogen (Pd-Mo) and helium (Pd-MoO2) atmospheres. Pd-Mo catalysts supported with γ-Al2O3 have been tested in oxidation of CO and H2 mixtures.",
keywords = "Catalysis, Pd-Mo nanoalloy, Tetraamminepalladium(II) molybdate, Thermal behavior",
author = "Gubanov, {Alexander I.} and Filatov, {Eugeny Yu} and Semitut, {Eugeny Yu} and Smolentsev, {Anton I.} and Snytnikov, {Pavel V.} and Potemkin, {Dmitry I.} and Korenev, {Sergey V.}",
year = "2013",
doi = "10.1016/j.tca.2013.03.036",
language = "English",
volume = "566",
pages = "100--104",
journal = "Thermochimica Acta",
issn = "0040-6031",
publisher = "Elsevier",

}

TY - JOUR

T1 - Pd(NH3)4MoO4 as a precursor for Pd-Mo-containing catalysts

T2 - Thermal behavior, X-ray analysis of the thermolysis products and related catalytic studies

AU - Gubanov, Alexander I.

AU - Filatov, Eugeny Yu

AU - Semitut, Eugeny Yu

AU - Smolentsev, Anton I.

AU - Snytnikov, Pavel V.

AU - Potemkin, Dmitry I.

AU - Korenev, Sergey V.

PY - 2013

Y1 - 2013

N2 - Compound [Pd(NH3)4]MoO4 (1) has been synthesized and characterized by IR spectroscopy, analytical data, powder and single-crystal X-ray crystallography. Thermal properties of 1 have been examined by thermogravimetry. Powder X-ray diffraction has been applied to investigate the nanosized products of thermal decomposition of the precursor in hydrogen (Pd-Mo) and helium (Pd-MoO2) atmospheres. Pd-Mo catalysts supported with γ-Al2O3 have been tested in oxidation of CO and H2 mixtures.

AB - Compound [Pd(NH3)4]MoO4 (1) has been synthesized and characterized by IR spectroscopy, analytical data, powder and single-crystal X-ray crystallography. Thermal properties of 1 have been examined by thermogravimetry. Powder X-ray diffraction has been applied to investigate the nanosized products of thermal decomposition of the precursor in hydrogen (Pd-Mo) and helium (Pd-MoO2) atmospheres. Pd-Mo catalysts supported with γ-Al2O3 have been tested in oxidation of CO and H2 mixtures.

KW - Catalysis

KW - Pd-Mo nanoalloy

KW - Tetraamminepalladium(II) molybdate

KW - Thermal behavior

UR - http://www.scopus.com/inward/record.url?scp=84884522376&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84884522376&partnerID=8YFLogxK

U2 - 10.1016/j.tca.2013.03.036

DO - 10.1016/j.tca.2013.03.036

M3 - Article

VL - 566

SP - 100

EP - 104

JO - Thermochimica Acta

JF - Thermochimica Acta

SN - 0040-6031

ER -

Access to Document