Oxidative modification of petroleum resins and reception of emulsions with industrial oils

Daria V. Fisenko, Anna A. Manankova, Vladimir G. Bondaletov, Marina Y. Fillipova, Vera A. Yakimova

Research output: Contribution to journalArticle

Abstract

In this paper, the petroleum resin modification process by oxidation with hydrogen peroxide under phase transfer catalysis has been studied. As a result of oxidation petroleum resins with various oxygen-containing groups (carboxyl, hydroperoxide and epoxy groups) have been obtained. The possibility of using oxidized resins as emulsifiers to stabilize oil-in-water emulsions has been shown. The optimum mixing ratio water/petroleum resin has been determined, and stable oil-in-water emulsions with modified petroleum resins have been obtained. The dependence of the emulsion stability on the acid number of the oxidized resins included in the composition of the obtained emulsions has been determined. The effect of the composition on the rheological characteristics of the emulsions: dynamic viscosity, shear stress, and the shear rate have been identified.

Original languageEnglish
Pages (from-to)590-596
Number of pages7
JournalPetroleum and Coal
Volume58
Issue number5
Publication statusPublished - 2016

Fingerprint

Emulsions
Resins
Crude oil
Water
Oxidation
Chemical analysis
Hydrogen peroxide
Shear deformation
Catalysis
Oils
Shear stress
Viscosity
Oxygen
Acids

Keywords

  • Modification
  • Petroleum resins
  • Phase transfer catalysis
  • Stable oil-in-water emulsions

ASJC Scopus subject areas

  • Energy(all)

Cite this

Oxidative modification of petroleum resins and reception of emulsions with industrial oils. / Fisenko, Daria V.; Manankova, Anna A.; Bondaletov, Vladimir G.; Fillipova, Marina Y.; Yakimova, Vera A.

In: Petroleum and Coal, Vol. 58, No. 5, 2016, p. 590-596.

Research output: Contribution to journalArticle

Fisenko, Daria V. ; Manankova, Anna A. ; Bondaletov, Vladimir G. ; Fillipova, Marina Y. ; Yakimova, Vera A. / Oxidative modification of petroleum resins and reception of emulsions with industrial oils. In: Petroleum and Coal. 2016 ; Vol. 58, No. 5. pp. 590-596.
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