Oxidation of Dimedone by Hydrobromic Acid in Dimethylsulfoxide and Synthesis of 3,5-Dibromo-2,6-dihydroxy-4,4-dimethyl-2,5-cyclohexadien-1-one and 3,5,5-Tribromo-4,4-dimethyl-2-hydroxy-2-cyclopenten-1-one

Abstract

Hydrogen bromide in DMSO oxidizes dimedone differently than known cyclic β-diketones: 3,5-dibromo-2,6-dihydroxy-4,4-dimethyl-2,5-cyclohexadien-1-one and 3,5,5-tribromo-4,4-dimethyl-2-hydroxy-2-cyclopenten-1-one are formed instead of vicinal triketones.

Original language	English
Pages (from-to)	158-160
Number of pages	3
Journal	Russian Journal of Organic Chemistry
Volume	33
Issue number	2
Publication status	Published - Feb 1997

ASJC Scopus subject areas

Organic Chemistry

Fingerprint Dive into the research topics of 'Oxidation of Dimedone by Hydrobromic Acid in Dimethylsulfoxide and Synthesis of 3,5-Dibromo-2,6-dihydroxy-4,4-dimethyl-2,5-cyclohexadien-1-one and 3,5,5-Tribromo-4,4-dimethyl-2-hydroxy-2-cyclopenten-1-one'. Together they form a unique fingerprint.

Cite this

Oxidation of Dimedone by Hydrobromic Acid in Dimethylsulfoxide and Synthesis of 3,5-Dibromo-2,6-dihydroxy-4,4-dimethyl-2,5-cyclohexadien-1-one and 3,5,5-Tribromo-4,4-dimethyl-2-hydroxy-2-cyclopenten-1-one. / Yusubov, M. S.; Zholobova, G. A.; Habicher, W.; Filimonov, V. D.

In: Russian Journal of Organic Chemistry, Vol. 33, No. 2, 02.1997, p. 158-160.

Research output: Contribution to journal › Article › peer-review

@article{da1dd4475ed640b8ad3d1a92ffc3514f,

title = "Oxidation of Dimedone by Hydrobromic Acid in Dimethylsulfoxide and Synthesis of 3,5-Dibromo-2,6-dihydroxy-4,4-dimethyl-2,5-cyclohexadien-1-one and 3,5,5-Tribromo-4,4-dimethyl-2-hydroxy-2-cyclopenten-1-one",

abstract = "Hydrogen bromide in DMSO oxidizes dimedone differently than known cyclic β-diketones: 3,5-dibromo-2,6-dihydroxy-4,4-dimethyl-2,5-cyclohexadien-1-one and 3,5,5-tribromo-4,4-dimethyl-2-hydroxy-2-cyclopenten-1-one are formed instead of vicinal triketones.",

author = "Yusubov, {M. S.} and Zholobova, {G. A.} and W. Habicher and Filimonov, {V. D.}",

year = "1997",

month = feb,

language = "English",

volume = "33",

pages = "158--160",

journal = "Russian Journal of Organic Chemistry",

issn = "1070-4280",

publisher = "Maik Nauka-Interperiodica Publishing",

number = "2",

}

TY - JOUR

T1 - Oxidation of Dimedone by Hydrobromic Acid in Dimethylsulfoxide and Synthesis of 3,5-Dibromo-2,6-dihydroxy-4,4-dimethyl-2,5-cyclohexadien-1-one and 3,5,5-Tribromo-4,4-dimethyl-2-hydroxy-2-cyclopenten-1-one

AU - Yusubov, M. S.

AU - Zholobova, G. A.

AU - Habicher, W.

AU - Filimonov, V. D.

PY - 1997/2

Y1 - 1997/2

N2 - Hydrogen bromide in DMSO oxidizes dimedone differently than known cyclic β-diketones: 3,5-dibromo-2,6-dihydroxy-4,4-dimethyl-2,5-cyclohexadien-1-one and 3,5,5-tribromo-4,4-dimethyl-2-hydroxy-2-cyclopenten-1-one are formed instead of vicinal triketones.

AB - Hydrogen bromide in DMSO oxidizes dimedone differently than known cyclic β-diketones: 3,5-dibromo-2,6-dihydroxy-4,4-dimethyl-2,5-cyclohexadien-1-one and 3,5,5-tribromo-4,4-dimethyl-2-hydroxy-2-cyclopenten-1-one are formed instead of vicinal triketones.

UR - http://www.scopus.com/inward/record.url?scp=0031323633&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0031323633&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0031323633

VL - 33

SP - 158

EP - 160

JO - Russian Journal of Organic Chemistry

JF - Russian Journal of Organic Chemistry

SN - 1070-4280

IS - 2

ER -