p-nitrotoluene bromination using barium fluorobromate Ba(BrF₄)₂

Vasily Igorevich Sobolev, Vyacheslav Radchenko, Roman Ostvald, Victor Filimonov, Ivan Zherin

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Abstract

It was shown that Ba(BrF₄)₂ acts like a highly-active brominating agent in case of interaction with p-nitrotoluene, the pure 3-bromo-nitrotoluene is formed. It was shown that typical electrophilic bromination of the aromatic compound with electron-donating and electron-accepting substituents occurs without any catalysts or hard conditions.

Original language	English
Title of host publication	Advanced Materials Research
Publisher	Trans Tech Publications Ltd
Pages	337-341
Number of pages	5
Volume	1040
ISBN (Print)	9783038352648
DOIs	https://doi.org/10.4028/www.scientific.net/AMR.1040.337
Publication status	Published - 2014
Event	International Conference for Young Scientists “High Technology: Research and Applications 2014”, HTRA 2014 - Tomsk, Russian Federation Duration: 26 Mar 2014 → 28 Mar 2014

Publication series

Name	Advanced Materials Research
Volume	1040
ISSN (Print)	10226680
ISSN (Electronic)	16628985

Other

Other	International Conference for Young Scientists “High Technology: Research and Applications 2014”, HTRA 2014
Country	Russian Federation
City	Tomsk
Period	26.3.14 → 28.3.14

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Keywords

Bromination
Bromine trifluoride
Chromatography
Fluorine
Fluorohalogenate
Synthesis

ASJC Scopus subject areas

Engineering(all)

Cite this

Sobolev, V. I., Radchenko, V., Ostvald, R., Filimonov, V., & Zherin, I. (2014). p-nitrotoluene bromination using barium fluorobromate Ba(BrF₄)₂. In Advanced Materials Research (Vol. 1040, pp. 337-341). (Advanced Materials Research; Vol. 1040). Trans Tech Publications Ltd. https://doi.org/10.4028/www.scientific.net/AMR.1040.337

p-nitrotoluene bromination using barium fluorobromate Ba(BrF₄)₂. / Sobolev, Vasily Igorevich; Radchenko, Vyacheslav; Ostvald, Roman ; Filimonov, Victor ; Zherin, Ivan.

Advanced Materials Research. Vol. 1040 Trans Tech Publications Ltd, 2014. p. 337-341 (Advanced Materials Research; Vol. 1040).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Sobolev, VI, Radchenko, V, Ostvald, R , Filimonov, V & Zherin, I 2014, p-nitrotoluene bromination using barium fluorobromate Ba(BrF₄)₂. in Advanced Materials Research. vol. 1040, Advanced Materials Research, vol. 1040, Trans Tech Publications Ltd, pp. 337-341, International Conference for Young Scientists “High Technology: Research and Applications 2014”, HTRA 2014, Tomsk, Russian Federation, 26.3.14. https://doi.org/10.4028/www.scientific.net/AMR.1040.337

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Access to Document

10.4028/www.scientific.net/AMR.1040.337