On the displacements of centres of vibration-rotation lines under isotope substitution in polyatomic molecules

A. D. Bykov, Yu S. Makushkin, O. N. Ulenikov

Research output: Contribution to journal › Article

20 Citations (Scopus)

Abstract

The general form of the corrections to the vibration-rotation hamiltonian resulting from isotope substitution of heavy nuclei has been obtained. These results are used for predicting the displacements of the vibration-rotation line centres. Some results of numerical calculations are given as an illustration.

Original languageEnglish
Pages (from-to)907-918
Number of pages12
JournalMolecular Physics
Volume51
Issue number4
DOIs
Publication statusPublished - 1984

Fingerprint

polyatomic molecules
Vibration
Isotopes
Substitution reactions
isotopes
substitutes
Hamiltonians
vibration
Molecules
heavy nuclei

ASJC Scopus subject areas

  • Biophysics
  • Molecular Biology
  • Physical and Theoretical Chemistry
  • Condensed Matter Physics

Cite this

On the displacements of centres of vibration-rotation lines under isotope substitution in polyatomic molecules. / Bykov, A. D.; Makushkin, Yu S.; Ulenikov, O. N.

In: Molecular Physics, Vol. 51, No. 4, 1984, p. 907-918.

Research output: Contribution to journal › Article

Bykov, AD, Makushkin, YS & Ulenikov, ON 1984, 'On the displacements of centres of vibration-rotation lines under isotope substitution in polyatomic molecules', Molecular Physics, vol. 51, no. 4, pp. 907-918. https://doi.org/10.1080/00268978400100601
Bykov AD, Makushkin YS, Ulenikov ON. On the displacements of centres of vibration-rotation lines under isotope substitution in polyatomic molecules. Molecular Physics. 1984;51(4):907-918. https://doi.org/10.1080/00268978400100601
Bykov, A. D. ; Makushkin, Yu S. ; Ulenikov, O. N. / On the displacements of centres of vibration-rotation lines under isotope substitution in polyatomic molecules. In: Molecular Physics. 1984 ; Vol. 51, No. 4. pp. 907-918.
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