Abstract
Alkylphenyl-and dialkylacetylenes are oxidized by the DMSO-PdCl2 or DMSO-Pd/C system to give the corresponding 1,2-diketones. Oxidation of these compounds, unlike that of diarylacetylenes, is less selective and is accompanied by the partial cleavage of triple bonds and formation of ketones, 1,3-diketones, and aromatic compounds as secondary condensation products.
| Original language | English |
|---|---|
| Pages (from-to) | 649-653 |
| Number of pages | 5 |
| Journal | Russian Chemical Bulletin |
| Volume | 50 |
| Issue number | 4 |
| DOIs | |
| Publication status | Published - 2001 |
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Keywords
- Alkylacetylencs
- Alkylphenylacetylenes
- Diketones
- Dimethyl sulfoxide
- Palladium chloride
ASJC Scopus subject areas
- Chemistry(all)
Cite this
Oxidation of alkylphenylacetylenes and dialkylacetylenes on palladium catalysts in DMSO. / Yusubov, M. S.; Filimonov, V. D.; Chi, Ki Whan.
In: Russian Chemical Bulletin, Vol. 50, No. 4, 2001, p. 649-653.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Oxidation of alkylphenylacetylenes and dialkylacetylenes on palladium catalysts in DMSO
AU - Yusubov, M. S.
AU - Filimonov, V. D.
AU - Chi, Ki Whan
PY - 2001
Y1 - 2001
N2 - Alkylphenyl-and dialkylacetylenes are oxidized by the DMSO-PdCl2 or DMSO-Pd/C system to give the corresponding 1,2-diketones. Oxidation of these compounds, unlike that of diarylacetylenes, is less selective and is accompanied by the partial cleavage of triple bonds and formation of ketones, 1,3-diketones, and aromatic compounds as secondary condensation products.
AB - Alkylphenyl-and dialkylacetylenes are oxidized by the DMSO-PdCl2 or DMSO-Pd/C system to give the corresponding 1,2-diketones. Oxidation of these compounds, unlike that of diarylacetylenes, is less selective and is accompanied by the partial cleavage of triple bonds and formation of ketones, 1,3-diketones, and aromatic compounds as secondary condensation products.
KW - Alkylacetylencs
KW - Alkylphenylacetylenes
KW - Diketones
KW - Dimethyl sulfoxide
KW - Palladium chloride
UR - http://www.scopus.com/inward/record.url?scp=0035537658&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0035537658&partnerID=8YFLogxK
U2 - 10.1023/A:1011308811448
DO - 10.1023/A:1011308811448
M3 - Article
VL - 50
SP - 649
EP - 653
JO - Russian Chemical Bulletin
JF - Russian Chemical Bulletin
SN - 1066-5285
IS - 4
ER -