Abstract
We herein report the direct harnessing of visible-to-near-IR light energy by a novel azobenzene-based colloidal porous organic polymer amenable to a post-synthetic loading of metallic Pd nanocrystals for photocatalytic Suzuki and Suzuki-type couplings using in-built Mott-Schottky heterojunction. Upon photo-illumination, the desired products were obtained in a quantitative manner with the highest ever TOF reported till date. Identical catalytic activities were maintained under natural solar irradiance, for bulk-scale reaction and over ten successive recycling of the catalyst. Detailed mechanistic investigations were performed to understand the role of each variable and reactive species involved in the course of the reaction. Inspired by the fast reactivity, a prototypal reaction was pursued in a custom-designed pressure controlled continuous flow setup that instantaneously gave the required product in a quantitative manner.
Original language | English |
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Pages (from-to) | 580-588 |
Number of pages | 9 |
Journal | Chemical Engineering Journal |
Volume | 358 |
DOIs | |
Publication status | Published - 15 Feb 2019 |
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Keywords
- Azobenzene
- Colloidal porous organic polymer
- Continuous flow
- Mechanism
- Mott-Schottky interface
- Visible and sunlight induced Suzuki
ASJC Scopus subject areas
- Chemistry(all)
- Environmental Chemistry
- Chemical Engineering(all)
- Industrial and Manufacturing Engineering
Cite this
Pd-nanoparticle decorated azobenzene based colloidal porous organic polymer for visible and natural sunlight induced Mott-Schottky junction mediated instantaneous Suzuki coupling. / Chakraborty, Jeet; Nath, Ipsita; Verpoort, Francis.
In: Chemical Engineering Journal, Vol. 358, 15.02.2019, p. 580-588.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Pd-nanoparticle decorated azobenzene based colloidal porous organic polymer for visible and natural sunlight induced Mott-Schottky junction mediated instantaneous Suzuki coupling
AU - Chakraborty, Jeet
AU - Nath, Ipsita
AU - Verpoort, Francis
PY - 2019/2/15
Y1 - 2019/2/15
N2 - We herein report the direct harnessing of visible-to-near-IR light energy by a novel azobenzene-based colloidal porous organic polymer amenable to a post-synthetic loading of metallic Pd nanocrystals for photocatalytic Suzuki and Suzuki-type couplings using in-built Mott-Schottky heterojunction. Upon photo-illumination, the desired products were obtained in a quantitative manner with the highest ever TOF reported till date. Identical catalytic activities were maintained under natural solar irradiance, for bulk-scale reaction and over ten successive recycling of the catalyst. Detailed mechanistic investigations were performed to understand the role of each variable and reactive species involved in the course of the reaction. Inspired by the fast reactivity, a prototypal reaction was pursued in a custom-designed pressure controlled continuous flow setup that instantaneously gave the required product in a quantitative manner.
AB - We herein report the direct harnessing of visible-to-near-IR light energy by a novel azobenzene-based colloidal porous organic polymer amenable to a post-synthetic loading of metallic Pd nanocrystals for photocatalytic Suzuki and Suzuki-type couplings using in-built Mott-Schottky heterojunction. Upon photo-illumination, the desired products were obtained in a quantitative manner with the highest ever TOF reported till date. Identical catalytic activities were maintained under natural solar irradiance, for bulk-scale reaction and over ten successive recycling of the catalyst. Detailed mechanistic investigations were performed to understand the role of each variable and reactive species involved in the course of the reaction. Inspired by the fast reactivity, a prototypal reaction was pursued in a custom-designed pressure controlled continuous flow setup that instantaneously gave the required product in a quantitative manner.
KW - Azobenzene
KW - Colloidal porous organic polymer
KW - Continuous flow
KW - Mechanism
KW - Mott-Schottky interface
KW - Visible and sunlight induced Suzuki
UR - http://www.scopus.com/inward/record.url?scp=85054588092&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85054588092&partnerID=8YFLogxK
U2 - 10.1016/j.cej.2018.09.037
DO - 10.1016/j.cej.2018.09.037
M3 - Article
AN - SCOPUS:85054588092
VL - 358
SP - 580
EP - 588
JO - Chemical Engineering Journal
JF - Chemical Engineering Journal
SN - 1385-8947
ER -