One-pot synthesis of diaryliodonium salts from arenes and aryl iodides with Oxone-sulfuric acid

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2 Citations (Scopus)

Abstract

A facile synthesis of diaryliodonium salts utilizing Oxone as versatile and cheap oxidant has been developed. This method shows wide applicability and can be used for the preparation of iodonium salts containing electron-donating or electron-withdrawing groups in good yields. In addition, this procedure can be applied to the preparation of symmetric iodonium salts directly from arenes via a one-pot iodination-oxidation sequence.

Original languageEnglish
Pages (from-to)849-855
Number of pages7
JournalBeilstein Journal of Organic Chemistry
Volume14
DOIs
Publication statusPublished - 12 Apr 2018

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Iodides
Salts
Electrons
Oxidants
Oxidation
sulfuric acid
potassium peroxymonosulfuric acid

Keywords

  • Diaryliodonium salts
  • Iodine
  • Iodonium
  • Oxidation
  • Oxone

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

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title = "One-pot synthesis of diaryliodonium salts from arenes and aryl iodides with Oxone-sulfuric acid",
abstract = "A facile synthesis of diaryliodonium salts utilizing Oxone as versatile and cheap oxidant has been developed. This method shows wide applicability and can be used for the preparation of iodonium salts containing electron-donating or electron-withdrawing groups in good yields. In addition, this procedure can be applied to the preparation of symmetric iodonium salts directly from arenes via a one-pot iodination-oxidation sequence.",
keywords = "Diaryliodonium salts, Iodine, Iodonium, Oxidation, Oxone",
author = "Natalia Soldatova and Pavel Postnikov and Olga Kukurina and Zhdankin, {Viktor V.} and Akira Yoshimura and Thomas Wirth and Yusubov, {Mekhman S.}",
year = "2018",
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T1 - One-pot synthesis of diaryliodonium salts from arenes and aryl iodides with Oxone-sulfuric acid

AU - Soldatova, Natalia

AU - Postnikov, Pavel

AU - Kukurina, Olga

AU - Zhdankin, Viktor V.

AU - Yoshimura, Akira

AU - Wirth, Thomas

AU - Yusubov, Mekhman S.

PY - 2018/4/12

Y1 - 2018/4/12

N2 - A facile synthesis of diaryliodonium salts utilizing Oxone as versatile and cheap oxidant has been developed. This method shows wide applicability and can be used for the preparation of iodonium salts containing electron-donating or electron-withdrawing groups in good yields. In addition, this procedure can be applied to the preparation of symmetric iodonium salts directly from arenes via a one-pot iodination-oxidation sequence.

AB - A facile synthesis of diaryliodonium salts utilizing Oxone as versatile and cheap oxidant has been developed. This method shows wide applicability and can be used for the preparation of iodonium salts containing electron-donating or electron-withdrawing groups in good yields. In addition, this procedure can be applied to the preparation of symmetric iodonium salts directly from arenes via a one-pot iodination-oxidation sequence.

KW - Diaryliodonium salts

KW - Iodine

KW - Iodonium

KW - Oxidation

KW - Oxone

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