Oxidation of organic substances with compounds of trivalent manganese. XXIII. Preparation, stability, and determination of the titer of standard solutions of the fluoride complex of trivalent manganese

J. Barek, A. Berka, H. Skokánková

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

A method of preparation of 10-2 -10-3M standard solutions of the fluoride complex of manganese(III) by the reaction of manganese(II) with permanganate in a medium of potassium fluoride acidified with sulfuric acid has been developed. It has been found that in a medium of 1 M sulfuric acid, 0.5 M manganese(II) sulfate, and 0.1 M potassium fluoride these solutions are sufficiently stable for both direct and indirect titrimetric determinations. The titer was determined using potassium iodide as a primary standard and potentiometric, bipotentiometric, or biamperometric titration.

Original languageEnglish
Pages (from-to)393-400
Number of pages8
JournalMicrochemical Journal
Volume27
Issue number3
DOIs
Publication statusPublished - 1 Jan 1982
Externally publishedYes

Fingerprint

Manganese
Fluorides
Oxidation
Potassium Iodide
Titration
Sulfates
sulfuric acid
potassium fluoride

ASJC Scopus subject areas

  • Analytical Chemistry
  • Spectroscopy

Cite this

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abstract = "A method of preparation of 10-2 -10-3M standard solutions of the fluoride complex of manganese(III) by the reaction of manganese(II) with permanganate in a medium of potassium fluoride acidified with sulfuric acid has been developed. It has been found that in a medium of 1 M sulfuric acid, 0.5 M manganese(II) sulfate, and 0.1 M potassium fluoride these solutions are sufficiently stable for both direct and indirect titrimetric determinations. The titer was determined using potassium iodide as a primary standard and potentiometric, bipotentiometric, or biamperometric titration.",
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T1 - Oxidation of organic substances with compounds of trivalent manganese. XXIII. Preparation, stability, and determination of the titer of standard solutions of the fluoride complex of trivalent manganese

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AU - Berka, A.

AU - Skokánková, H.

PY - 1982/1/1

Y1 - 1982/1/1

N2 - A method of preparation of 10-2 -10-3M standard solutions of the fluoride complex of manganese(III) by the reaction of manganese(II) with permanganate in a medium of potassium fluoride acidified with sulfuric acid has been developed. It has been found that in a medium of 1 M sulfuric acid, 0.5 M manganese(II) sulfate, and 0.1 M potassium fluoride these solutions are sufficiently stable for both direct and indirect titrimetric determinations. The titer was determined using potassium iodide as a primary standard and potentiometric, bipotentiometric, or biamperometric titration.

AB - A method of preparation of 10-2 -10-3M standard solutions of the fluoride complex of manganese(III) by the reaction of manganese(II) with permanganate in a medium of potassium fluoride acidified with sulfuric acid has been developed. It has been found that in a medium of 1 M sulfuric acid, 0.5 M manganese(II) sulfate, and 0.1 M potassium fluoride these solutions are sufficiently stable for both direct and indirect titrimetric determinations. The titer was determined using potassium iodide as a primary standard and potentiometric, bipotentiometric, or biamperometric titration.

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