Oxygen-chelated indenylidene ruthenium catalysts for olefin metathesis

Yu Xie, Ye Yuan, Bibimaryam Mousavi, Yuan Cai, Cheng Kai, Yin Lu, Mehman Yusubov, Francis Walter Cornelius Verpoort

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Olefin metathesis is a transition metal-mediated transformation that rearranges the carbon atoms of the carbon-carbon double bond of olefins. This reaction has become one of the most important and powerful reactions. Therefore development of new, well-defined, highly active and selective catalysts is very desirable and a valuable goal. This mini-review mainly introduces the development of ruthenium catalysts in olefin metathesis highlighting oxygen-chelated indenylidene ruthenium catalysts. Applying an alkoxyl group on the indenylidene ligand fragment can generate the Ru chelating bond. Additionally, various modifications of the ligand as well as the catalytic activity for ring-closing metathesis reaction and selectivity of cross metathesis reaction are overviewed. Finally, the perspectives on the development of new catalysts are summarized.

Original languageEnglish
Pages (from-to)573-579
Number of pages7
JournalApplied Organometallic Chemistry
Volume29
Issue number9
DOIs
Publication statusPublished - 1 Sep 2015

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Ruthenium
Alkenes
Oxygen
Catalysts
Carbon
Ligands
Catalyst selectivity
Chelation
Transition metals
Catalyst activity
Atoms

Keywords

  • chelation
  • indenylidene
  • olefin metathesis
  • ruthenium catalyst

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Chemistry(all)

Cite this

Oxygen-chelated indenylidene ruthenium catalysts for olefin metathesis. / Xie, Yu; Yuan, Ye; Mousavi, Bibimaryam; Cai, Yuan; Kai, Cheng; Lu, Yin; Yusubov, Mehman; Verpoort, Francis Walter Cornelius.

In: Applied Organometallic Chemistry, Vol. 29, No. 9, 01.09.2015, p. 573-579.

Research output: Contribution to journalArticle

Xie, Yu ; Yuan, Ye ; Mousavi, Bibimaryam ; Cai, Yuan ; Kai, Cheng ; Lu, Yin ; Yusubov, Mehman ; Verpoort, Francis Walter Cornelius. / Oxygen-chelated indenylidene ruthenium catalysts for olefin metathesis. In: Applied Organometallic Chemistry. 2015 ; Vol. 29, No. 9. pp. 573-579.
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