Oxidation of Alcohols with Dimethyl Sulfoxide. Oxidant and Substrate Activation Pathways

Abstract

Oxidation of diphenylmethanol, diphenylmethyl acetate, and diphenylmethyl trifluoroacetate with dimethyl sulfoxide in the presence of electrophilic acylating species involves mainly activation of DMSO as S-nucleophile. In the presence of KBr and sulfuric acid, an alternative oxidation pathway prevails, where DMSO acts as O-nucleophile.

Original language	English
Pages (from-to)	31-33
Number of pages	3
Journal	Russian Journal of Organic Chemistry
Volume	34
Issue number	1
Publication status	Published - Jan 1998

ASJC Scopus subject areas

Organic Chemistry

Fingerprint Dive into the research topics of 'Oxidation of Alcohols with Dimethyl Sulfoxide. Oxidant and Substrate Activation Pathways'. Together they form a unique fingerprint.

Cite this

@article{1f3a839e9ca345b082464598ca3ababd,

title = "Oxidation of Alcohols with Dimethyl Sulfoxide. Oxidant and Substrate Activation Pathways",

abstract = "Oxidation of diphenylmethanol, diphenylmethyl acetate, and diphenylmethyl trifluoroacetate with dimethyl sulfoxide in the presence of electrophilic acylating species involves mainly activation of DMSO as S-nucleophile. In the presence of KBr and sulfuric acid, an alternative oxidation pathway prevails, where DMSO acts as O-nucleophile.",

author = "Filimonov, {V. D.} and Krasnokutskaya, {E. A.} and Yusubov, {M. S.} and Kuznetsova, {Yu A.}",

year = "1998",

month = jan,

language = "English",

volume = "34",

pages = "31--33",

journal = "Russian Journal of Organic Chemistry",

issn = "1070-4280",

publisher = "Maik Nauka-Interperiodica Publishing",

number = "1",

}

TY - JOUR

T1 - Oxidation of Alcohols with Dimethyl Sulfoxide. Oxidant and Substrate Activation Pathways

AU - Filimonov, V. D.

AU - Krasnokutskaya, E. A.

AU - Yusubov, M. S.

AU - Kuznetsova, Yu A.

PY - 1998/1

Y1 - 1998/1

N2 - Oxidation of diphenylmethanol, diphenylmethyl acetate, and diphenylmethyl trifluoroacetate with dimethyl sulfoxide in the presence of electrophilic acylating species involves mainly activation of DMSO as S-nucleophile. In the presence of KBr and sulfuric acid, an alternative oxidation pathway prevails, where DMSO acts as O-nucleophile.

AB - Oxidation of diphenylmethanol, diphenylmethyl acetate, and diphenylmethyl trifluoroacetate with dimethyl sulfoxide in the presence of electrophilic acylating species involves mainly activation of DMSO as S-nucleophile. In the presence of KBr and sulfuric acid, an alternative oxidation pathway prevails, where DMSO acts as O-nucleophile.

UR - http://www.scopus.com/inward/record.url?scp=0032357847&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0032357847&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0032357847

VL - 34

SP - 31

EP - 33

JO - Russian Journal of Organic Chemistry

JF - Russian Journal of Organic Chemistry

SN - 1070-4280

IS - 1

ER -