Abstract
The 'expanded local mode approach' derived in Ref. [1] (Ulenikov et al., Spectrochim. Acta Part A, 52 (1996) 1829) is modified in an appropriate way for the analysis of XY2 (C2v) molecules having an arbitrary value of the equilibrium interbond angle 2αe. It is shown that the conditions considered allow one to estimate with good enough accuracy the harmonic frequencies (quadratic force field parameters) of a molecule on the basis of experimental information on pure rotational spectra only.
| Original language | English |
|---|---|
| Pages (from-to) | 329-334 |
| Number of pages | 6 |
| Journal | Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy |
| Volume | 53 |
| Issue number | 3 PART A |
| Publication status | Published - 1 Mar 1997 |
Keywords
- Centrifugal parameters
- Harmonic frequencies
- Local modes
ASJC Scopus subject areas
- Analytical Chemistry
- Atomic and Molecular Physics, and Optics
- Instrumentation
- Spectroscopy
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Ulenikov, O. N., Yurchenko, S. N., & Tolchenov, R. N. (1997). On the study of XY2 (my ≪ mx) plane molecules. Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 53(3 PART A), 329-334.