Oxidation of aqueous pharmaceuticals by pulsed corona discharge

Iris Panorel, Sergey Preis, Iakov Kornev, Henry Hatakka, Marjatta Louhi-Kultanen

Research output: Contribution to journalArticle

36 Citations (Scopus)

Abstract

Oxidation of aromatic compounds of phenolic (paracetamol, β-oestradiol and salicylic acid) and carboxylic (indomethacin and ibuprofen) structure used in pharmaceutics was studied. Aqueous solutions were treated with pulsed corona discharge (PCD) as a means for advanced oxidation. Pulse repetition frequency, delivered energy dose and oxidation media were the main parameters studied for their influence on the process energy efficiency. The PCD treatment appeared to be effective in oxidation of the target compounds: complete degradation of pollutant together with partial mineralization was achieved at moderate energy consumption; oxidation proceeds faster in alkaline media. Low-molecular carboxylic acids were identified as ultimate oxidation by-products formed in the reaction.

Original languageEnglish
Pages (from-to)923-930
Number of pages8
JournalEnvironmental Technology (United Kingdom)
Volume34
Issue number7
DOIs
Publication statusPublished - 1 Apr 2013

Fingerprint

corona
drug
oxidation
Oxidation
Pharmaceutical Preparations
salicylic acid
Salicylic Acid
Aromatic compounds
Ibuprofen
carboxylic acid
Acetaminophen
Carboxylic Acids
energy efficiency
Indomethacin
Discharge (fluid mechanics)
Byproducts
Energy efficiency
Estradiol
Energy utilization
aqueous solution

Keywords

  • AOPs
  • ozone
  • pharmaceuticals
  • wastewater
  • water

ASJC Scopus subject areas

  • Environmental Chemistry
  • Waste Management and Disposal
  • Water Science and Technology

Cite this

Oxidation of aqueous pharmaceuticals by pulsed corona discharge. / Panorel, Iris; Preis, Sergey; Kornev, Iakov; Hatakka, Henry; Louhi-Kultanen, Marjatta.

In: Environmental Technology (United Kingdom), Vol. 34, No. 7, 01.04.2013, p. 923-930.

Research output: Contribution to journalArticle

Panorel, Iris ; Preis, Sergey ; Kornev, Iakov ; Hatakka, Henry ; Louhi-Kultanen, Marjatta. / Oxidation of aqueous pharmaceuticals by pulsed corona discharge. In: Environmental Technology (United Kingdom). 2013 ; Vol. 34, No. 7. pp. 923-930.
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