Oxidation of organic substances with compounds of trivalent manganese. XVII. Coulometric generation of the diphosphate complex of trivalent manganese in sulphuric acid medium and hexaaquomanganese(III) ions in perchloric acid medium

J. Barek, A. Berka, K. Jakubec

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Conditions were found for the electrochemical generation of the diphosphate complex of trivalent manganese in a sulfuric acid medium and of hexaaquomanganese(III) ions in perchloric acid medium. Practical application of the studied reagents was verified by coulometric titration of the order of tenths of milligrams of ferrous ions and hydroquinone. Indirect determination of oxalic acid based on its oxidation with excess electrochemically produced trivalent manganese in perchloric acid medium and on coulometric back titration of the unreacted oxidizing agent with ferrous ions was also studied.

Original languageEnglish
Pages (from-to)454-462
Number of pages9
JournalMicrochemical Journal
Volume24
Issue number4
DOIs
Publication statusPublished - 1 Jan 1979
Externally publishedYes

Fingerprint

Diphosphates
Manganese
Ions
Titration
Oxidation
Acids
Oxalic Acid
Oxidants
Perchloric Acid

ASJC Scopus subject areas

  • Analytical Chemistry
  • Spectroscopy

Cite this

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abstract = "Conditions were found for the electrochemical generation of the diphosphate complex of trivalent manganese in a sulfuric acid medium and of hexaaquomanganese(III) ions in perchloric acid medium. Practical application of the studied reagents was verified by coulometric titration of the order of tenths of milligrams of ferrous ions and hydroquinone. Indirect determination of oxalic acid based on its oxidation with excess electrochemically produced trivalent manganese in perchloric acid medium and on coulometric back titration of the unreacted oxidizing agent with ferrous ions was also studied.",
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T1 - Oxidation of organic substances with compounds of trivalent manganese. XVII. Coulometric generation of the diphosphate complex of trivalent manganese in sulphuric acid medium and hexaaquomanganese(III) ions in perchloric acid medium

AU - Barek, J.

AU - Berka, A.

AU - Jakubec, K.

PY - 1979/1/1

Y1 - 1979/1/1

N2 - Conditions were found for the electrochemical generation of the diphosphate complex of trivalent manganese in a sulfuric acid medium and of hexaaquomanganese(III) ions in perchloric acid medium. Practical application of the studied reagents was verified by coulometric titration of the order of tenths of milligrams of ferrous ions and hydroquinone. Indirect determination of oxalic acid based on its oxidation with excess electrochemically produced trivalent manganese in perchloric acid medium and on coulometric back titration of the unreacted oxidizing agent with ferrous ions was also studied.

AB - Conditions were found for the electrochemical generation of the diphosphate complex of trivalent manganese in a sulfuric acid medium and of hexaaquomanganese(III) ions in perchloric acid medium. Practical application of the studied reagents was verified by coulometric titration of the order of tenths of milligrams of ferrous ions and hydroquinone. Indirect determination of oxalic acid based on its oxidation with excess electrochemically produced trivalent manganese in perchloric acid medium and on coulometric back titration of the unreacted oxidizing agent with ferrous ions was also studied.

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