Abstract
Alkylphenyl-and dialkylacetylenes are oxidized by the DMSO-PdCl2 or DMSO-Pd/C system to give the corresponding 1,2-diketones. Oxidation of these compounds, unlike that of diarylacetylenes, is less selective and is accompanied by the partial cleavage of triple bonds and formation of ketones, 1,3-diketones, and aromatic compounds as secondary condensation products.
Original language | English |
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Pages (from-to) | 649-653 |
Number of pages | 5 |
Journal | Russian Chemical Bulletin |
Volume | 50 |
Issue number | 4 |
DOIs | |
Publication status | Published - 2001 |
Keywords
- Alkylacetylencs
- Alkylphenylacetylenes
- Diketones
- Dimethyl sulfoxide
- Palladium chloride
ASJC Scopus subject areas
- Chemistry(all)