On the analysis of the gauche-form microwave spectrum of the isopropyl alcohol molecule

Abstract

The microwave spectrum of isopropyl alcohol was investigated in the region 10-80 GHz with a high-sensitivity Stark-modulation spectrometer. The spectrum of gauche form of this molecule has been analyzed. To correctly reproduce the experimental data, the effective vibration-rotation Hamiltonian has been improved. The parameters obtained from the fitting reproduce the experimental data with an average deviation σ {reversed tilde equals} 200 kHz.

Original language	English
Pages (from-to)	262-269
Number of pages	8
Journal	Journal of Molecular Spectroscopy
Volume	145
Issue number	2
DOIs	https://doi.org/10.1016/0022-2852(91)90113-O
Publication status	Published - 1991

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Spectroscopy
Atomic and Molecular Physics, and Optics

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10.1016/0022-2852(91)90113-O

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Ulenikov, O. N., Malikova, A. B., Qagar, C. O., Musaev, S. A., Adilov, A. A., & Mehtiev, M. I. (1991). On the analysis of the gauche-form microwave spectrum of the isopropyl alcohol molecule. Journal of Molecular Spectroscopy, 145(2), 262-269. https://doi.org/10.1016/0022-2852(91)90113-O

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abstract = "The microwave spectrum of isopropyl alcohol was investigated in the region 10-80 GHz with a high-sensitivity Stark-modulation spectrometer. The spectrum of gauche form of this molecule has been analyzed. To correctly reproduce the experimental data, the effective vibration-rotation Hamiltonian has been improved. The parameters obtained from the fitting reproduce the experimental data with an average deviation σ {reversed tilde equals} 200 kHz.",

author = "Ulenikov, {O. N.} and Malikova, {A. B.} and Qagar, {Ch O.} and Musaev, {S. A.} and Adilov, {A. A.} and Mehtiev, {M. I.}",

year = "1991",

doi = "10.1016/0022-2852(91)90113-O",

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journal = "Journal of Molecular Spectroscopy",

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T1 - On the analysis of the gauche-form microwave spectrum of the isopropyl alcohol molecule

AU - Ulenikov, O. N.

AU - Malikova, A. B.

AU - Qagar, Ch O.

AU - Musaev, S. A.

AU - Adilov, A. A.

AU - Mehtiev, M. I.

PY - 1991

Y1 - 1991

N2 - The microwave spectrum of isopropyl alcohol was investigated in the region 10-80 GHz with a high-sensitivity Stark-modulation spectrometer. The spectrum of gauche form of this molecule has been analyzed. To correctly reproduce the experimental data, the effective vibration-rotation Hamiltonian has been improved. The parameters obtained from the fitting reproduce the experimental data with an average deviation σ {reversed tilde equals} 200 kHz.

AB - The microwave spectrum of isopropyl alcohol was investigated in the region 10-80 GHz with a high-sensitivity Stark-modulation spectrometer. The spectrum of gauche form of this molecule has been analyzed. To correctly reproduce the experimental data, the effective vibration-rotation Hamiltonian has been improved. The parameters obtained from the fitting reproduce the experimental data with an average deviation σ {reversed tilde equals} 200 kHz.

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