TY - JOUR
T1 - Oxidation of Alcohols with Dimethyl Sulfoxide. Oxidant and Substrate Activation Pathways
AU - Filimonov, V. D.
AU - Krasnokutskaya, E. A.
AU - Yusubov, M. S.
AU - Kuznetsova, Yu A.
PY - 1998/1
Y1 - 1998/1
N2 - Oxidation of diphenylmethanol, diphenylmethyl acetate, and diphenylmethyl trifluoroacetate with dimethyl sulfoxide in the presence of electrophilic acylating species involves mainly activation of DMSO as S-nucleophile. In the presence of KBr and sulfuric acid, an alternative oxidation pathway prevails, where DMSO acts as O-nucleophile.
AB - Oxidation of diphenylmethanol, diphenylmethyl acetate, and diphenylmethyl trifluoroacetate with dimethyl sulfoxide in the presence of electrophilic acylating species involves mainly activation of DMSO as S-nucleophile. In the presence of KBr and sulfuric acid, an alternative oxidation pathway prevails, where DMSO acts as O-nucleophile.
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M3 - Article
AN - SCOPUS:0032357847
VL - 34
SP - 31
EP - 33
JO - Russian Journal of Organic Chemistry
JF - Russian Journal of Organic Chemistry
SN - 1070-4280
IS - 1
ER -