One-pot synthesis of monosubstituted aryl(hetaryl)acetylenes by direct introduction of the C≡CH residue into arenes and hetarenes

Sergei F. Vasilevsky, Svetlana V. Klyatskaya, José Elguero

Research output: Contribution to journalArticle

25 Citations (Scopus)

Abstract

A convenient one-pot synthesis of aryl(hetaryl)acetylenes by cross-coupling of aryl(hetaryl)iodides with acetylene in presence of PdCl2(Ph 3)2, CuI and K2CO3 in DMF has been developed.

Original languageEnglish
Pages (from-to)6685-6688
Number of pages4
JournalTetrahedron
Volume60
Issue number31
DOIs
Publication statusPublished - 26 Jul 2004
Externally publishedYes

Fingerprint

Acetylene
Alkynes
Iodides
potassium carbonate
palladium chloride

Keywords

  • Cross-coupling
  • Homogeneous catalysis
  • Monosubstituted acetylenes

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Cite this

One-pot synthesis of monosubstituted aryl(hetaryl)acetylenes by direct introduction of the C≡CH residue into arenes and hetarenes. / Vasilevsky, Sergei F.; Klyatskaya, Svetlana V.; Elguero, José.

In: Tetrahedron, Vol. 60, No. 31, 26.07.2004, p. 6685-6688.

Research output: Contribution to journalArticle

@article{3d915f5cd1134cb099eb1ab886e016ab,
title = "One-pot synthesis of monosubstituted aryl(hetaryl)acetylenes by direct introduction of the C≡CH residue into arenes and hetarenes",
abstract = "A convenient one-pot synthesis of aryl(hetaryl)acetylenes by cross-coupling of aryl(hetaryl)iodides with acetylene in presence of PdCl2(Ph 3)2, CuI and K2CO3 in DMF has been developed.",
keywords = "Cross-coupling, Homogeneous catalysis, Monosubstituted acetylenes",
author = "Vasilevsky, {Sergei F.} and Klyatskaya, {Svetlana V.} and Jos{\'e} Elguero",
year = "2004",
month = "7",
day = "26",
doi = "10.1016/j.tet.2004.05.093",
language = "English",
volume = "60",
pages = "6685--6688",
journal = "Tetrahedron",
issn = "0040-4020",
publisher = "Elsevier Limited",
number = "31",

}

TY - JOUR

T1 - One-pot synthesis of monosubstituted aryl(hetaryl)acetylenes by direct introduction of the C≡CH residue into arenes and hetarenes

AU - Vasilevsky, Sergei F.

AU - Klyatskaya, Svetlana V.

AU - Elguero, José

PY - 2004/7/26

Y1 - 2004/7/26

N2 - A convenient one-pot synthesis of aryl(hetaryl)acetylenes by cross-coupling of aryl(hetaryl)iodides with acetylene in presence of PdCl2(Ph 3)2, CuI and K2CO3 in DMF has been developed.

AB - A convenient one-pot synthesis of aryl(hetaryl)acetylenes by cross-coupling of aryl(hetaryl)iodides with acetylene in presence of PdCl2(Ph 3)2, CuI and K2CO3 in DMF has been developed.

KW - Cross-coupling

KW - Homogeneous catalysis

KW - Monosubstituted acetylenes

UR - http://www.scopus.com/inward/record.url?scp=4143100648&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=4143100648&partnerID=8YFLogxK

U2 - 10.1016/j.tet.2004.05.093

DO - 10.1016/j.tet.2004.05.093

M3 - Article

VL - 60

SP - 6685

EP - 6688

JO - Tetrahedron

JF - Tetrahedron

SN - 0040-4020

IS - 31

ER -