Paramagnetic Properties and Complexation Kinetics of Edta With Praseodymium and Holmium(III) Cations in Aqueous Solution

S. P. Babailov, V. V. Kokovkin, P. A. Stabnikov

Research output: Contribution to journal › Article

3 Citations (Scopus)

Abstract

The NMR method is used to study the features of the complexation kinetics of paramagnetic lanthanide cations with EDTA in aqueous media at temperature and pD variation. The acidity of solutions is determined by the potentiometric method with a glass electrode. By the dynamic NMR method it is found that the activation enthalpy of the association between EDTA complexones and Ln cations is ΔH = 71±5 kJ/mol in a temperature range from 290 K to 368 K (at pD = 1.6). The obtained results indicate that Ho and Pr complexes with EDTA are promising compounds as in vivo NMR thermosensors for biology and medicine.
Original languageEnglish
Pages (from-to)652-656
Number of pages5
JournalJournal of Structural Chemistry
Volume51
Issue number4
DOIs
Publication statusPublished - 24 Sep 2010
Externally publishedYes

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Praseodymium
Holmium
holmium
praseodymium
ethylenediaminetetraacetic acids
Ethylenediaminetetraacetic acid
Complexation
Edetic Acid
Cations
Positive ions
Nuclear magnetic resonance
aqueous solutions
cations
nuclear magnetic resonance
Kinetics
kinetics
glass electrodes
Lanthanoid Series Elements
Rare earth elements
biology

Keywords

  • aqueous solutions

Cite this

Paramagnetic Properties and Complexation Kinetics of Edta With Praseodymium and Holmium(III) Cations in Aqueous Solution. / Babailov, S. P.; Kokovkin, V. V.; Stabnikov, P. A.

In: Journal of Structural Chemistry, Vol. 51, No. 4, 24.09.2010, p. 652-656.

Research output: Contribution to journal › Article

Babailov, SP, Kokovkin, VV & Stabnikov, PA 2010, 'Paramagnetic Properties and Complexation Kinetics of Edta With Praseodymium and Holmium(III) Cations in Aqueous Solution', Journal of Structural Chemistry, vol. 51, no. 4, pp. 652-656. https://doi.org/10.1007/s10947-010-0095-y
Babailov SP, Kokovkin VV, Stabnikov PA. Paramagnetic Properties and Complexation Kinetics of Edta With Praseodymium and Holmium(III) Cations in Aqueous Solution. Journal of Structural Chemistry. 2010 Sep 24;51(4):652-656. https://doi.org/10.1007/s10947-010-0095-y
Babailov, S. P. ; Kokovkin, V. V. ; Stabnikov, P. A. / Paramagnetic Properties and Complexation Kinetics of Edta With Praseodymium and Holmium(III) Cations in Aqueous Solution. In: Journal of Structural Chemistry. 2010 ; Vol. 51, No. 4. pp. 652-656.
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