On the study of high-resolution rovibrational spectrum of H2S in the region of 7300-7900 cm-1

O. N. Ulenikov, A. W. Liu, E. S. Bekhtereva, O. V. Gromova, L. Y. Hao, S. M. Hu

Research output: Contribution to journalArticle

31 Citations (Scopus)

Abstract

High-resolution Fourier transform infrared spectrum of H2S was recorded and analyzed in the region of the v=v1+v2/ 2+v3=3 poliad. Experimental transitions were assigned to the 3ν1, 2ν13, ν1+2ν3, 3ν3, 2ν1+2ν2, and ν1+2ν23 bands with the maximum value of quantum number J equal to 11, 14, 10, 11, 8, and 11, respectively. The theoretical analysis was fulfilled with the Hamiltonian model which takes into account numerous resonance interactions between all the mentioned vibrational states. The rms deviation of the reproduction of 510 upper energy levels (derived from more than 1550 transitions) with 75 parameters was 0.0022cm -1.

Original languageEnglish
Pages (from-to)57-70
Number of pages14
JournalJournal of Molecular Spectroscopy
Volume226
Issue number1
DOIs
Publication statusPublished - 1 Jul 2004

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Hamiltonians
Electron transitions
Electron energy levels
Fourier transforms
Infrared radiation
high resolution
vibrational states
quantum numbers
infrared spectra
energy levels
deviation
interactions

Keywords

  • HS molecule
  • Resonance interactions
  • Spectroscopic parameters
  • Vibration-rotation spectra

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics
  • Spectroscopy
  • Physical and Theoretical Chemistry

Cite this

On the study of high-resolution rovibrational spectrum of H2S in the region of 7300-7900 cm-1. / Ulenikov, O. N.; Liu, A. W.; Bekhtereva, E. S.; Gromova, O. V.; Hao, L. Y.; Hu, S. M.

In: Journal of Molecular Spectroscopy, Vol. 226, No. 1, 01.07.2004, p. 57-70.

Research output: Contribution to journalArticle

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AU - Bekhtereva, E. S.

AU - Gromova, O. V.

AU - Hao, L. Y.

AU - Hu, S. M.

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AB - High-resolution Fourier transform infrared spectrum of H2S was recorded and analyzed in the region of the v=v1+v2/ 2+v3=3 poliad. Experimental transitions were assigned to the 3ν1, 2ν1+ν3, ν1+2ν3, 3ν3, 2ν1+2ν2, and ν1+2ν2+ν3 bands with the maximum value of quantum number J equal to 11, 14, 10, 11, 8, and 11, respectively. The theoretical analysis was fulfilled with the Hamiltonian model which takes into account numerous resonance interactions between all the mentioned vibrational states. The rms deviation of the reproduction of 510 upper energy levels (derived from more than 1550 transitions) with 75 parameters was 0.0022cm -1.

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